Polymer composition with improved long-term stability, moulded parts produced herefrom and also purposes of use

Patent metadata

Field	Value
Publication number	US-10214631-B2
Application number	US-201314442606-A
Country	US
Kind code	B2
Filing date	Nov 18, 2013
Priority date	Nov 19, 2012
Publication date	Feb 26, 2019
Grant date	Feb 26, 2019

Abstract

The present invention relates to a polymer composition with improved long-term stability which comprises at least one thermoplastic polymer, carbon nanotubes, at least one antioxidant and also at least one additive or consists hereof. In addition, the present invention relates to molded parts which can be produced from the polymer compositions according to the invention. The invention likewise indicates possibilities for use of the polymer composition or of the molded parts.

First claim

The invention claimed is:

1. An ageing-resistant polymer composition with improved long-term stability, comprising, relative to the total composition,
a) 82 to 99.7% by weight of at least one thermoplastic polymer or a blend of at least two thermoplastic polymers,
b) 0.2 to 11% by weight of carbon nanotubes,
c) 0.05 to 1.0% by weight of at least one antioxidant, selected from the group consisting of phenols, phosphites, phosphonites, amines, mixtures and combinations thereof,
d) 0.05 to 3% by weight of at least one mono- or polyfunctional epoxide compound and at least one metal deactivator,
wherein the mono- or polyfunctional epoxide compound comprises a group of the formula:

wherein R 4 is the same or different at each occurrence and is selected from the group consisting of hydrogen and linear or branched alkyl radicals with 1 to 8 carbon atoms, and l is 0 or 1, and
e) 0 to 3% by weight of at least one additive.

2. The polymer composition according to claim 1 , wherein the at least one thermoplastic polymer is selected from the group consisting of
a) polymers from olefins or diolefins and polyolefin-based copolymers in the form of statistical or block structures,
b) polystyrene, polymethylstyrene, styrene-butadiene, poly(styrene-butadiene-styrene) (SBS), poly(styrene-isoprene), poly(styrene-isoprene-styrene) (SIS), poly(styrene-butadiene-acrylonitrile) (ABS), poly(styrene-acrylonitrile-acrylate) (ASA), poly(methylacrylate-butadiene-styrene) (MBS), styrene-maleic anhydride polymers, corresponding graft copolymers, and hydrated polymers obtainable therefrom,
c) halogen-containing polymers,
d) polymers of unsaturated esters, polyacrylonitrile and/or polyacrylamide,
e) polymers of unsaturated alcohols and derivatives,
f) polyacetals,
g) polyphenylene oxides and blends with polystyrene or polyamides,
h) polyurethanes,
i) polyamides and aromatic polyamides,
j) polyimides, polyamide imides, polyether imides, polyketones, polysulphones, polyether sulphones, polyphenylene sulphide, and polybenzimidazoles,
k) polyesters,
l) polycarbonate,
m) cellulose derivatives,
n) and mixtures, combinations and blends of two or more of the previously mentioned polymers.

3. The polymer composition according to claim 2 , wherein the carbon nanotubes are multiwall carbon nanotubes.

4. The polymer composition according to claim 2 , wherein the phenols are selected from the group consisting of compounds of the subsequently illustrated formula

R 1 being the same or different with each occurrence and being selected from the group consisting of linear or branched alkyl radicals with 1 to 8 carbon atoms and hydrogen,
X being selected from the group consisting of alkylene radicals, alkylene-carbonyl radicals, and alkylene-amide radicals,
n being 1 to 4, and
Z in the case where n=1 being hydrogen, in the case where n=2 being a chemical bond or an alkylene, in the case where n=3 being an alkinyl or in the case where n=4 being a carbon atom.

5. The polymer composition according to claim 2 , wherein the phosphites and/or phosphonites are selected from compounds of the subsequently illustrated formulae

respectively
R 2 being the same or different with each occurrence and being selected from the group consisting of alkyl-, aryl- and alkylated aryl substituents, in the case where two —O—R 2 substituents are bonded to one phosphorus atom, two radicals R 2 also being able to be bonded together to form a ring system,
Y being oxygen or a chemical bond,
m being 1 or 2,
R 3 in the case where m=1 being an alkyl- or aryl radical, or in the case where m=2 being an alkylene- or arylene radical.

