Method for electrical contact materials including Ag plated CNTs

Patent metadata

Field	Value
Publication number	US-10210965-B2
Application number	US-201615162471-A
Country	US
Kind code	B2
Filing date	May 23, 2016
Priority date	May 22, 2015
Publication date	Feb 19, 2019
Grant date	Feb 19, 2019

Abstract

In some embodiments, the effect of uniformly dispersing carbon nanotubes in the material is achieved by including Ag in the carbon nanotubes to suppress the aggregation of carbon nanotubes when the electrical contacts are prepared.

First claim

What is claimed is:

1. A method for preparing electrical contact materials comprising Ag plated carbon nanotubes, the method comprising:
(a) putting carbon nanotubes into a silver nitrate solution and subjecting the carbon nanotubes to ultrasonic dispersion and acid treatment;
(b) washing the carbon nanotubes subjected to the ultrasonic dispersion and acid treatment in step (a);
(c) binding tin and palladium to surfaces of the carbon nanotubes by subsequently mixing the washed carbon nanotubes with a mixed solution of tin chloride and hydrochloric acid and a mixed solution of palladium chloride and hydrochloric acid, and then each applying ultrasonic wave thereto;
(d) putting an aqueous silver (I) nitrate solution and an aqueous ammonia solution into a container and mixing the resulting solution until the solution becomes colorless, and then mixing the carbon nanotubes prepared in step (c) with the solution;
(e) preparing Ag plated carbon nanotubes by mixing an aqueous glyoxylic acid solution with an aqueous sodium hydroxide solution, and then washing the resulting nanotubes with deionized water; and
(f) preparing a powder mixture by mixing the Ag plated carbon nanotubes with an alloy where the metals are mixed.

2. The method of claim 1 , wherein the metals including the alloy mixed with the carbon nanotubes in step (f) have a conductivity of 14.3 MS/m or more.

3. The method of claim 1 , wherein the alloy comprises one or more metals selected from the group consisting of copper, nickel, and gold.

4. The method of claim 1 , further comprising:
(g) subjecting the powder mixture to ultrasonic dispersion, and vacuum drying the powder mixture; and
(h) sintering the vacuum-dried powder mixture.

5. The method of claim 1 , wherein in step (b), the carbon nanotubes are washed until being reached at pH 7.

6. The method of claim 1 , wherein in step (e), the aqueous glyoxylic acid solution and the aqueous sodium hydroxide solution are mixed until being reached at pH 9.

7. The method of claim 6 , wherein the aqueous glyoxylic acid solution and the aqueous sodium hydroxide solution are washed with deionized water until being reached at pH 7.

8. The method of claim 1 , wherein in step (a), the carbon nanotubes are subjected to ultrasonic dispersion for 5 minutes and to acid treatment for 2 hours.

9. The method of claim 1 , wherein in step (e), the aqueous glyoxylic acid solution and the aqueous sodium hydroxide solution are reacted with each other at 90° C. for 1 hour when the solutions are mixed.

10. The method of claim 4 , wherein step (h) is performed by a spark plasma sintering method.

Assignees

• Lsis Co Ltd
• Research & Business Found Sungkyunkwan Univ

Inventors

• Cho Wookdong
• Moon Chuldong
• Choi Hyeonjeong
• Kim Wonyoung
• Baik Seunghyun
• Lee Dongmok
• Sim Jeonghyun

Classifications

• H01H2300/036

  Application nanoparticles, e.g. nanotubes, integrated in switch components, e.g. contacts, the switch itself being clearly of a different scale, e.g. greater than nanoscale · CPC title

• H01H11/048 Primary

  by powder-metallurgical processes · CPC title

• H01H1/027

  containing carbon particles or fibres · CPC title

• H01H1/023

  having a noble metal as the basic material · CPC title

• H01B1/04

  mainly consisting of carbon-silicon compounds, carbon or silicon · CPC title