Method and apparatus for separating alkyl aromatic hydrocarbon

Patent metadata

Field	Value
Publication number	US-10207967-B2
Application number	US-201715713972-A
Country	US
Kind code	B2
Filing date	Sep 25, 2017
Priority date	Jun 29, 2012
Publication date	Feb 19, 2019
Grant date	Feb 19, 2019

Abstract

A method for separating an alkyl aromatic hydrocarbon, the method having a step of adding a first diluent and an extractant having a superacid to a mixture comprising the alkyl aromatic hydrocarbon and one or more isomers thereof to carry out an acid-base extraction to thereby form a complex of the alkyl aromatic hydrocarbon with the superacid, and thereafter separating the complex from the mixture, and a step of adding an eliminating agent having a relative basicity in a range of 0.06 to 10 with respect to the alkyl aromatic hydrocarbon and a second diluent to the complex, and carrying out complex exchange of the alkyl aromatic hydrocarbon for the eliminating agent to thereby separate the alkyl aromatic hydrocarbon from the complex.

First claim

The invention claimed is:

1. An apparatus for separating an alkyl aromatic hydrocarbon comprising: an acid-base extraction column; and a complex exchange column,
wherein the acid-base extraction column comprises: a pipe for feeding a mixture comprising an alkyl aromatic hydrocarbon and one or more isomers thereof; a pipe for feeding a first diluent; a pipe for feeding a complex solution of an eliminating agent and a superacid withdrawn from a column bottom of the complex exchange column; a pipe for discharging the alkyl aromatic hydrocarbon as a complex solution of the alkyl aromatic hydrocarbon and the superacid from a column bottom of the acid-base extraction column; and a pipe for discharging a mixed liquid comprising the eliminating agent separated by the complex exchange, unextracted extraction residual isomers, and the diluent from a column top of the acid-base extraction column, and
wherein the complex exchange column comprises: a pipe for feeding the complex solution of the alkyl aromatic hydrocarbon and the superacid discharged from the column bottom of the acid-base extraction column; a pipe for feeding a second diluent and the eliminating agent; a pipe for discharging a mixed liquid comprising the extracted alkyl aromatic hydrocarbon, the eliminating agent and the diluent from a column top of the complex exchange column; and a pipe for discharging a complex solution of the eliminating agent and the superacid after the complex exchange has been carried out from the column bottom of the complex exchange column.

2. The apparatus according to claim 1 , wherein the pipe for feeding the second diluent and the eliminating agent is separated into a pipe for feeding the second diluent and a pipe for feeding the eliminating agent.

3. The apparatus according to claim 1 , wherein in the complex exchange column, the complex solution of the alkyl aromatic hydrocarbon and the superacid fed, and the fed mixed solution of the second diluent and the eliminating agent are brought into countercurrent contact.

4. The apparatus according to claim 1 , further comprising a distillation column to distill the mixed liquid comprising the alkyl aromatic hydrocarbon, the eliminating agent and the diluent discharged from the complex exchange column to thereby separate the alkyl aromatic hydrocarbon, the eliminating agent and the diluent.

5. The apparatus according to claim 1 , further comprising a distillation column to distill the mixed liquid comprising the eliminating agent, the unextracted extraction residual isomers and the diluent discharged from the acid-base extraction column to thereby separate the eliminating agent, the extraction residual isomers and the diluent.

Assignees

• Mitsubishi Gas Chemical Co

Inventors

• Nishiuchi Junya
• Nagao Shinichi
• Tanaka Yoshitaka
• Kitamura Mitsuharu
• Oka Hiroaki

Classifications

• B01D11/043

  with stationary contacting elements, sieve plates or loose contacting elements · CPC title

• C07C7/152

  by forming adducts or complexes · CPC title

• C07C7/04

  by distillation · CPC title

• C07C7/10 Primary

  by extraction, i.e. purification or separation of liquid hydrocarbons with the aid of liquids · CPC title

• B01D11/04

  of solutions which are liquid · CPC title