Cross current staged reverse osmosis

Patent metadata

Field	Value
Publication number	US-10214437-B2
Application number	US-201715612570-A
Country	US
Kind code	B2
Filing date	Jun 2, 2017
Priority date	Jun 6, 2016
Publication date	Feb 26, 2019
Grant date	Feb 26, 2019

Abstract

Systems and processes for purifying and concentrating a liquid feed stream are disclosed. In the systems, the concentrated liquid output from the high pressure side of a reverse osmosis stage is used as the draw solution in the low pressure side of the reverse osmosis stage in a configuration called osmotically assisted reverse osmosis. This reduces the osmotic pressure differential across the membrane, permitting high solute concentrations to be obtained, hastening the purification of the liquid. Reduced system pressures are also obtained by arranging multiple osmotically assisted reverse osmosis stages in a cross-current arrangement. Overall system energy consumption is reduced compared to conventional thermal processes for high concentration streams.

First claim

The invention claimed is:

1. A system for purifying a liquid feed stream to obtain a permeate, comprising:
(a) an initial reverse osmosis stage having: an initial high pressure side with an initial high pressure side inlet for receiving the liquid feed stream and an initial high pressure side outlet for outputting an initial recycle stream and an initial concentrate stream, and an initial low pressure side with an initial low pressure side inlet for receiving the initial recycle stream from the initial high pressure side outlet, and an initial low pressure side outlet for outputting a diluted stream, wherein the initial high pressure side outlet is split to form the initial recycle stream that is fed to the initial low pressure side inlet, and the initial concentrate stream;
(b) an intermediate section having one or more intermediate reverse osmosis stages arranged in series, wherein each intermediate stage has: an intermediate high pressure side with an intermediate high pressure side inlet and an intermediate high pressure side outlet, an intermediate low pressure side with an intermediate low pressure side inlet and an intermediate low pressure side outlet, an intermediate recycle stream and an intermediate concentrate stream exiting the intermediate high pressure side outlet, the intermediate recycle stream being sent to the intermediate low pressure side inlet, and an exit stream exiting the intermediate low pressure side outlet; and wherein the intermediate section receives the diluted stream from the initial reverse osmosis stage and outputs a purified stream, wherein the intermediate high pressure side outlet is split to form the intermediate recycle stream that is fed to the intermediate low pressure side inlet, and the intermediate concentrate stream; and
(c) a final reverse osmosis stage having: a final high pressure side having a final high pressure side inlet for receiving the purified stream and a final high pressure side outlet for outputting a reject stream, and a final low pressure side that outputs the permeate.

2. The system of claim 1 , wherein the reject stream of the final reverse osmosis stage is combined with the diluted stream from the initial reverse osmosis stage and received by the intermediate section.

3. The system of claim 2 , further comprising a pressurizing means for increasing the pressure of the diluted stream.

4. The system of claim 1 , wherein the reject stream of the final reverse osmosis stage is combined with the liquid feed stream and received by the initial reverse osmosis stage.

5. The system of claim 1 , further comprising a pressure reduction device through which at least the initial recycle stream of the initial reverse osmosis stage passes for reducing a pressure of the initial recycle stream.

6. The system of claim 1 , further comprising an energy recovery device at the intermediate high pressure side outlet of each intermediate reverse osmosis stage.

7. The system of claim 1 , further comprising a feed pump for pressurizing the liquid feed stream received by the initial reverse osmosis stage, an interstage pump for pressurizing the diluted stream that is received by the intermediate section, and a final pump for pressurizing the purified stream received by the final reverse osmosis stage.

8. The system of claim 1 , wherein the intermediate section has a first intermediate reverse osmosis stage and a second intermediate reverse osmosis stage,
the first intermediate reverse osmosis stage receives the diluted stream from the initial reverse osmosis stage,
the intermediate high pressure side of the second intermediate reverse osmosis stage receives the exit stream of the first intermediate reverse osmosis stage,
the purified stream is the exit stream of the second intermediate reverse osmosis stage; and
the reject stream of the final reverse osmosis stage is combined with the exit stream of the first intermediate reverse osmosis stage and received by the second intermediate reverse osmosis stage.

9. The system of claim 1 , further comprising a means for pretreating the liquid feed stream upstream of the initial reverse osmosis stage.

10. The system of claim 9 , wherein the means for pretreating the liquid feed stream includes a capacitive deionization system or a forward osmosis system.

11. The system of claim 10 , further comprising a sonication system for receiving a concentrate from the capacitive deionization system.

12. The system of claim 1 , wherein the initial reverse osmosis stage has a plurality of initial reverse osmosis modules, and the initial low pressure side outlet of each initial reverse osmosis module outputs a yield stream, the yield streams being combined to form the diluted stream.

13. The system of claim 12 , wherein for each initial reverse osmosis module, an output stream exiting the initial high pressure side outlet is split to form an initial recycle stream that is fed to the initial low pressure side outlet.

14. The system of claim 12 , wherein the initial recycle stream passes through a valve or energy recovery device prior to being fed to the initial low pressure side inlet.

15. The system of claim 1 , wherein the intermediate section has a plurality of intermediate reverse osmosis stages, and the intermediate low pressure side outlet of each intermediate reverse osmosis stage outputs a yield stream, the yield streams being combined to form the purified stream.

16. The system of claim 15 , wherein the intermediate recycle stream passes through a valve or energy recovery device prior to being fed to the intermediate low pressure side inlet.

Assignees

• Battelle Memorial Institute

Inventors

• Blohm Kurt
• Peterson Richard
• Lane Ann E
• Winecki Slawomir
• Argumedo Darwin

Classifications

• B01D2311/25

  Recirculation, recycling or bypass, e.g. recirculation of concentrate into the feed · CPC title

• F03G7/005

  Electro-chemical actuators; Actuators having a material for absorbing or desorbing gas, e.g. a metal hydride; Actuators using the difference in osmotic pressure between fluids; Actuators with elements stretchable when contacted with liquid rich in ions, with UV light, with a salt solution · CPC title

• C02F2301/08

  Multistage treatments, e.g. repetition of the same process step under different conditions · CPC title

• B01D61/04

  Feed pretreatment · CPC title

• B01D2313/246

  Energy recovery means · CPC title