Systems and methods for measuring particle accumulation on reactor surfaces

Patent metadata

Field	Value
Publication number	US-10207237-B2
Application number	US-201715659243-A
Country	US
Kind code	B2
Filing date	Jul 25, 2017
Priority date	Jul 16, 2010
Publication date	Feb 19, 2019
Grant date	Feb 19, 2019

Abstract

Systems and methods for monitoring a particle/fluid mixture are provided. The method can include flowing a mixture comprising charged particles and a fluid past a particle accumulation probe. The method can also include measuring electrical signals detected by the probe as some charged particles pass the probe without contacting the probe while other charged particles contact the probe. The measured electrical signals can be manipulated to provide an output. The method can also include determining from the output if the charged particles contacting the probe have, on average, a different charge than the charged particles that pass the probe without contacting the probe.

First claim

What is claimed is:

1. A method for monitoring a particle/fluid mixture, comprising:
flowing a mixture comprising charged particles and a fluid past a particle accumulation probe;
measuring electrical signals detected by the probe as some charged particles pass the probe without contacting the probe while other charged particles contact the probe;
manipulating the measured electrical signal to provide an output wherein manipulating the measured electrical signal includes using an absolute autocorrelation method that correlates mean centered data using an approaching curve indicating a charge on particles that approach the probe, a leaving curve indicating a charge on particles that pass and move away from the probe, and a zero-lag peak that indicates the charge on the particles that contact the probe to provide the output; and
determining from the output if the charged particles contacting the probe have, on average, a different charge than the charged particles that pass the probe without contacting the probe.

2. The method of claim 1 , wherein the charged particles comprise catalyst particles and polymer particles, and wherein the fluid comprises one or more hydrocarbons.

3. The method of claim 1 , wherein the charged particles comprise primarily polymer particles having, on average, a negative charge and a minority of catalyst particles having, on average, a positive charge, wherein the output indicates the charged particles contacting the probe are, on average, negatively charged polymer particles, and wherein the output indicates that catalyst particles are not segregating out of the mixture in an amount sufficient to cause the formation of agglomerations.

4. The method of claim 1 , wherein the charged particles comprise primarily polymer particles having, on average, a negative charge and a minority of catalyst particles having, on average, a positive charge, wherein the output indicates the charged particles contacting the probe are, on average, positively charged catalyst particles, and wherein the output indicates that the catalyst particles are segregating out of the mixture in an amount sufficient to cause the formation of agglomerations.

5. The method of claim 1 , wherein the charged particles comprise primarily polymer particles having, on average, a positive charge and a minority of catalyst particles having, on average, a negative charge, wherein the output indicates the charged particles contacting the probe are, on average, positively charged polymer particles, and wherein the output indicates that catalyst particles are not segregating out of the mixture in an amount sufficient to cause the formation of agglomerations.

6. The method of claim 1 , wherein the charged particles comprise primarily polymer particles having, on average, a positive charge and a minority of catalyst particles having, on average, a negative charge, wherein the output indicates the charged particles contacting the probe are, on average, negatively charged catalyst particles, and wherein the output indicates that the catalyst particles are segregating out of the mixture in an amount sufficient to cause the formation of agglomerations.

7. The method of claim 1 , wherein the charged particles comprise catalyst particles, and said catalyst particles comprise one or more metallocene catalysts.

8. The method of claim 1 , wherein the flowing mixture is located within a polymerization system.

9. The method of claim 1 , wherein the flowing mixture is located within a cycle line of a gas phase polymerization reactor.

10. The method of claim 1 , wherein the particle accumulation probe is in communication with an internal volume of a polymerization reactor or a cycle line of the polymerization reactor.

11. The method of claim 1 , further comprising altering one or more process parameters if the charged particles contacting the probe have, on average, a positive charge.

12. The method of claim 1 , further comprising introducing one or more continuity additives to the mixture if the charged particles contacting the probe have, on average, a negative charge.

13. The method of claim 1 , wherein manipulating the measured electrical signal is carried out using a processor.

14. The method of claim 1 , wherein the electrical signal is measured at a sampling frequency of about 100 Hz or more.

Assignees

• Univation Tech Llc

Inventors

• Markel Eric J

Classifications

• C08F2400/02

  Control or adjustment of polymerization parameters · CPC title

• B01J8/388

  externally, i.e. the particles leaving the vessel and subsequently re-entering it · CPC title

• B01J2219/00198

  at the reactor inlet · CPC title

• C08F2500/24

  Polymer with special particle form or size · CPC title

• B01J2219/0245

  of synthetic organic material · CPC title