Optical fiber rod, optical fiber, image fiber, and method for manufacturing optical fiber rod

Patent metadata

Field	Value
Publication number	US-10215916-B2
Application number	US-201515539271-A
Country	US
Kind code	B2
Filing date	Dec 22, 2015
Priority date	Dec 25, 2014
Publication date	Feb 26, 2019
Grant date	Feb 26, 2019

Abstract

An optical fiber rod ( 30 ) according to the present invention includes a center region ( 35 ), an outer region ( 31 ) formed around the center region ( 35 ), and an intermediate region ( 33 ) formed between the center region ( 35 ) and the outer region ( 31 ), and satisfies nA>nB>nC where nA is the refractive index of a material A produced by polymerization of a monomer ma, nB is the refractive index of a material B produced by polymerization of a monomer mb, and nC is the refractive index of a material C produced by polymerization of a monomer mc. The center region ( 35 ) is made of a material produced by polymerization of a monomer mixture containing the monomer ma, the outer region ( 31 ) is made of a material produced by polymerization of a monomer mixture containing the monomer mc, and the intermediate region ( 33 ) is made of a material produced by polymerization of a monomer mixture containing the monomer mb. The refractive index decreases in the order: the center region ( 35 )>the intermediate region ( 33 )>the outer region ( 31 ).

First claim

The invention claimed is:

1. An optical fiber rod, comprising:
a center region;
an outer region formed around the center region; and
an intermediate region formed between the center region and the outer region, wherein:
nA>nB>nC is satisfied where nA is a refractive index of a material A produced by polymerization of a monomer ma, nB is a refractive index of a material B produced by polymerization of a monomer mb, and nC is a refractive index of a material C produced by polymerization of a monomer mc,
the center region is made of a material produced by polymerization of a monomer mixture containing the monomer ma and not containing the monomer mc,
the outer region is made of a material produced by polymerization of a monomer mixture containing the monomer mc and not containing the monomer ma,
the intermediate region is made of a material produced by polymerization of a monomer mixture containing the monomer mb and not containing the monomer ma and the monomer mc,
a refractive index decreases in the order: the center region >the intermediate region >the outer region;
when the diameter of the optical fiber rod is 100, a diameter of the center region is 40 to 80, and a width of the outer region is 5 to 55, and
the intermediate region is at the midpoint between the outermost periphery of the center region and the innermost periphery of the outer region.

2. The optical fiber rod according to claim 1 , further comprising:
a first copolymer region formed between the center region and the intermediate region,
wherein the first copolymer region is made of a material produced by copolymerization of a monomer mixture comprising the monomer ma and the monomer mb and not containing the monomer mc.

3. The optical fiber rod according to claim 2 , wherein a refractive index of the first copolymer region continuously decreases from the center region side toward the intermediate region side.

4. The optical fiber rod according to claim 1 , further comprising:
a second copolymer region formed between the intermediate region and the outer region,
wherein the second copolymer region is made of a material produced by copolymerization of a monomer mixture comprising the monomer mb and the monomer mc and not containing the monomer ma.

5. The optical fiber rod according to claim 4 , wherein a refractive index of the second copolymer region continuously decreases from the intermediate region side toward the outer region side.

6. An optical fiber manufactured by stretching the optical fiber rod according to claim 1 .

7. An image fiber manufactured by stretching a bundle of a plurality of optical fibers according to claim 6 .

8. A method for manufacturing an optical fiber rod including a center region, an outer region formed around the center region, and an intermediate region formed between the center region and the outer region, where a refractive index decreases in the order: the center region >the intermediate region >the outer region, and nA>nB>nC is satisfied where nA is a refractive index of a material A produced by polymerization of only a monomer ma, nB is a refractive index of a material B produced by polymerization of only a monomer mb, and nC is a refractive index of a material C produced by polymerization of only a monomer mc, when the diameter of the optical fiber rod is 100, a diameter of the center region is 40 to 80, and a width of the outer region is 5 to 55, and the intermediate region is at the midpoint between the outermost periphery of the center region and the innermost periphery of the outer region, the method comprising:
forming the outer region by polymerization of a monomer mixture comprising the monomer mc and not containing the monomer ma;
forming the intermediate region on an inside of the outer region by polymerization of a monomer mixture comprising the monomer mb and not containing the monomer ma and the monomer mc; and
forming the center region on an inside of the intermediate region by polymerization of a monomer mixture comprising the monomer ma and not containing the monomer mc.

9. The optical fiber rod according to claim 2 , further comprising:
a second copolymer region formed between the intermediate region and the outer region,
wherein the second copolymer region is made of a material produced by copolymerization of a monomer mixture comprising the monomer mb and the monomer mc and not containing the monomer ma.

10. The optical fiber rod according to claim 9 , wherein a refractive index of the second copolymer region continuously decreases from the intermediate region side toward the outer region side.

11. A method of manufacturing an optical fiber rod, comprising:
stacking monomers on an inner surface of a rotating cylindrical reaction container by injecting a polymerization composition through an inlet at one end of the rotating cylindrical reaction container in a length direction, wherein the monomers are stacked atop one another sequentially toward an inner side, wherein a composition of the monomers changes continuously or intermittently during the stacking such that the resulting optical fiber rod is transparent and has an outer region having low refractive index and a central region having high refractive index.

12. A method of manufacturing an optical fiber, comprising:
heating an optical fiber rod produced by the method of claim 11 , and
pressing and drawing the heated optical fiber rod between a pair of rollers to form the optical fiber.

13. A method for manufacturing an image fiber, comprising:
placing a plurality of optical fibers produced according to claim 12 inside a pipe formed of a transparent thermoplastic resin, wherein the plurality of optical fibers are arranged inside the pipe in parallel to one another to form a bundle; and
heating and stretching the bundle.

14. The image fiber of claim 7 , wherein the image fiber has a sea-island structure having a plurality of cores placed separately from one another in a cladding, wherein the cladding is one continuous form, such that a number of cores forming the image fiber is 1000 or more, each core has a diameter of 1 μm or more and 20 μm or less, a width of the cladding is 0.2 μm or more and 2.0 μm or less, and an outside diameter of the image fiber is 0.2 mm or more and 4 mm or less.

Assignees

• Kuraray Co

Inventors

• Iwakawa Ryuichi

Classifications

• G02B6/03633

  arranged - - · CPC title

• G02B6/02038

  with core or cladding having graded refractive index · CPC title

• C08F265/04

  on to polymers of esters · CPC title

• G02B6/04

  formed by bundles of fibres (G02B6/24 takes precedence) · CPC title

• C03B2201/08

  doped with boron or fluorine or other refractive index decreasing dopant · CPC title