Method of forming microsphere having structural color

Patent metadata

Field	Value
Publication number	US-10220367-B2
Application number	US-201615231871-A
Country	US
Kind code	B2
Filing date	Aug 9, 2016
Priority date	Apr 14, 2009
Publication date	Mar 5, 2019
Grant date	Mar 5, 2019

Abstract

Provided is a method of forming a microsphere having a structural color, which includes providing a composition for generating a structural color including a curable material and magnetic nanoparticles dispersed in the curable material, forming an emulsion by adding the composition for generating a structural color to an immiscible solvent, arranging the magnetic nanoparticles located in the emulsion droplet of the curable material in a one-dimensional chain structure by applying a magnetic field to the emulsion, and fixing the chain structure by curing the emulsion droplet.

First claim

What is claimed is:

1. A microsphere having a structural color comprising:
a solid matrix; and
magnetic nanoparticles aligned to exhibit a structural color within the solid matrix,
wherein the solid matrix and the magnetic nanoparticles form a microsphere,
wherein the microsphere is made by the steps of:
providing a composition, wherein the composition includes a curable material and the magnetic nanoparticles dispersed in the curable material;
adding the composition to an immiscible solvent to form an emulsion including spherical droplets of the curable material dispersed in the immiscible solvent, each spherical droplet including the magnetic nanoparticles dispersed therein;
applying a magnetic field to the emulsion to align the magnetic nanoparticles located in each spherical droplet of the curable material; and
curing the spherical droplets dispersed in the immiscible solvent while applying the magnetic field to the emulsion to
i) fix the aligned magnetic nanoparticles in each spherical droplet and
ii) form the microsphere which is cured and dispersed in the immiscible solvent, wherein the microsphere includes the aligned magnetic nanoparticles in the cured material and has the structural color generated by a diffraction of light passing through the microsphere,
wherein the microsphere contains an ordered structure of a photonic crystal due to the alignment of the magnetic nanoparticles, and a diffraction angle of the light passing through the microsphere is changed with rotation of the microsphere.

2. The microsphere according to claim 1 , wherein the magnetic nanoparticles include a superparamagnetic material.

3. The microsphere according to claim 1 , wherein the magnetic nanoparticles have a structure coated with a shell layer surrounding a core formed in a cluster of magnetic nanocrystals.

4. The microsphere according to claim 3 , further comprising a solvation layer coating a surface of the magnetic nanoparticles.

5. The microsphere according to claim 1 , wherein the microsphere is dispersed in a phase-changeable matrix.

6. A display device comprising a microsphere rotated by an external magnetic field, wherein the microsphere having a structural color comprising:
a solid matrix; and
magnetic nanoparticles aligned to exhibit a structural color within the solid matrix,
wherein the solid matrix and the magnetic nanoparticles form a microsphere,
wherein the microsphere is made by the steps of:

providing a composition, wherein the composition includes a curable material and the magnetic nanoparticles dispersed in the curable material:
adding the composition to an immiscible solvent to form an emulsion including spherical droplets of the curable material dispersed in the immiscible solvent each spherical droplet including the magnetic nanoparticles dispersed therein:
applying a magnetic field to the emulsion to align the magnetic nanoparticles located in each spherical droplet of the curable material; and
curing the spherical droplets dispersed in the immiscible solvent while applying the magnetic field to the emulsion to
i) fix the aligned magnetic nanoparticles in each spherical droplet and
ii) form the microsphere which is cured and dispersed in the immiscible solvent wherein the microsphere includes the aligned magnetic nanoparticles in the cured material and has the structural color generated by a diffraction of light passing through the microsphere,

wherein the microsphere contains an ordered structure of a photonic crystal due to alignment of magnetic nanoparticles, and a diffraction angle of light passing through the microsphere is changed with rotation of the microsphere.

7. The display device according to claim 6 , wherein the magnetic nanoparticles include a superparamagnetic material.

8. The display device according to claim 6 , wherein the magnetic nanoparticles have a structure coated with a shell layer surrounding a core formed in a cluster of magnetic nanocrystals.

9. The microsphere according to claim 6 , further comprising a solvation layer coating a surface of the magnetic nanoparticles.

10. The display device according to claim 6 , wherein the microsphere is dispersed in a phase-changeable matrix.

11. The display device according to claim 6 , wherein, when a phase-changeable matrix is in a liquid phase, adjusting an angle of the external magnetic field changes an orientation of the microsphere.

Assignees

• Snu R&Db Foundation

Inventors

• Kwon Sunghoon
• Kim Hyoki
• Yin Yadong
• Ge Jianping

Classifications

• G02B2207/101

  Nanooptics · CPC title

• G02B5/201

  in the form of arrays · CPC title

• C09C1/24

  Oxides of iron · CPC title

• C08K3/22

  of metals · CPC title

• B82Y25/00

  Nanomagnetism, e.g. magnetoimpedance, anisotropic magnetoresistance, giant magnetoresistance or tunneling magnetoresistance · CPC title