6. The polymer composition according to claim 2 , wherein the amines are selected from the group consisting of N,N′-diisopropyl-p-phenylenediamine, N,N′-di-sec-butyl-p-phenylenediamine, N,N′-bis(1,4-dimethylpentyl)-p-phenylenediamine, N,N′-bis(1-ethyl-3-methylpentyl)-p-phenylenediamine, N,N′-bis(1-methylheptyl-p-phenylenediamine, N,N′-dicyclohexyl-p-phenylenediamine, N,N′-diphenyl-p-phenylenediamine, N,N′-bis(2-naphthyl)-p-phenylenediamine, N-isopropyl-N′-phenyl-p-phenylenediamine, N-(1,3-dimethylbutyl)-N′-phenyl-p-phenylenediamine, N-(1-methylheptyl)-N′-phenyl-p-phenylenediamine, N-cyclohexyl-N′-phenyl-p-phenylenediamine, 4-(p-tolnolsulphamoyl)diphenylamine, N,N′-dimethyl-N,N′-di-sec-butyl-p-phenylenediamine, diphenylamine, N-allyldiphenylamine, 4-isopropoxydiphenylamine, N-phenyl-1-naphthylamine, N-(4-tert-octylphenyl)-1-naphthylamine, N-phenyl-2-naphthylamine, octylated diphenylamine, e.g. p,p′-di-tert-octyldiphenylamine, 4-n-butylaminophenol, 4-butyrylaminophenol, 4-nonanoylaminophenol, 4-dodecanoylaminophenol, 4-octadecanoylaminophenol, bis(4-methoxyphenyl)amine, 2,6-di-tert-butyl-4-dimethylaminomethylphenol), 2,4′-diaminodiphenylmethane, 4,4′-diaminodiphenylmethane, N,N,N′,N′-tetramethyl-4,4′-diaminodiphenylmethane, 1,2-bis[(2-methylphenyl)amino]ethane, 1,2-bis(phenylamino)propane, (o-tolyl)biguanide, bis[4-(1′,3′-dimethylbutyl)phenyl]amine, tert-octylated N-phenyl-1-naphthylamine, a mixture of mono- and dialkylated tert-butyl/tert-octyldiphenylamine, a mixture of mono- and dialkylated nonyldiphenylamine, a mixture of mono- and dialkylated dodecyldiphenylamines, a mixture of mono- and dialkylated isopropyl/isohexyl-diphenylamines, a mixture of mono- and dialkylated tert-butyldiphenylamines, 2,3-dihydro-3,3-dimethyl-4H-1,4-benzothiazine, phenothiazine, a mixture of mono- and dialkylated tert-butyl/tert-octylphenothiazines, a mixture of mono- and dialkylated tert-octylphenothiazines, N-allylphenothiazine, N,N,N′,N′-tetraphenyl-1,4-diaminobut-2-ene and mixtures and combinations thereof.

7. The polymer composition according to claim 2 , wherein the metal deactivators are selected from the group consisting of N,N′-diphenyloxamide, N-salicylal-N′-salicyloyl hydrazine, N,N′-bis(salicyloyl) hydrazine, N,N′-bis(3,5-di-tert-butyl-4-hydroxyphenylpropionyl) hydrazine, 3-salicyloylamino-1,2,4-triazole, bis(benzylidene)oxalyl dihydrazide, oxanilide, isophthaloyl dihydrazide, sebacoylbisphenyl hydrazide, N,N′-diacetyladipoyl dihydrazide, N,N′-bis(salicyloyl)oxylyl dihydrazide, N,N′-bis(salicyloyl)thiopropionyl dihydrazide and mixtures and combinations thereof.

8. The polymer composition according to claim 1 , wherein the carbon nanotubes are multiwall carbon nanotubes.

9. The polymer composition according to claim 1 , wherein the phenols are selected from the group consisting of compounds of the subsequently illustrated formula

R 1 being the same or different with each occurrence and being selected from the group consisting of linear or branched alkyl radicals with 1 to 8 carbon atoms and hydrogen,
X being selected from the group consisting of alkylene radicals, alkylene-carbonyl radicals, and alkylene-amide radicals,
n being 1 to 4, and
Z in the case where n=1 being hydrogen, in the case where n=2 being a chemical bond or an alkylene, in the case where n=3 being an alkinyl or in the case where n=4 being a carbon atom.

10. The polymer composition according to claim 1 , wherein the phosphites and/or phosphonites are selected from compounds of the subsequently illustrated formulae

Assignees

• Fraunhofer Ges Forschung

Inventors

• Pfaendner Rudolf
• Metzsch-Zillingen Elke

Classifications

• C08K3/04

  Carbon · CPC title

• B29K2023/12

  PP, i.e. polypropylene · CPC title

• C08K5/20

  Carboxylic acid amides · CPC title

• C08K5/1345

  Carboxylic esters of phenolcarboxylic acids · CPC title

• C08K2201/011

  Nanostructured additives · CPC title