Power cable having an aluminum corrosion inhibitor

Patent metadata

Field	Value
Publication number	US-10217546-B2
Application number	US-201515760791-A
Country	US
Kind code	B2
Filing date	Sep 25, 2015
Priority date	Sep 25, 2015
Publication date	Feb 26, 2019
Grant date	Feb 26, 2019

Abstract

A power cable having a metallic electrical conductor surrounded by one or more semiconductive layer and more or more insulating layer, wherein the cable has at least one metallic element made of aluminum, having a corrosion inhibitor provided in direct contact with the at least one metallic element made of aluminum.

First claim

The invention claimed is:

1. Power cable comprising a metallic element made of aluminum, wherein a corrosion inhibitor is provided in direct contact with the metallic element, the corrosion inhibitor having the following general formula (I):
R1-Ar—R2  (I)

wherein R1 is a 1-hydroxy-tetrazol-5-yl group a 2-hydroxy-tetrazol-5-yl group, 1-acryloxy-tetrazol-5-yl group or 1-(2-carboxyethenyl)-tetrazol-5-yl group;
Ar is a monocyclic or bicyclic aromatic moiety; and
R2 is a hydrogen atom (H) or a 1-hydroxy-tetrazol-5-yl group, a 2-hydroxy-tetrazol-5-yl group, a hydroxyl group (OH), a vinyl group, an allyl group or a —O—CO—R4 group, where R4 is an alkenyl group having from 2 to 6 carbon atoms.

2. Power cable according to claim 1 , wherein, when Ar is a monocyclic aromatic moiety and R2 is different from hydrogen atom, R1 and R2 are in ortho, meta, or para position with respect to each other.

3. Power cable according to claim 1 , wherein, when Ar is a bicyclic aromatic moiety and R2 is different from hydrogen atom, R1 and R2 are in peri position with respect to each other, or are substituents of the same cycle.

4. Power cable according to claim 1 , wherein the corrosion inhibitor has the following general formula (Ia)

wherein R1 and R2 have the same meanings as defined in formula (I) of claim 1 .

5. Power cable according to claim 1 , wherein R1 is a 1-hydroxy-tetrazol-5-yl group and R2 is a hydrogen atom.

6. Power cable according to claim 1 , wherein R2 is a hydrogen atom, a 1-hydroxy-tetrazol-5-yl group, preferably in ortho position with respect to R1, or a hydroxyl group (OH).

7. Power cable according to claim 1 , wherein the corrosion inhibitor of formula (I) is associated with a supporting material to form a corrosion inhibiting element, where the corrosion inhibitor is in direct contact with the metallic element made of aluminum.

8. Power cable according to claim 7 , wherein the corrosion inhibitor is absorbed in or adsorbed on the supporting material.

9. Power cable according to claim 1 wherein the corrosion inhibitor of formula (I) in direct contact with the metallic element made of aluminum is in an average amount of from 1×10 −3 g/cm 2 to 100×10 −3 g/cm 2 with respect to the surface of the metallic element.

10. Process for producing a power cable comprising a metallic element made of aluminum and a corrosion inhibiting element comprising a supporting material associated to a corrosion inhibitor of formula (I),
R1-Ar—R2  (I)

wherein R1 is a 1-hydroxy-tetrazol-5-yl group or a 2-hydroxy-tetrazol-5-yl group;
Ar is a monocyclic or bicyclic aromatic moiety; and
R2 is a hydrogen atom (H) or a 1-hydroxy-tetrazol-5-yl group, a 2-hydroxy-tetrazol-5-yl group, a hydroxyl group (OH), a vinyl group, an allyl group or a —O—CO—R4 group, where R4 is an alkenyl group having from 2 to 6 carbon atoms;
the process comprising the steps of
sprinkling the supporting material with said corrosion inhibitor of formula (I) in dry form or dissolved in a polar solvent to be subsequently evaporated, to provide said corrosion inhibiting element; and
positioning the corrosion inhibiting element in direct contact with the metallic element made of aluminum.

11. Process according to claim 10 wherein the polar solvent is selected from water, acetone and hydroxyl-containing solvents.

12. Process according to claim 10 wherein the corrosion inhibitor is dissolved in the polar solvent at a concentration of up to 250-300 ppmw (parts per million weight).

Assignees

• Prysmian Spa
• Milano Politecnico

Inventors

• De Martino Pamela
• Fallahmohammadi Ehsan
• Citterio Attilio
• Terruzzi Lidia

Classifications

• H01B7/2806 Primary

  Protection against damage caused by corrosion · CPC title

• C23F11/149

  Heterocyclic compounds containing nitrogen as hetero atom · CPC title

• H01B7/2825

  using a water impermeable sheath · CPC title

• H01B7/282

  Preventing penetration of fluid {, e.g. water or humidity,} into conductor or cable · CPC title

• H01B3/185

  Substances or derivates of cellulose · CPC title