Functionally graded cemented tungsten carbide with engineered hard surface and the method for making the same
US-8936750-B2 · Jan 20, 2015 · US
US10208366B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10208366-B2 |
| Application number | US-201615112002-A |
| Country | US |
| Kind code | B2 |
| Filing date | Feb 29, 2016 |
| Priority date | Mar 20, 2015 |
| Publication date | Feb 19, 2019 |
| Grant date | Feb 19, 2019 |
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A metal matrix composite tool that includes a hard composite portion comprising a reinforcement material infiltrated with a binder material, wherein the reinforcement material comprises a refractory metal component dispersed with reinforcing particles, wherein a surface roughness of the reinforcing particles is at least two times greater than the refractory metal component, wherein the refractory metal component has a failure strain of at least 0.05 and a shear modulus of 200 GPa or less, and wherein the reinforcing particles have a failure strain of 0.01 or less but at least five times less than the failure strain of the refractory metal component, and the reinforcing particles have a shear modulus of greater than 200 GPa and at least two times greater than the shear modulus of the refractory metal component. The reinforcing particles may comprise an intermetallic, a boride, a carbide, a nitride, an oxide, a ceramic, and/or a diamond.
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What is claimed is: 1. A metal matrix composite (MMC) tool, comprising: a hard composite portion that comprises a reinforcement material infiltrated with a binder material, wherein the reinforcement material comprises a refractory metal component dispersed with reinforcing particles, wherein a surface roughness of the reinforcing particles is at least two times greater than a surface roughness of the refractory metal component, wherein the refractory metal component has a failure strain of at least 0.05 and a shear modulus of 200 GPa or less, and wherein the reinforcing particles have a failure strain of 0.01 or less but at least five times less than the failure strain of the refractory metal component, and the reinforcing particles have a shear modulus of greater than 200 GPa and at least two times greater than the shear modulus of the refractory metal component. 2. The MMC tool of claim 1 , wherein the reinforcing particles comprise particles of a material selected from the group consisting of an intermetallic, a boride, a carbide, a nitride, an oxide, a ceramic, diamond, and any combination thereof. 3. The MMC tool of claim 1 , wherein the refractory metal component is selected from the group consisting of a refractory metal, a refractory metal alloy, and a combination of a refractory metal and a refractory metal alloy. 4. The MMC tool of claim 3 , wherein the refractory metal component has solidus temperature greater than 1500° F. and is selected from the group consisting of tungsten, rhenium, osmium, tantalum, molybdenum, niobium, iridium, ruthenium, hafnium, boron, rhodium, vanadium, chromium, zirconium, platinum, titanium, lutetium, palladium, thulium, scandium, iron, yttrium, erbium, cobalt, holmium, nickel, silicon, dysprosium, terbium, gadolinium, beryllium, manganese, copper, samarium, gold, neodymium, silver, germanium, praseodymium, lanthanum, calcium, europium, ytterbium, and any alloy thereof. 5. The MMC tool of claim 1 , wherein the refractory metal component is a tungsten metal powder and the reinforcing particles are a tungsten carbide powder. 6. The MMC tool of claim 1 , wherein the hard composite portion comprises the refractory metal component at a concentration ranging from between 1% and 40% by weight of the reinforcement material. 7. The MMC tool of claim 1 , wherein the reinforcement material is infiltrated with the binder material at a temperature greater than a liquidus temperature of the binder material but lower than a solidus temperature of the refractory metal component. 8. The MMC tool of claim 1 , wherein the hard composite portion further comprises one or more localized hard composite portions comprising the refractory metal component dispersed with the reinforcing particles at a concentration ranging between 80% and 100% by weight of reinforcement material. 9. The MMC tool of claim 1 , wherein a gradient of concentration of the refractory metal component progressively decreases in a direction through the hard composite portion. 10. The MMC tool of claim 1 , wherein the hard composite portion comprises a plurality of distinct layers of varying concentration of the refractory metal component. 11. A drill bit, comprising: a bit body; and a plurality of cutting elements coupled to an exterior of the bit body, wherein at least a portion of the bit body comprises a hard composite portion that comprises a reinforcement material infiltrated with a binder material, wherein the reinforcement material comprises a refractory metal component dispersed with reinforcing particles, wherein a surface roughness of the reinforcing particles is at least two times greater than a surface roughness of the refractory metal component, wherein the refractory metal component has a failure strain of at least 0.05 and a shear modulus of 200 GPa or less, and wherein the reinforcing particles have a failure strain of 0.01 or less and at least five times less than the failure strain of the refractory metal component, and the reinforcing particles have a shear modulus of greater than 200 GPa and at least two times greater than the shear modulus of the refractory metal component. 12. The drill bit of claim 11 , wherein the refractory metal component is selected from the group consisting of a refractory metal, a refractory metal alloy, and a combination of a refractory metal and a refractory metal alloy. 13. The drill bit of claim 11 , wherein the refractory metal component is a tungsten metal powder or tungsten alloy powder and the reinforcement material is a tungsten carbide powder. 14. The drill bit of claim 11 , wherein the hard composite portion comprises the refractory metal component at a concentration ranging from between 1% and 40% by weight of the reinforcement material. 15. The drill bit of claim 11 , wherein the refractory metal component and the reinforcement material are infiltrated with the binder material at a temperature greater than a melting point of the binder material but lower than a solidus temperature of the refractory metal component. 16. The drill bit of claim 11 , wherein the hard composite portion further comprises one or more localized hard composite portions comprising the refractory metal component dispersed with the reinforcing particles at a concentration ranging between 80% and 100% by weight of reinforcement material. 17. The drill bit of claim 11 , wherein a gradient of concentration of the refractory metal component progressively decreases in a direction through the hard composite portion. 18. The drill bit of claim 11 , wherein the hard composite portion comprises a plurality of distinct layers of varying concentration of the refractory metal component. 19. A drilling assembly, comprising: a drill string extendable from a drilling platform and into a wellbore; a drill bit attached to an end of the drill string; and a pump fluidly connected to the drill string and configured to circulate a drilling fluid to the drill bit and through the wellbore, wherein the drill bit comprises a bit body and a plurality of cutting elements coupled to an exterior of the bit body, and wherein at least a portion of the bit body comprises a hard composite portion that comprises a reinforcement material infiltrated with a binder material, wherein the reinforcement material comprises a refractory metal component dispersed with reinforcing particles, wherein a surface roughness of the reinforcing particles is at least two times greater than a surface roughness of the refractory metal component, wherein the refractory metal component has a failure strain of at least 0.05 and a shear modulus of 200 GPa or less, and wherein the reinforcing particles have a failure strain of 0.01 or less and at least five times less than the failure strain of the refractory metal component, and the reinforcing particles have a shear modulus of greater than 200 GPa and at least two times greater than the shear modulus of the refractory metal component. 20. The drilling assembly of claim 19 , wherein the reinforcing particles comprise particles of a material selected from the group consisting of an intermetallic, a boride, a carbide, a nitride, an oxide, a ceramic, diamond, and any combination thereof, and wherein the refractory metal component is selected from the group consisting of a refractory metal, a refractory metal alloy, and a combination of a refractory metal and a refractory metal alloy.
Metallic powder containing lubricating or binding agents; Metallic powder containing organic material · CPC title
only carbides · CPC title
starting from a melt · CPC title
Refractory metals · CPC title
the bit being of the rotary drag type, e.g. fork-type bits · CPC title
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