Activation of a self-activating hydroprocessing catalyst with steam

Patent metadata

Field	Value
Publication number	US-10220374-B2
Application number	US-201414258402-A
Country	US
Kind code	B2
Filing date	Apr 22, 2014
Priority date	Apr 24, 2013
Publication date	Mar 5, 2019
Grant date	Mar 5, 2019

Abstract

A self-activating hydroprocessing catalyst for treating heavy hydrocarbon feedstocks is further activated by contacting the self-activating catalyst with steam. The steam may be added to the heavy hydrocarbon feedstock prior to contacting with the self-activating catalyst or may be added to a reactor vessel containing the self-activating catalyst.

First claim

The invention claimed is:

1. A method, comprising:
co-mulling an inorganic oxide powder, molybdenum trioxide powder in the form of finely divided particles having a maximum dimension of less than 500 microns and a nickel compound to thereby form a co-mulled mixture;
forming said co-mulled mixture into a particle;
calcining said particle at a controlled calcination temperature in the range of from 700° C. to 790° C. for a calcination time period that is effective to provide a calcined particle consisting essentially of an inorganic oxide, molybdenum that is present in an amount in the range of from 1 to 10 weight percent, as metal and based on the total weight of said calcined particle, and nickel that is present in an amount such that the weight ratio of said nickel-to-said molybdenum is less than 0.4, and wherein said calcined particle has a pore size distribution such that less than 70% of the total pore volume of said calcined particle is in the pores of said calcined particle having a diameter in the range of from 70 Å to 150 Å, at least 10% of the total pore volume of said calcined particle is in the pores of said calcined particle having a diameter in the range of from 130 Å to 300 Å, and at least 1%, but less than 10%, of the total pore volume of said calcined particle is in the pores having a diameter greater than 1000 Å; and
contacting said calcined particle with a heavy hydrocarbon having a nickel content in the range of from 1 ppmw to 250 ppmw, a vanadium content in the range of from 5 ppmw to 250 ppmw, and a steam content in the range of from 0.01 wt % to 10 wt %, based on the weight of said heavy hydrocarbon feedstock, under conditions to provide a self-activating catalyst.

2. A The method as recited in claim 1 , wherein said steam content of said heavy hydrocarbon feedstock is in the range of from 2 wt % to 6 wt % based on the weight of the heavy hydrocarbon feedstock.

3. The method as recited in claim 2 , wherein the heavy hydrocarbon feedstock has a Sulfur content in the range of from 2 wt % to 8 wt %.

4. The method as recited in claim 3 , wherein the heavy hydrocarbon feedstock contains from 10 volume percent pitch to 90 volume percent pitch.

5. The method as recited in claim 4 , wherein said self-activating catalyst is capable of providing the conversion of the microcarbon residue (MCR) in said heavy hydrocarbon feedstock of at least 50 weight percent.

6. The method as recited in claim 5 , wherein the sulfur conversion activity of said self-activating catalyst is improved at least 10 weight percent.

7. The method as recited in claim 6 , wherein from 3% to 9% of the total pore volume of said calcined particle is in pores of a diameter greater than 1000 Å.

8. The method as recited in claim 7 , wherein said heavy hydrocarbon feedstock contains from 30 volume percent pitch to 75 volume percent pitch.

Assignees

• Shell Oil Co

Inventors

• Bhan Opinder Kishan

Classifications

• B01J23/883

  and nickel · CPC title

• B01J23/94

  of catalysts comprising metals, oxides or hydroxides of the iron group metals or copper · CPC title

• B01J38/06

  using steam · CPC title

• B01J27/02 Primary

  Sulfur, selenium or tellurium; Compounds thereof · CPC title

• B01J37/0036

  Grinding · CPC title