Fluoropolymer coatings comprising aziridine compounds

Patent metadata

Field	Value
Publication number	US-10208223-B2
Application number	US-201815953120-A
Country	US
Kind code	B2
Filing date	Apr 13, 2018
Priority date	Nov 7, 2013
Publication date	Feb 19, 2019
Grant date	Feb 19, 2019

Abstract

In another embodiment, an article is described comprising a substrate wherein a surface of the substrate comprises a coating comprising fluoropolymer particles; and a reaction product of at least one aziridine compound comprising at least two aziridine groups or at least one aziridine group and at least one alkoxy silane group. The coating can be utilized as a primer for bonding a non-fluorinated substrate to a fluoropolymer film and/or the coating can be used as an (e.g. outer exposed) surface layer. In some embodiments, the article may be the (e.g. backside) film of a photovoltaic module.

First claim

What is claimed is:

1. A fluoropolymer coating composition comprising:
an aqueous liquid medium;
fluoropolymer particles dispersed in the aqueous liquid medium, wherein the fluoropolymer particles comprise at least 60 wt. % fluorine and reactive functionality derived from inclusion of a cure-site monomer, wherein the reactive functionality is selected from Br, I, or nitrile; and
at least one aziridine compound comprising at least two aziridine groups.

2. The fluoropolymer coating composition of claim 1 wherein the aqueous liquid medium is basic.

3. The fluoropolymer coating composition of claim 1 further comprising inorganic oxide nanoparticles.

4. The fluoropolymer coating composition of claim 3 wherein the inorganic oxide nanoparticles comprise silica, clay, or a mixture thereof.

5. The fluoropolymer coating composition of claim 3 wherein the inorganic oxide nanoparticles have an average particle size of less than 100 nm.

6. The fluoropolymer coating composition of claim 1 wherein the aziridine compound has the general structure:

wherein R is a core moiety having a valency of Y;
L is a bond, a divalent atom, or a divalent linking group;
R1, R2, R3, and R4 are independently hydrogen or a C1-C4 alkyl; and
Y ranges from 2 to 6.

7. The fluoropolymer coating composition of claim 6 wherein R-L is a residue of a multi(meth)acrylate compound.

8. The fluoropolymer coating composition of claim 6 wherein the aziridine compound is free of hydrolyzable groups.

9. The fluoropolymer coating composition of claim 1 wherein the fluoropolymer comprises 15 to 35 mole-% of monomeric units derived from VF, VDF or a combination thereof; at least 45 mole-% of monomeric units derived from TFE; and
monomeric units derived from HFP.

10. The fluoropolymer coating composition of claim 1 wherein the fluoropolymer comprises at least 50 mole-% of monmeric units derived from VF, VDF or a combination.

11. The fluoropolymer coating composition of claim 1 wherein the fluoropolymer comprises at least 50 mole-% of monomeric units derived from TFE and repeat units derived from alkyl vinyl ether.

12. The fluoropolymer coating composition of claim 1 wherein the fluoropolymer comprises at least 45 mole-% of monomeric units derived from TFE and monomeric units derived from perfluoroalkyl vinyl ether.

13. The fluoropolymer coating of claim 1 further comprising surfactants, pigments including TiO 2 , and light stabilizers.

14. A coated substrate comprising a substrate wherein a surface of the coated substrate comprises a dried coating composition according to claim 1 .

15. The coated substrate of claim 14 wherein the substrate in is an inorganic or organic substrate.

16. A photovoltaic module comprising a backside film, the backside film comprising:
a substrate wherein a surface of the substrate comprises a coating comprising fluoropolymer particles, wherein the fluoropolymer particles comprise at least 60 wt. % fluorine and reactive functionality derived from inclusion of a cure-site monomer, wherein the reactive functionality is selected from Br, I, or nitrile; and
wherein the fluoropolymer is cured as a result of reaction between the reactive functionality of the fluoropolymer and at least one aziridine compound comprising at least two aziridine groups.

17. The photovoltaic module of claim 16 wherein the coating is a primer having a thickness ranging from 0.1 mils to 1 mil.

18. The photovoltaic module of claim 16 wherein a fluoropolymer layer lacking fluoropolymer particles is disposed on the primer.

19. The photovoltaic module of claim 16 wherein the coating is a backside coating that is exposed on the outer surface layer having a thickness ranging from 0.2 to 10 mils.

20. The fluoropolymer coating composition of claim 1 wherein the coating composition comprising non-fluorinated polymer binder in an amount no greater than 5 wt. %.

Assignees

• 3M Innovative Properties Co

Inventors

• Jing Naiyong
• Lochhaas Kai H
• Hamer Kevin M
• Blong Thomas J
• Fletcher Timothy D
• Yu Zhigang
• Juergens Michael

Classifications

• C08K3/346

  Clay · CPC title

• C09D127/22 Primary

  modified by chemical after-treatment · CPC title

• C08K5/5442

  Chemistry & Metallurgy · mapped topic

• H01L31/049

  Electricity · mapped topic

• C09D7/61 Primary

  inorganic · CPC title