Tire with tread intended for off-the-road service

Patent metadata

Field	Value
Publication number	US-10214633-B2
Application number	US-201615270689-A
Country	US
Kind code	B2
Filing date	Sep 20, 2016
Priority date	Sep 20, 2016
Publication date	Feb 26, 2019
Grant date	Feb 26, 2019

Abstract

This invention relates to heavy duty pneumatic rubber tires with treads intended for use on diverse surfaces, particularly for off-the-road service.

First claim

What is claimed is:

1. A rubber composition comprised of, based on parts by weight per 100 parts by weight of elastomer (phr),
(A) conjugated diene-based elastomers comprised of:
(1) about 80 to about 100 phr of natural cis 1,4-polyisoprene rubber, and
(2) up to about 20 phr of additional diene-based synthetic elastomer comprised of at least one of cis 1,4-polybutadiene rubber and styrene/butadiene rubber,

(B) about 20 to about 120 phr of rubber reinforcing filler comprised of a combination of pre-hydrophobated precipitated silica and rubber reinforcing carbon black, wherein said reinforcing filler is comprised of from about 5 to about 100 phr of rubber reinforcing carbon black, and wherein said pre-hydrophobated precipitated silica is comprised of a composite of precipitated silica pre-treated prior to addition to said rubber composition with bis(3-triethoxysillylpropyl) polysulfide having an average of from about 2 to about 4 connecting sulfur atoms in its polysulfidic bridge or with an alkoxyorganomercaptosilane, and
(C) from about 1 to about 50 phr of fatty acid amide, where said fatty acid amide is comprised of the general formula (I):

where R 1 is comprised of an alkyl hydrocarbon radical containing from 12 to 36 carbon atoms, an alkenyl hydrocarbon radical containing from 12 to 36 carbon atoms or alkadiene hydrocarbon radical containing from 12 to 36 carbon atoms, and
wherein said styrene/butadiene rubber is at least one of:
(1) tin or silicon coupled styrene/butadiene/butadiene rubber and
(2) functionalized styrene/butadiene rubber containing functional groups reactive with hydroxyl groups contained on said pre-hydrophobated silica.

2. The rubber composition of claim 1 wherein said rubber composition contains said styrene/butadiene rubber, wherein said styrene/butadiene rubber is a functionalized styrene/butadiene rubber containing functional groups reactive with hydroxyl groups on said pre-hydrophobated silica and wherein said fatty acid amide is comprised of at least one of caprylamide, lauralamide, palmitylamide, stearamide, oleylamide and myristylamide.

3. The rubber composition of claim 2 wherein said functional groups are comprised of at least one of amine, siloxy, thiol, hydroxyl and epoxy groups.

4. The rubber composition of claim 1 wherein said rubber composition contains said styrene/butadiene rubber wherein said styrene/butadiene rubber is a tin or silicon coupled styrene/butadiene rubber and wherein said fatty acid amide is comprised of at least one of caprylamide, lauralamide, palmitylamide, stearamide, oleylamide and myristylamide.

5. The rubber composition of claim 4 wherein said styrene/butadiene rubber is a functionalized styrene/butadiene rubber containing functional groups reactive with hydroxyl groups on said pre-hydrophobated silica where said functional groups are comprised of at least one of amine, siloxy, thiol, hydroxyl and epoxy groups.

6. A tire having a tread of the rubber composition of claim 1 .

7. A tire having a tread of the rubber composition of claim 2 .

8. A tire having a tread of the rubber composition of claim 5 .

Assignees

• Goodyear Tire & Rubber

Inventors

• Schmidt Ryan Michael
• Sandstrom Paul Harry

Classifications

• C08K5/20

  Carboxylic acid amides · CPC title

• C08L7/00

  Compositions of natural rubber · CPC title

• C08K3/04

  Carbon · CPC title

• C08K9/06 Primary

  with silicon-containing compounds · CPC title

• C08K3/36

  Silica · CPC title