Hybrid electrochemical cell

Patent metadata

Field	Value
Publication number	US-10211495-B2
Application number	US-201515319286-A
Country	US
Kind code	B2
Filing date	Jun 16, 2015
Priority date	Jun 16, 2014
Publication date	Feb 19, 2019
Grant date	Feb 19, 2019

Abstract

Disclosed is a hybrid electrochemical cell with a first conductor having at least one portion that is both a first capacitor electrode and a first battery electrode. The hybrid electrochemical cell further includes a second conductor having at least one portion that is a second capacitor electrode and at least one other portion that is a second battery electrode. An electrolyte is in contact with both the first conductor and the second conductor. In some embodiments, the hybrid electrochemical cell further includes a separator between the first conductor and the second conductor to prevent physical contact between the first conductor and the second conductor, while facilitating ion transport between the first conductor and the second conductor.

First claim

What is claimed is:

1. A hybrid electrochemical cell comprising:
a) a first conductor having at least one portion that is both a first capacitor electrode and a first battery electrode;
b) a second conductor having at least one portion that is a second capacitor electrode comprising a layered metal oxide positive electrode and at least one other portion that is a second battery electrode comprising an activated carbon positive electrode; and
c) an electrolyte in contact with both the first conductor and the second conductor, wherein the hybrid electrochemical cell comprises at least one of a lithium-ion material and a lithium-ion chemistry.

2. The hybrid electrochemical cell of claim 1 further comprising a separator between the first conductor and the second conductor that is configured in a manner to prevent or reduce physical contact between the first conductor and the second conductor and that facilitates ion transport between the first conductor and the second conductor.

3. The hybrid electrochemical cell of claim 1 wherein the first battery electrode comprises hard carbon, silicon alloy, composite alloy, or any combination thereof.

4. The hybrid electrochemical cell of claim 1 wherein the second battery electrode comprises lithium cobalt oxide, lithium manganese oxide, lithium nickel oxide, lithium nickel manganese cobalt oxide, lithium nickel cobalt aluminum oxide, lithium titanium oxide, lithium iron phosphate, or any combination thereof.

5. The hybrid electrochemical cell of claim 1 wherein the second capacitor electrode comprises an interconnected corrugated carbon-based network (ICCN).

6. The hybrid electrochemical cell of claim 5 wherein the interconnected corrugated carbon-based network (ICCN) electrode comprises a plurality of expanded and interconnected carbon layers that include a corrugated carbon layer.

7. The hybrid electrochemical cell of claim 1 wherein the second capacitor electrode is redox active to store charge via intercalation pseudo-capacitance.

8. The hybrid electrochemical cell of claim 7 wherein the second capacitor electrode comprises niobium pentoxide.

9. The hybrid electrochemical cell of claim 1 integrated as a micro-hybrid electrochemical cell with an implantable medical device, a smart card, a radio frequency identification (RFID) tag, a wireless sensor, a wearable electronic device, an energy harvester, a solar cell, or any combination thereof.

10. The hybrid electrochemical cell of claim 1 wherein the second capacitor electrode and the second battery electrode have electrode digits with a length L, a width W, and an interspace I.

11. The hybrid electrochemical cell of claim 10 , wherein the length L is about 4000 μm to about 5000 μm, the width W is about 300 μm to around about 1800 μm, and the interspace I is about 100 μm to about 200 μm.

12. The hybrid electrochemical cell of claim 10 , wherein the length L is around about 0.5 cm to about 1.5 cm, the width W ranges from around about 0.05 cm to about 0.2 cm, and the interspace I is about 0.01 cm to about 0.05 cm.

13. The hybrid electrochemical cell of claim 1 wherein the hybrid electrochemical cell comprises nickel-cadmium (Ni—Cd) and/or nickel-metal hydride (Ni-MH) chemistries.

14. The hybrid electrochemical cell of claim 1 wherein energy density of the hybrid electrochemical cell ranges between 20 watt-hour/kilogram (Wh/kg) to around about 200 Wh/kg.

15. The hybrid electrochemical cell of claim 1 wherein power density of the hybrid electrochemical cell ranges between nearly 1,000 watt /kilogram (W/kg) to about 10,000 W/kg.

16. A method of manufacturing a micro-hybrid electrochemical cell comprising lithium-ion (Li-Ion) material, the method comprising growing porous positive and negative electrode materials on interconnected corrugated carbon-based network (ICCN) interdigitated patterns, wherein an ICCN pattern is created using a consumer-grade optical disc burner drive, comprising a series of steps of:
a) a first step, wherein a graphite oxide (GO) dispersion in water is dropcast onto an optical disc and dried in air to form a GO film;
b) a second step, wherein a micro-pattern made with imaging or drafting software is directly printed onto the GO coated optical disc, and wherein the GO film absorbs energy from a laser and is converted into an ICCN pattern;
c) a third step, wherein anode and cathode materials are sequentially electrodeposited on the ICCN pattern, and voltage-controlled and current-controlled electrodeposition is used to ensure conformal coating of active materials throughout the three-dimensional (3D) structure of the ICCN;
d) a fourth step, wherein a nickel-tin alloy, silicon, or graphite micro-particles are electrodeposited onto the ICCN pattern corresponding to an anode; and
e) a fifth step, wherein a drop of electrolyte is added to provide ions that allow continuous electron flow when the micro-hybrid electrochemical cell is under load.

17. A method of manufacturing a micro-hybrid electrochemical cell relying on nickel-cadmium (Ni—Cd) and/or nickel-metal hydride (Ni-MH) chemistries, the method comprising growing porous positive and negative electrode materials on interconnected corrugated carbon-based network (ICCN) interdigitated patterns, wherein an ICCN pattern is created using an optical disc burner drive, comprising a series of steps of:
a) a first step, wherein a graphite oxide (GO) dispersion in water is dropcast onto an optical disc and dried in air to form a GO film;
b) a second step, wherein a micro-pattern made with imaging or drafting software is directly printed onto the GO-coated optical disc, and wherein the GO film absorbs energy from a laser and is converted into an ICCN pattern;
c) a third step, wherein voltage-controlled and current-controlled electrodeposition is used to ensure conformal coating of active materials throughout the three-dimensional (3D) structure of ICCN, and a metal is electrodeposited on ICCN microelectrodes making up a second battery electrode that forms a portion of an anode;
d) a fourth step, wherein cadmium hydroxide (Cd(OH)2) is added to the ICCN corresponding to the anode; and
e) a fifth step, wherein a drop of electrolyte is added to provide ions that allow continuous electron flow when the micro-hybrid electrochemical cell is under load.

Assignees

• Univ California

Inventors

• El-Kady Maher F
• Kaner Richard B

Classifications

• H01M4/485

  of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy (H01M4/505, H01M4/525 take precedence) · CPC title

• H01M4/386

  Silicon or alloys based on silicon · CPC title

• H01M12/00

  Hybrid cells; Manufacture thereof (hybrid capacitors H01G11/00) · CPC title

• H01G11/32

  Carbon-based · CPC title

• H01G11/86

  specially adapted for electrodes (carbonisation or activation of carbon for the manufacture of electrodes H01G11/34) · CPC title