Molybdenum oxide and cobalt oxyhydroxide composite electrochemical glucose sensor
US-2024175842-A1 · May 30, 2024 · US
US10220443B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10220443-B2 |
| Application number | US-201414901203-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jun 20, 2014 |
| Priority date | Jun 27, 2013 |
| Publication date | Mar 5, 2019 |
| Grant date | Mar 5, 2019 |
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The invention relates to a method for producing a steel shaped body, particularly, for example, a component for common rail fuel injection valves, comprising the method steps of: forming a powderous composition based on iron oxide, from oxide particles, with the addition of carbon and micro-alloy elements so as to adjust a bainitic microstructure; heating the powderous composition to a sinter temperature; reducing the shaped body obtained by sintering; and cooling the sintered shaped body to room temperature. As a result, from the three essential state phases in a state diagram ( 10 ), specifically the ferrite-perlite state range ( 11 ), the bainite state range ( 12 ) and the martensite state range ( 13 ), preferably the bainitic state phase is formed in a medium temperature range by the ferrite-perlite state range ( 11 ) being shifted to longer cooling periods and the martensite state range ( 13 ) being shifted to lower temperatures.
Opening claim text (preview).
The invention claimed is: 1. A method for producing a steel shaped body, comprising the following method steps: forming a powderous composition based on iron oxide, from solid oxide particles, with the addition of carbon and at least one micro-alloy element so as to adjust a bainitic microstructure, heating the powderous composition to sinter temperature, reducing the shaped body obtained by sintering, and cooling the sintered shaped body to room temperature. 2. The method according to claim 1 , characterized in that the oxide particles of the powderous composition comprise as element components: manganese at a content level of approximately 0.8 to 1.9%, silicon at a content level of approximately 0.3 to 1.5%, chrome at a content level of approximately 0.1 to 1.8%, nickel at a content level of approximately 0.2 to 1.5% and molybdenum at a content level of 0.1 to 0.5%. 3. The method according to claim 1 , characterized in that micro-alloy elements are added to the powderous composition based on iron oxide, said micro-alloy elements comprising aluminum at a content level of 0.01 to 0.04% and/or boron at a content level of ≤0.0025% and/or vanadium at a content level of 0.05 to 0.20%. 4. The method according to claim 1 , characterized in that carbon is added by means of a process gas. 5. The method according to claim 1 , characterized in that carbon is added by admixing graphite and/or carbides. 6. The method according to claim 1 , characterized in that carbon is added by means of a binder containing hydrocarbons. 7. The method according to claim 6 , characterized in that a process step is carried out to debind the shaped body. 8. The method according to claim 1 , characterized in that the addition of carbon results in a final content in the range between approximately 0.15 to 0.3%. 9. The method according to claim 1 , characterized in that carbide forming elements are admixed to the composition based on iron oxide, the carbide forming elements comprising titanium at a content level of approximately 0.01 to 0.03% and/or niobium at a content level of approximately 0.01 to 0.04%. 10. The method according to claim 9 , characterized in that carbon and/or nitrogen is/are introduced together with the carbide forming elements. 11. The method according to claim 10 , characterized in that nitrogen at a final content level in the range of approximately 0.01 to 0.03% is introduced as a process gas by means of N 2 or NH 3 during sintering. 12. The method according to claim 10 , characterized in that nitrogen at a final content level in the range of approximately 0.01 to 0.03% is introduced as a process gas. 13. The method according to claim 1 , characterized in that superfine-grained oxide ceramic particles are admixed to the powderous composition, the oxide ceramic particles being formed from one or a plurality of chemical compounds of the group: zirconium oxide, silicon oxide, aluminum oxide, yttrium oxide, silicon nitride, silicon carbide. 14. The method according to claim 1 , characterized in that carbon is added by means of carbon monoxide.
containing an organic binding agent comprising a mixture of, or obtained by reaction of, two or more components other than a solvent or a lubricating agent · CPC title
Metallic powder coated with organic material · CPC title
Oxide · CPC title
Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product · CPC title
the maximum content of each alloying element not exceeding 5% · CPC title
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