Decorative part for motor vehicles

Patent metadata

Field	Value
Publication number	US-10214158-B2
Application number	US-201214342443-A
Country	US
Kind code	B2
Filing date	Aug 29, 2012
Priority date	Sep 5, 2011
Publication date	Feb 26, 2019
Grant date	Feb 26, 2019

Abstract

The present invention relates to a decorative part, comprising an electroplated layer array applied to a plastic substrate. On the electroplated layer array, a PVD layer array having an adhesive layer, a mixed layer and a color-providing cover layer is provided, wherein the mixed layer provides for durability, in particular corrosion protection, and the necessary hardness of the surface.

First claim

What is claimed is:

1. Decorative part for a motor vehicle, comprising:
a substrate,
an electroplated layer array on the substrate wherein the electroplated layer array comprises multiple metal layers, and
a coloring cover layer applied to the outer surface of the electroplated layer array by means of physical vapor deposition,
wherein the coloring cover layer is part of a PVD layer system that comprises, between the substrate and the coloring cover layer, an adhesive layer directly on the electroplated layer array and that comprises, between the adhesive layer and the coloring cover layer being the outermost layer, a mixed layer directly on the adhesive layer,
wherein the mixed layer comprises at least a first metal Me1 and a second metal Me2 and element X,
wherein X is at least one element from the group consisting of carbon and nitrogen,
wherein X has, at least in a portion of the mixed layer, a sub-stoichiometric concentration, and
wherein the concentration of element X varies within the mixed layer from a sub-stoichiometric concentration at the interface of the mixed layer and the adhesive layer to a layer with an over-stoichiometric concentration.

2. Decorative part according to claim 1 , characterized in that the mixed layer is formed according to the formula (Me1 a Me2 b ) u X v , wherein a+b≤1.

3. Decorative part according to claim 2 , characterized in that a+b=1 and thus Me1 and Me2 are the only metallic elements in the mixed layer.

4. Decorative part according to claim 1 , characterized in that Me1 is chromium and Me2 is zirconium.

5. Decorative part according to claim 1 , characterized in that X comprises both nitrogen as well as carbon.

6. Decorative part according to claim 1 , characterized in that the adhesive layer, the mixed layer and the coloring cover layer comprises each chromium or each zirconium or each both elements.

7. Decorative part according to claim 1 , characterized in that the coloring cover layer comprises nitrogen and carbon.

8. Decorative part according to claim 1 , wherein the substrate is a plastic substrate.

9. Decorative part according to claim 5 , wherein X consists of nitrogen and carbon.

10. Decorative part according to claim 7 , wherein the coloring cover layer comprises nitrogen and carbon in an overstoichiometric manner.

11. Decorative part according to claim 1 , wherein the adhesive layer comprises a metallic layer.

12. Decorative part according to claim 11 , wherein the metallic layer includes one of chromium and zirconium.

13. Decorative part according to claim 1 , wherein the portion is directly in contact with the adhesive layer.

Assignees

• Ribeiro Carlos
• Bauer Sascha
• Oerlikon Surface Solutions Ag Pfaeffikon

Inventors

• Ribeiro Carlos
• Bauer Sascha

Classifications

• C23C14/024

  Deposition of sublayers, e.g. to promote adhesion of the coating (C23C14/027 takes precedence) · CPC title

• Y10T428/31678

  Of metal · CPC title

• C23C14/0641

  Nitrides (C23C14/0617 takes precedence) · CPC title

• B60R13/04 Primary

  External} Ornamental or guard strips; Ornamental inscriptive devices {thereon (fastening strips or bars to sheets or plates by means of clips F16B5/12) · CPC title

• C23C28/34

  including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates · CPC title