Thin-layer chromatography for screening oil-field surfactants

Patent metadata

Field	Value
Publication number	US-10215679-B2
Application number	US-201615220801-A
Country	US
Kind code	B2
Filing date	Jul 27, 2016
Priority date	Jul 27, 2016
Publication date	Feb 26, 2019
Grant date	Feb 26, 2019

Abstract

A thin-layer chromatography device can be used to determine or select a surfactant solution for use during hydrocarbon-fluid production operations. The thin-layer chromatography device can include a chamber that can receive a surfactant solution that includes a surfactant and a fluid. The thin-layer chromatography device can also include a substrate that can be coated with a layer of adsorbent material to form a thin-layer substrate and a hydrocarbon fluid can be disposed on the thin-layer substrate. The thin-layer substrate, along with the hydrocarbon fluid, can be positioned within the chamber to determine a mobility index of the hydrocarbon fluid when the hydrocarbon fluid contacts the surfactant solution. The mobility index can indicate an eluting capability of the surfactant solution with respect to the hydrocarbon fluid and can be used to select the surfactant solution to be injected into a wellbore that includes the hydrocarbon fluid to enhance hydrocarbon-fluid production operations.

First claim

What is claimed is:

1. A method comprising:
disposing a layer of an adsorbent material on a substrate to form a thin-layer substrate;
disposing a hydrocarbon fluid sample on a surface of the thin-layer substrate;
disposing a surfactant solution within a sample chamber, the surfactant solution comprising a surfactant and a fluid;
disposing the thin-layer substrate within the sample chamber;
determining a mobility index associated with the hydrocarbon fluid sample based on a distance traveled by the hydrocarbon fluid sample along the surface of the thin-layer substrate disposed within the sample chamber, the mobility index indicating an eluting capability of the surfactant solution with respect to the hydrocarbon fluid sample and usable for selecting, from among a plurality of surfactant solutions, a particular surfactant solution for use in a wellbore associated with the hydrocarbon fluid sample, the particular surfactant solution comprising the surfactant solution;
comparing the mobility index associated with the hydrocarbon fluid sample to a mobility index threshold;
selecting the particular surfactant solution from among the plurality of surfactant solutions based on comparing the mobility index to the mobility index threshold; and
injecting the particular surfactant solution into the wellbore to sweep hydrocarbon fluid from the wellbore.

2. The method of claim 1 , further comprising:
disposing a first surfactant solution within the sample chamber;
disposing a first amount of the hydrocarbon fluid sample on the surface of the thin-layer substrate;
disposing the thin-layer substrate that includes the first amount of the hydrocarbon fluid sample within the sample chamber and into the first surfactant solution;
determining a first mobility index associated with the first amount of the hydrocarbon fluid sample based on a first distance traveled by the first amount of the hydrocarbon fluid sample along the surface of the thin-layer substrate disposed within the sample chamber, the first mobility index indicating an eluting capability of the first surfactant solution with respect to the hydrocarbon fluid sample;
disposing, after removing the first surfactant solution from the sample chamber, a second surfactant solution within the sample chamber;
disposing a second amount of the hydrocarbon fluid sample on the surface of the thin-layer substrate;
disposing the thin-layer substrate that includes the second amount of the hydrocarbon fluid sample within the sample chamber and into the second surfactant solution;
determining a second mobility index associated with the second amount of the hydrocarbon fluid sample based on a second distance traveled by the second amount of the hydrocarbon fluid sample along the surface of the thin-layer substrate disposed within the sample chamber, the second mobility index indicating an eluting capability of the second surfactant solution with respect to the hydrocarbon fluid sample; and
comparing the first mobility index and the second mobility index for selecting the first surfactant solution or the second surfactant solution for use in the wellbore.

3. The method of claim 1 , further comprising:
disposing a plurality of hydrocarbon fluid samples on the surface of the thin-layer substrate;
determining mobility indices associated with the hydrocarbon fluid samples;
comparing mobility indices associated with the hydrocarbon fluid samples to determine a hydrocarbon fluid sample having a highest mobility index among the hydrocarbon fluid samples; and
selecting the particular surfactant solution for use in a wellbore associated with the hydrocarbon fluid sample having the highest mobility index.

