Chitin nanocrystals and process for preparation thereof

Patent metadata

Field	Value
Publication number	US-10214596-B2
Application number	US-201415036080-A
Country	US
Kind code	B2
Filing date	Nov 12, 2014
Priority date	Nov 18, 2013
Publication date	Feb 26, 2019
Grant date	Feb 26, 2019

Abstract

A process for producing chitin nanocrystals (ChNCs) involves contacting a chitinous material with a sufficient amount of an inorganic persulfate to produce chitin nanocrystals from the chitinous material. The process permits one-spot production of ChNCs from biomasses such as crustaceans, fungi, mushrooms, insects or mixtures thereof. Chitin nanocrystals produced by the process comprise surface carboxylic groups and are not initially deacetylated.

First claim

The invention claimed is:

1. A process for producing chitin nanocrystals (ChNCs) comprising contacting a chitinous material with a sufficient amount of an inorganic persulfate to produce chitin nanocrystals from the chitinous material.

2. The process according to claim 1 , further comprising providing the chitinous material to be contacted with the inorganic persulfate and recovering the chitin nanocrystals after contacting the chitinous material with the inorganic persulfate.

3. The process according to claim 1 , wherein the inorganic persulfate comprises ammonium persulfate, sodium persulfate, potassium persulfate or a mixture thereof.

4. The process according to claim 1 , wherein the chitinous material comprises non-vegetative biomass.

5. The process according to claim 1 , wherein the chitinous material comprises crustaceans, fungi, mushrooms, insects or mixtures thereof.

6. The process according to claim 1 , wherein the chitinous material comprises shrimp, crab, lobster and mixtures thereof.

7. The process according to claim 1 , wherein the inorganic persulfate is contacted with the chitinous material at a temperature in a range of 45-80° C.

8. The process according to claim 1 , wherein the persulfate is provided in an aqueous solution having a concentration of persulfate in a range of from 0.5 M to 2.0 M.

9. The process according to claim 1 , wherein the chitinous material and the inorganic persulfate are contacted in amounts to provide a ratio of chitin to inorganic persulfate in a range of 1:2 to 1:5.

10. The process according to claim 1 , wherein the persulfate is stirred with the chitinous material for a period of time in a range of from 6 hours to 24 hours.

11. The process according to claim 1 performed at a pH of 4 or less.

12. The process according to claim 1 , wherein contacting the chitinous material with an inorganic persulfate is performed at about 60° C., the persulfate is provided in an aqueous solution at a pH of 4 or less having a concentration of persulfate of about 1.0 M, and the persulfate is stirred with the chitinous material for about 12 hours.

13. The process according to claim 1 , further comprising deacetylating the chitin nanocrystals.

14. A chitin-based material comprising nanocrystals of chitin produced by the process of claim 1 , the nanocrystals having surface carboxylic acid groups.

15. The chitin-based material according to claim 14 , wherein the nanocrystals have a degree of oxidation in a range of from 0.04 to 0.20.

16. The chitin-based material according to claim 14 , wherein the nanocrystals are selectively oxidized at C6 primary hydroxyl groups.

17. The chitin-based material according to claim 14 , wherein the nanocrystals comprise an average width of 3-10 nm and an aspect ratio of 10 or greater.

18. The chitin-based material according to claim 14 , wherein the nanocrystals are deacetylated to a degree of deacetylation of 15-65%.

19. The chitin-based material according to claim 14 , wherein the nanocrystals have a crystallinity index at least 3% greater than the crystallinity index of a chitinous material from which the nanocrystals are made and a crystallinity index of 89% or greater.

20. The process according to claim 1 , wherein the chitinous material comprises crustaceans.

Assignees

• Nat Res Council Canada

Inventors

• Luong John H
• Lam Edmond
• Leung Chi Woon
• Hrapovic Sabahudin
• Male Keith B

Classifications

• C30B7/00

  Single-crystal growth from solutions using solvents which are liquid at normal temperature, e.g. aqueous solutions (from molten solvents C30B9/00; by normal or gradient freezing C30B11/00; under a protective fluid C30B27/00) · CPC title

• C08B37/003

  Chitin, i.e. 2-acetamido-2-deoxy-(beta-1,4)-D-glucan or N-acetyl-beta-1,4-D-glucosamine; Chitosan, i.e. deacetylated product of chitin or (beta-1,4)-D-glucosamine; Derivatives thereof · CPC title

• C30B1/10

  by solid state reactions or multi-phase diffusion · CPC title

• C30B29/60

  characterised by shape · CPC title

• C08B37/0003 Primary

  General processes for their isolation or fractionation, e.g. purification or extraction from biomass · CPC title