Process for co-producing C3 olefins, iC4 olefins, nC4 olefins and diolefins, and/or C5 olefins and diolefins

Patent metadata

Field	Value
Publication number	US-10207965-B2
Application number	US-201816028507-A
Country	US
Kind code	B2
Filing date	Jul 6, 2018
Priority date	Dec 10, 2014
Publication date	Feb 19, 2019
Grant date	Feb 19, 2019

Abstract

Processes and systems for producing olefins, including: dehydrogenating a first n-alkane to produce a first effluent; and dehydrogenating at least one of a first isoalkane or a second n-alkane to produce a second effluent. The first and second effluents may be compressed and fed to a common separation train to separate the effluents into two or more fractions. In some embodiments, each of the first and second dehydrogenation reaction zones may include two reactors, one reactor in each of the reaction zones operating in a dehydrogenation cycle, one operating in a regeneration cycle, and one operating in a purge or evacuation/reduction cycle. Operation of the reactors in the dehydrogenation cycle is staggered, such that the purge cycle, regeneration cycle, or evacuation/reduction cycle of the reactors may not overlap.

First claim

What is claimed:

1. A process for producing olefins, comprising:
dehydrogenating a first n-alkane in a first dehydrogenation reaction zone comprising at least four reactors to produce a first effluent comprising at least one of a first n-olefin or a first diolefin;
dehydrogenating at least one of a first isoalkane or a second n-alkane in a second dehydrogenation reaction zone comprising at least four reactors to produce a second effluent comprising at least one of a first isoolefin, a second n-olefin, or a second diolefin;
operating each reactor in a cyclic operation with sequential steps including a dehydrogenation cycle, a purge cycle, a regeneration cycle, and an evacuation/reduction cycle; and
controlling the operation of the reactors in the dehydrogenation cycle in a staggered fashion such that, in each of the first and second dehydrogenation reaction zones, no two reactors are in the purge cycle at the same time, no two reactors are in the evacuation/reduction cycle at the same time, no two reactors are in the regeneration cycle at the same time, and no more than two reactors are in the dehydrogenation cycle at the same time;
compressing the first effluent;
compressing the second effluent;
feeding the first and second effluents to a common separation train to separate the first and second effluents into two or more fractions.

2. The process of claim 1 , further comprising:
dehydrogenating at least one of a second isoalkane or a third n-alkane in a third dehydrogenation reaction zone comprising at least four reactors to produce a third effluent comprising at least one of a second isoolefin, a third n-olefin, or a third diolefin;
controlling the operation of the reactors in the dehydrogenation cycle in a staggered fashion such that, in the third dehydrogenation reaction zone, no two reactors are in the purge cycle at the same time, no two reactors are in the evacuation/reduction cycle at the same time, no two reactors are in the regeneration cycle at the same time, and no more than two reactors are in the dehydrogenation cycle at the same time;
compressing the third effluent;
feeding the third effluent to the common separation train to separate the first, second, and third effluents into three or more fractions.

3. The process of claim 2 , wherein inclusive of the first, second, and third dehydrogenation reaction zone, no more than six reactors are in the dehydrogenation cycle.

4. The process of claim 2 , wherein inclusive of the first, second, and third dehydrogenation reaction zone, no more than three reactors are in the purge cycle.

5. The process of claim 2 , wherein inclusive of the first, second, and third dehydrogenation reaction zone, no more than three reactors are in the evacuation/reduction cycle.

6. The process of claim 2 , wherein inclusive of the first, second, and third dehydrogenation reaction zone, no more than three reactors are in the regeneration cycle.

7. The process of claim 2 , further comprising recycling at least one of the three or more fractions to at least one of the first, second, or third dehydrogenation reaction zones.

8. The process of claim 2 , further comprising recovering heat from at least one of the first effluent, the second effluent, and the third effluent.

9. The process of claim 1 , further comprising:
combining an effluent comprising steam and hydrocarbons from a reactor in a purge cycle with the second effluent;
separating the steam from the hydrocarbons in the purge effluent and the second effluent.

10. The process of claim 9 , wherein the separating the steam comprises condensing the steam in a compressor inter-stage cooler.

11. The process of claim 9 , further comprising removing condensation in a downstream product compressor inter-stage cooler.

12. The process of claim 1 , further comprising recycling at least one of the two or more fractions to at least one of the first or second dehydrogenation reaction zones.

13. The process of claim 1 , wherein the two or more fractions include a fraction comprising isobutene and isobutane, the process further comprising:
etherifying at least a portion of the isobutene; and
separating ethers from the isobutane.

14. The process of claim 1 , further comprising recovering heat from at least one of the first effluent and the second effluent.

Assignees

• Lummus Technology Inc
• Lummus Technology Inc

Inventors

• Schwint Kevin John
• Brummer Robert John

Classifications

• C07C5/333 Primary

  Catalytic processes · CPC title

• B01J2208/021

  comprising a plurality of beds with flow of reactants in parallel · CPC title

• B01J2208/00008

  Controlling the process · CPC title

• B01J8/02

  with stationary particles, e.g. in fixed beds · CPC title