Mitigation of vapor cloud explosion by chemical inhibition

Patent metadata

Field	Value
Publication number	US-10220230-B2
Application number	US-201314433404-A
Country	US
Kind code	B2
Filing date	Nov 12, 2013
Priority date	Nov 14, 2012
Publication date	Mar 5, 2019
Grant date	Mar 5, 2019

Abstract

A method to mitigate the consequences of a vapor cloud explosion due to an accidental release of a flammable gas in an open area, comprising: defining an hazardous area wherein an accidental release of flammable gas is likely to happen; receiving a signal from a detector device able to detect the presence of the flammable gas within the hazardous area, upon reception of a signal indicating the presence of the flammable gas within the hazardous area, generating a control signal to activate a release of a flame acceleration suppression product in the hazardous area, at a rate that is determined as a function of the volume of said hazardous area.

First claim

The invention claimed is:

1. A device to mitigate consequences of a vapor cloud explosion due to an accidental release of a flammable gas in an open area, comprising:
a memory to store an identifier of a hazardous area wherein an accidental release of flammable gas is likely to happen;
an output pin or an entry port to receive a signal from a detector device able to detect presence of the flammable gas within the hazardous area;
a central processing unit or a processor that are arranged to, upon reception of a signal indicating the presence of the flammable gas within the hazardous area, generate a control signal and activate a release of a flame acceleration suppression product in the hazardous area, at a rate that is determined as a function of a volume of said hazardous area, wherein the rate of the flame acceleration suppression product varies from 5 to 15 kg/s, and a ratio between the rate of the flame acceleration suppression product and the volume of the hazardous area equals a predetermined amount between 1 and 4 g·s −1 ·m −3 (every cubic meter with a rate of gram per second); and
an output pin or an output port to transmit the control signal toward at least one nozzle connected to a vessel.

2. A method to mitigate the consequences of a vapor cloud explosion due to an accidental release of a flammable gas in an open area, comprising providing a device according to claim 1 and using said device:
storing an identifier of a hazardous area wherein an accidental release of flammable gas is likely to happen;
receiving a signal from the detector device able to detect the presence of the flammable gas within the hazardous area;
upon reception of a signal indicating the presence of the flammable gas within the hazardous area, generating the control signal and activate a release of the flame acceleration suppression product in the hazardous area, at a rate that is determined as a function of a volume of said hazardous area, wherein the rate of the flame acceleration suppression product varies from 5 to 15 kg/s, and a ratio between the rate of the flame acceleration suppression product and the volume of the hazardous area equals a predetermined amount between 1 and 4 g·s −1 ·m −3 (every cubic meter with a rate of gram per second).

3. The method according to claim 2 , wherein
the volume of the hazardous area varies from 4500 to 5500 m 3 .

4. The method according to claim 2 , comprising generating the control signal such that the release of the flame acceleration suppression product takes place for more than 5 minutes.

5. The method according to claim 2 , wherein the release of the quantity of flame acceleration suppression product is performed continuously within a determined lapse of time.

6. The method according to claim 2 , wherein
the control signal to activate a release of a flame acceleration suppression product in the defined hazardous area is generated only if a number of detector devices, comprising at least two detector devices, detect the presence of the flammable gas within the hazardous area.

7. The method according to claim 6 , wherein the control signal is generated only if at least two adjacent detector devices detect the presence of the flammable gas.

8. The method according to claim 2 , comprising
on reception on a signal indicating a slight presence of the flammable gas within the hazardous area, activating an alarm.

9. The method according to claim 8 , further comprising
on reception of a signal confirming the presence of the flammable gas within the hazardous area, generating a signal so as to activate pressurization of a vessel containing the flame acceleration suppression product.

10. The method according to claim 2 , further comprising
storing a model of flammable cloud dispersal beyond the hazardous area,
upon receipt of the signal indicating the presence of the flammable gas within the hazardous area, generating an additional control signal to activate a release of some flame acceleration suppression product in an additional hazardous area that is determined as a function of the stored model.

11. The method according to claim 2 , further comprising providing a computer program product comprising instructions to perform the steps of claim 1 , and executing said steps with a processor.

12. A system to mitigate consequences of a vapor cloud explosion due to an accidental release of a flammable gas in an open area, comprising a device as recited in claim 1 , at least one set of two vessels comprising a first vessel for storing a flame acceleration suppression product and a second vessel for storing a carrier gas, and, for each set of two vessels:
at least one nozzle,
a duct arranged to connect the first vessel to said at least one nozzle.

13. The system according to claim 12 , wherein at least one set of the at least one set of two vessels comprises, at least two nozzles, and wherein the corresponding duct is arranged to connect the first vessel of said set to both nozzles.

14. The system according to claim 12 , wherein at least two nozzles are provided, and wherein two nozzles among said at least two nozzles are placed oppositely such that the flame acceleration suppression product released by one of the two nozzles placed oppositely is moved towards the other nozzle or lower, because of gravity.

15. The system according to claim 12 , wherein the flame acceleration suppression product comprises a mixture of at least two compounds selected form the group consisting of potassium chloride, sodium chloride and potassium carbonate.

16. An installation comprising a plurality of systems according to claim 12 , each system being associated to a block for which a corresponding hazardous area has been defined.

17. A system to mitigate consequences of a vapor cloud explosion due to an accidental release of a flammable gas in an open area, comprising a device, at least one set of two vessels comprising a first vessel for storing a flame acceleration suppression product and a second vessel for storing a carrier gas, and, for each set of two vessels:
at least one nozzle,
a duct arranged to connect the first vessel to said at least one nozzle,
wherein the device comprises:
a memory to store an identifier of a hazardous area wherein an accidental release of flammable gas is likely to happen;
an output pin or an entry port to receive a signal from a detector device able to detect presence of the flammable gas within the hazardous area;
a central processing unit or a processor that are arranged to, upon reception of a signal indicating the presence of the flammable gas within the hazardous area, generate a control signal and activate a release of a flame acceleration suppression product in the hazardous area, at a rate that is determined as a function of a volume of said hazardous area, wherein the rate of the flame acceleration suppression product varies from 5 to 15 kg/s, and a ratio between the rate of the flame acceleration suppression product and the volume of the hazardous area equals a predetermined amount between 1 and 4 g·s −1 ·m −3 (every cubic meter with a rate of gram per second); and
an output pin or an output port to transmit the control signal toward at least one nozzle connected to a vessel,
wherein the flame acceleration suppression product comprises a mixture of at least two compounds selected form the group consisting of potassium chloride, sodium chloride and potassium carbonate.

Assignees

• Total Raffinage Chimie

Inventors

• Gueret Christophe
• Roosendans Dirk
• Hoorelbeke Leopold
• Helschger Gilles

Classifications

• A62C99/0009

  Methods of extinguishing or preventing the spread of fire by cooling down or suffocating the flames · CPC title

• A62C3/06 Primary

  of highly inflammable material, e.g. light metals, petroleum products · CPC title

• A62C4/00

  Flame traps allowing passage of gas but not of flame or explosion wave · CPC title

• A62C37/36 Primary

  an actuating signal being generated by a sensor separate from an outlet device · CPC title

• A62C99/00 Primary

  Subject matter not provided for in other groups of this subclass · CPC title