Enhanced chemical detection using acid catalyzed hydrolysis

Patent metadata

Field	Value
Publication number	US-10209231-B2
Application number	US-201615256443-A
Country	US
Kind code	B2
Filing date	Sep 2, 2016
Priority date	Sep 2, 2016
Publication date	Feb 19, 2019
Grant date	Feb 19, 2019

Abstract

Various techniques are provided to determine the presence of trace chemicals corresponding to various materials of interest. In one example, a method includes receiving a vapor-phase nitric acid precursor. The vapor-phase nitric acid precursor is subsequently hydrolyzed in the presence of an acid catalyst to form nitric acid. The nitric acid is then received at a chemical reporter of a chemical detector. A response of the chemical reporter to the nitric acid is detected by the chemical reporter to determine whether materials of interest are present. Additional methods and related devices are also provided.

First claim

What is claimed is:

1. A device comprising:
an inlet configured to receive a vapor-phase nitric acid precursor;
a solid acid catalyst configured to react with the vapor-phase nitric acid precursor to form nitric acid; and
a chemical detector comprising a chemical reporter configured to respond to the nitric acid, wherein the chemical reporter is configured to detect a response of the chemical reporter to the nitric acid to determine whether materials of interest are present.

2. The device of claim 1 , further comprising:
an excitation source having an associated wavelength configured to illuminate the chemical reporter to provide the response as a change in fluorescence in the chemical reporter; and
wherein the chemical detector comprises an optical detector.

3. The device of claim 1 , wherein the chemical reporter comprises a colorimetric reporter, a resistive reporter, a luminescent reporter, or an infrared/Raman reporter.

4. The device of claim 1 , wherein the detector comprises an optical detector or a resistivity detector.

5. The device of claim 1 , wherein the nitric acid precursor comprises one or more of:
a nitrate ester comprising one or more of pentaerythritol tetranitrate (PETN), ethylene glycol dinitrate (EGDN), or nitroglycerin; or
a nitramine comprising cyclotrimethylenetrinitramine (RDX).

6. The device of claim 1 , wherein the solid acid catalyst comprises one or more perfluorinated polymers containing sulfonic acid groups.

7. The device of claim 1 , wherein the chemical detector comprises a substrate reporter surface having a sensing channel comprising a plurality of chemical reporters disposed therein.

8. The device of claim 6 , wherein the solid acid catalyst is disposed within the sensing channel upstream of the plurality of chemical reporters.

9. The device of claim 1 , wherein the chemical reporter is a first chemical reporter, and the device further comprises:
a second chemical reporter of the chemical detector configured to receive the vapor-phase nitric acid precursor, wherein the chemical detector is further configured to detect a response of the second chemical reporter to the vapor-phase nitric acid precursor; and
a processor configured to determine whether a particular material of interest is present based on the response of the first chemical reporter and the response of the second chemical reporter.

10. The device of claim 1 , wherein:
the chemical reporter is a first chemical reporter;
the inlet is further configured to receive a vapor-phase peroxide precursor;
the solid acid catalyst is further configured to react with the vapor-phase peroxide precursor to form hydrogen peroxide; and
the device further comprises a second chemical reporter of the chemical detector configured to respond to the hydrogen peroxide; and
the chemical detector is further configured to detect a response of the second chemical reporter to the hydrogen peroxide to determine whether materials of interest are present.

11. A method of operating the device of claim 1 , comprising:
receiving the vapor-phase nitric acid precursor;
hydrolyzing the vapor-phase nitric acid precursor in the presence of the solid acid catalyst to form nitric acid;
receiving the nitric acid at the chemical reporter; and
detecting, by the chemical detector, a response of the chemical reporter to the nitric acid to determine whether materials of interest are present.

12. The method of claim 11 , further comprising:
illuminating the chemical reporter with an excitation source having an associated wavelength to provide the response as a change in fluorescence in the chemical reporter; and
wherein the detecting is performed by an optical detector.

13. The method of claim 11 , wherein the chemical reporter comprises a colorimetric reporter, a resistive reporter, a luminescent reporter, or an infrared/Raman reporter.

14. The method of claim 11 , wherein the detecting is performed by an optical detector or a resistivity detector of the chemical detector.

15. The method of claim 11 , wherein the nitric acid precursor comprises one or more of:
a nitrate ester comprising one or more of pentaerythritol tetranitrate (PETN), ethylene glycol dinitrate (EGDN), or nitroglycerin; or
a nitramine comprising cyclotrimethylenetrinitramine (RDX).

16. The method of claim 11 , wherein the solid acid catalyst comprises one or more perfluorinated polymers containing sulfonic acid groups.

17. The method of claim 11 , wherein the chemical detector comprises a substrate reporter surface having a sensing channel comprising a plurality of chemical reporters disposed therein.

18. The method of claim 17 , wherein the solid acid catalyst is disposed within the sensing channel upstream of the plurality of chemical reporters.

19. The method of claim 11 , wherein the chemical reporter is a first chemical reporter, and the method further comprises:
receiving the vapor-phase nitric acid precursor at a second chemical reporter of the chemical detector
detecting, by the chemical detector, a response of the second chemical reporter to the vapor-phase nitric acid precursor; and
determining whether a particular material of interest is present based on the response of the first chemical reporter and the response of the second chemical reporter.

20. The method of claim 11 , wherein the chemical reporter is a first chemical reporter, and the method further comprises:
receiving a vapor-phase peroxide precursor:
reacting the solid acid catalyst with the vapor-phase peroxide precursor to form hydrogen peroxide;
receiving the hydrogen peroxide at a second chemical reporter of the chemical detector; and
detecting, by the chemical detector, a response of the second chemical reporter to the hydrogen peroxide to determine whether materials of interest are present.

Assignees

• Flir Detection Inc

Inventors

• Keen Steven
• Wald Lara
• Fisher Mark

Classifications

• G01N33/0057

  Warfare agents or explosives · CPC title

• G01N31/227 Primary

  for nitrates or nitrites · CPC title

• G01N31/10

  using catalysis · CPC title