4. The method of claim 1 , wherein the adsorbent material includes at least one of silica, alumina, cellulose, sand, or a particle from within the wellbore.

5. The method of claim 1 , wherein the surfactant solution further comprises at least one of brine, produced water, or fracturing fluid.

6. The method of claim 1 , wherein the substrate comprises glass, plastic, aluminum foil, or quartz.

7. A system comprising:
a sample chamber having an opening for receiving a surfactant solution that includes a surfactant and a fluid; and
a thin-layer substrate disposable within the sample chamber, the thin-layer substrate comprising a substrate and a layer of an adsorbent material disposed on the substrate on which an amount of a hydrocarbon fluid sample from within a wellbore is disposable for determining a mobility index associated with the hydrocarbon fluid sample based on a distance traveled by the hydrocarbon fluid sample along a surface of the thin-layer substrate subsequent to the thin-layer substrate being positioned within the sample chamber containing the surfactant solution, the mobility index indicating an eluting capability of the surfactant solution with respect to the hydrocarbon fluid sample,
wherein the surfactant solution is selectable from a plurality of surfactant solutions and each surfactant solution of the plurality of surfactant solutions is injectable into the wellbore to sweep hydrocarbon fluid from the wellbore based on differing values of the mobility index of the hydrocarbon fluid relative to a mobility index threshold.

8. The system of claim 7 , wherein the adsorbent material includes at least one of silica, alumina, cellulose, sand, or a particle.

9. The system of claim 8 , wherein the adsorbent material is collected from within a wellbore associated with the hydrocarbon fluid sample.

10. The system of claim 7 , wherein the fluid includes at least one of brine, produced water, or fracturing fluid.

11. The system of claim 7 , wherein the substrate comprises glass, plastic, aluminum foil, or quartz.

12. The system of claim 7 , wherein a plurality of hydrocarbon fluid samples are disposable on the thin-layer substrate for determining mobility indices associated with the plurality of hydrocarbon fluid samples, the mobility indices usable for selecting a particular surfactant solution for use in a wellbore associated with the hydrocarbon fluid sample having a highest mobility index among the plurality of hydrocarbon fluid samples.

13. A system comprising:
a thin-layer substrate comprising:
a substrate; and
a layer of an adsorbent material disposed on the substrate on which a hydrocarbon fluid sample obtained from within a wellbore is disposable for determining a mobility index associated with the hydrocarbon fluid sample based on a distance traveled by the hydrocarbon fluid sample along a surface of the thin-layer substrate subsequent to the thin-layer substrate being positioned within a sample chamber containing a surfactant solution, the mobility index indicating an eluting capability of the surfactant solution with respect to the hydrocarbon fluid sample,
wherein the surfactant solution is selectable from a plurality of additional surfactant solutions and each surfactant solution of the plurality of surfactant solutions is injectable into the wellbore to sweep hydrocarbon fluid from the wellbore based on differing values of the mobility index of the hydrocarbon fluid relative to a mobility index threshold.

14. The system of claim 13 , wherein the substrate comprises glass, plastic, aluminum foil, or quartz.

15. The system of claim 13 , wherein the adsorbent material includes at least one of silica, alumina, cellulose, or formation material.

16. The system of claim 15 , wherein the adsorbent material is collected from within the wellbore.

17. The system of claim 13 , wherein the surfactant solution comprises a surfa

Assignees

• Halliburton Energy Services Inc

Inventors

• Khamatnurova Tatyana V
• Holtsclaw Jeremy
• Holan Kristina Henkel

Classifications

• G01N11/02 Primary

  by measuring flow of the material · CPC title

• G01N2030/8854

  involving hydrocarbons · CPC title

• G01N30/90 Primary

  Plate chromatography, e.g. thin layer or paper chromatography · CPC title