High performance lubricating compositions

Patent metadata

Field	Value
Publication number	US-10208265-B2
Application number	US-201816026419-A
Country	US
Kind code	B2
Filing date	Jul 3, 2018
Priority date	Jan 7, 2015
Publication date	Feb 19, 2019
Grant date	Feb 19, 2019

Abstract

An oleaginous corrosion-resistant lubricating composition comprising at least one poly-alpha olefin synthetic oil and effective amounts of metal salts of sulfonic acids, metal salts of carboxylic acids, metal salts of mixtures of said sulfonic and carboxylic acids, alkylated aromatic stabilizers as solubility modifiers, pour-point depressants, at least one antioxidant, triazole deactivator compounds and fluoroacrylate copolymers.

First claim

The invention claimed is:

1. A corrosion-preventing free-flowing lubricating composition consisting essentially of, in parts by weight of:
60 to 80 parts of two different poly-alpha olefin synthetic lubricating oils,
7.0 to 15 parts of at least one oil soluble corrosion inhibitor selected from the group consisting of sulfonic acid metal salts, carboxylic acid metal salts and salts derived from the stoichiometric reaction of mixtures of sulfonic acids and carboxylic acids with metal compounds forming a complex of the acid salts,
10 to 14 parts of at least one oil soluble alkylated aromatic stabilizer,
1.0 to 3.0 parts of a pour-point depressant selected from the group consisting of heavy-paraffinic compounds and acrylic polymers,
1.0 to 1.6 parts of at least one oil soluble antioxidant, selected from the group consisting of aryl amines and carbamates,
0.1 to 0.2 parts of a triazole deactivator and 0.5 to 1.5 parts of a fluoroacrylate copolymer.

2. A corrosion-preventing free-flowing lubricating composition consisting essentially of from about, in parts by weight,
60 to 80 parts of a poly-alpha olefin synthetic lubricating oil,
7.0 to 15 parts of a carboxylic acid metal salt,
10 to 14 parts of an oil soluble alkylated aromatic stabilizer,
1.0 to 3.0 parts of a pour-point depressant consisting of a heavy-paraffinic compound,
1.0 to 1.6 parts of an oil soluble aryl amine antioxidant, 0.1 to 0.2 parts of a triazol deactivator and 0.5 to 1.5 parts of a fluoroacrylate copolymer.

3. A corrosion-preventing free-flowing lubricating composition consisting essentially of from about, in parts by weight,
60 to 80 parts of a poly-alpha olefin synthetic lubricating oil,
7.0 to 15 parts of a complex salt derived from the stoichiometric reaction of a sulfonic acid and a carboxylic acid with a metal compound,
10 to 14 parts of an oil soluble alkylated aromatic stabilizer compound,
1.0 to 3.0 parts of a pour-point depressant consisting of a heavy-paraffinic compound,
1.0 to 1.6 parts of an oil soluble aryl amine antioxidant, 0.1 to 0.2 parts of a trizaole deactivator and 0.5 to 1.5 parts of a fluoroacrylate copolymer.

4. The composition of claim 1 wherein the free-flowing lubricant is a mixture of poly-alpha olefin oils having different viscosities and boiling points.

5. The composition of claim 1 wherein the free-flowing lubricant is a mixture of poly-alpha olefin lubricating oils having kinematic viscosity of 1,900 at −40° C.

6. The composition of claim 1 wherein the pour-point depressant consists of hydrated distillate heavy-paraffinic compounds.

7. The composition of claim 1 wherein the sulfonic acid compound is an alkaline earth metal salt of a dialkylnaphthalene sulfonic acid.

8. The composition of claim 7 wherein the dialkylnaphthalene sulfonic acid is a dialkylnaphthalene sulfonic acid metal compound wherein the alkyl group of said sulfonic acid has one to twelve carbon atoms.

9. The composition of claim 1 wherein the pour-point is an acrylic copolymer.

10. A process of preventing corrosion of metal which comprises applying an effective amount of a corrosion-preventing free-flowing lubricating composition on said metal; said composition consisting essentially of, in parts by weight,
60 to 80 parts of two different poly-alpha olefin synthetic lubricating oils,
7.0 to 15 parts of at least one oil soluble corrosion inhibitor selected from the group consisting of sulfonic acid metal salts, carboxylic acid metal salts and acid salts derived from the stoichiometric reaction of mixtures of a sulfonic acid and a carboxylic acid with a metal compound forming a complex of the said acid salts,
10 to 14 parts of an oil soluble alkylated-aromatic stabilizer,
1.0 to 3.0 parts of a pour-point depressant selected from the group consisting of heavy-paraffinic compounds and acrylic copolymers,
1.0 to 1.6 parts of at least one oil soluble antioxidant selected from the group consisting of aryl amines and carbamates, 0.1 to 0.2 parts of a triazole deactivator and 0.5 to 1.5 parts of a fluoroacrylate copolymer.

11. The process of claim 10 wherein the poly-alpha olefin synthetic oils are a mixture of synthetic oils having different viscosities and boiling points.

12. The process of claim 11 wherein the pour-point is a hydrotreated distillate heavy paraffinic compound.

13. The process of claim 10 wherein the corrosion inhibitor is an alkaline earth metal salt of an alkylnapthalene sulfonic acid.

14. The process of claim 10 wherein the corrosion inhibitor is an alkaline earth carboxylic acid metal salt.

15. The process of claim 10 wherein the pour-point is a polymethacrylic acid copolymer.

16. The process of claim 10 wherein the antioxidant is diphenylamine.

17. The process of claim 10 wherein the lubricating composition has a viscosity of 1,900 at −40° C.

18. A corrosion-preventing lubricating composition consisting essentially of:

Parts by Weight

Poly-Alpha Olefin-Synthetic Fluid Base Oil
30-40

(1-Decene, Dimer homopolymer, hydrogenated)

Poly-Alpha Olefin-Synthetic Fluid Base Oil
30-40

(1-Decene, homopolymer, hydrogenated)

Acrylic Copolymer
1.0-3.0

(Pour-Point Depressant)

Calcium Dinonylnaphthalenesulfonate/
5-9

Carboxylate (Corrosion Inhibitor)

Calcium Alkylnaphthalenesulfonates
2-6

Alkylated Aromatic Additive, Stabilizer
10-14

Nonylated Diphenylamine, Antioxidant
0.4-0.6

Butylated, Octylated Diphenylamine,
0.2-0.4

Antioxident

Methylene-bis-(dibutyldithiocarbamate,
0.4-0.6

Antioxidant

Benzotriazole
0.1-0.2

Fluoroacrylate Copolymer
 0.5-1.5.

Assignees

• Arafat El Sayad
• Us Navy

Inventors

• Arafat El Sayad

Classifications

• C10M2203/06

  Well-defined aromatic compounds · CPC title

• C10M2209/084

  Acrylate; Methacrylate · CPC title

• C10M2207/10

  Carboxylix acids; Neutral salts thereof · CPC title

• C10N2030/02

  Pour-point; Viscosity index · CPC title

• C10M2219/066

  Thiocarbamic type compounds · CPC title