Fuel cell electrode assembly

Patent metadata

Field	Value
Publication number	US-10205186-B2
Application number	US-201214413410-A
Country	US
Kind code	B2
Filing date	Jul 10, 2012
Priority date	Jul 10, 2012
Publication date	Feb 12, 2019
Grant date	Feb 12, 2019

Abstract

An exemplary fuel cell electrode assembly includes a membrane. A first electrode is on the first side of the membrane. A second electrode is on a second side of the membrane. A first gas diffusion layer is adjacent the first electrode. At least a portion of the first gas diffusion layer is at least partially impregnated by a first plastic material that bonds the portion of the first gas diffusion layer to the first electrode. A second gas diffusion layer is adjacent the second electrode. At least a portion of the second gas diffusion layer is at least partially impregnated by a second plastic material that bonds the second gas diffusion layer to the second electrode. A third plastic material is between at least one of the gas diffusion layers and the adjacent electrode for electrically isolating the first gas diffusion layer from the second gas diffusion layer.

First claim

I claim:

1. A fuel cell electrode assembly, comprising
a membrane that includes outer edges that define an outer periphery of the membrane;
a first electrode on a first side of the membrane;
a second electrode on a second side of the membrane;
a first gas diffusion layer adjacent the first electrode, at least a portion of the first gas diffusion layer being at least partially impregnated by a first plastic material that bonds the portion of the first gas diffusion layer to the first electrode;
a second gas diffusion layer adjacent the second electrode, at least a portion of the second gas diffusion layer being at least partially impregnated by a second plastic material that bonds the second gas diffusion layer to the second electrode; and
a third plastic material between at least one of the gas diffusion layers and the adjacent electrode for electrically isolating the first gas diffusion layer from the second gas diffusion layer, the third plastic material embedded in the second plastic material such that at least a portion of the second plastic material is situated between the third plastic material and the adjacent electrode, the third plastic material having a width that is smaller than a width of the second plastic material and having outer edges that define an outer periphery of the third plastic material, the outer edges of the membrane being offset outwardly beyond the outer edges of the third plastic material.

2. The fuel cell electrode assembly of claim 1 , wherein the third plastic material is different than the first and second plastic materials.

3. The fuel cell electrode assembly of claim 2 , wherein
the first and second plastic materials have a melting temperature; and
the third plastic material has a melting temperature that is higher than the melting temperature of the first and second plastic materials.

4. The fuel cell electrode assembly of claim 2 , wherein
the first and second plastic materials comprise a low density polyethylene; and
the third plastic material comprises a linear low density polyethylene.

5. The fuel cell electrode assembly of claim 1 , wherein the third plastic material is fully encapsulated in the second plastic material.

6. The fuel cell electrode assembly of claim 5 wherein an outer lateral edge of the second plastic material is coextensive with an outer lateral edge of the membrane.

7. The fuel cell electrode assembly of claim 1 , wherein
the third plastic material is between the second gas diffusion layer and the second electrode;
the portion of the second gas diffusion layer, which is at least partially impregnated by the second plastic material, has a width in a direction along a plane of the second gas diffusion layer; and
the third plastic material has a width in the direction that is less than the width of the portion of the second gas diffusion layer.

8. The fuel cell electrode assembly of claim 1 , wherein
the first plastic material seals an interface between the first electrode and the portion of the first gas diffusion layer;
the first plastic material establishes a barrier along an outer periphery of the first gas diffusion layer for resisting fluid movement across the outer periphery of the first gas diffusion layer;
the second plastic material seals an interface between the second electrode and the portion of the second gas diffusion layer; and
the second plastic material establishes a barrier along an outer periphery of the second gas diffusion layer for resisting fluid movement across the outer periphery of the second gas diffusion layer.

9. A fuel cell electrode assembly, comprising:
a membrane that includes outer edges that define an outer periphery of the membrane;
a pair of opposing electrodes, each electrode positioned on a respective side of the membrane;
a pair of opposing gas diffusion layers, each gas diffusion layer positioned adjacent a respective one of the electrodes on a side opposite of the membrane,
wherein each gas diffusion layer is at least partially impregnated by a respective bonding structure to bond the gas diffusion layer to the respective one of the electrodes, and
wherein at least one of the bonding structures comprises a frame of plastic material that is fully encapsulated by other plastic material such that the frame of plastic material is isolated from the electrode by the other plastic material, the frame of plastic material including outer edges that define an outer periphery of the frame, and
wherein the outer edges of the membrane are offset outwardly beyond the outer edges of the frame.

10. The fuel cell electrode assembly of claim 9 , wherein the frame of plastic material has a width smaller than a width of the other plastic material that fully encapsulates the frame of plastic material.

11. The fuel cell electrode assembly of claim 9 , wherein an outer lateral end of the other plastic material is coplanar with an outer lateral end of the membrane.

12. A method of making a fuel cell electrode assembly, comprising:
situating a first plastic material between a first gas diffusion layer and a first electrode;
situating a second plastic material between a second gas diffusion layer and a second electrode;
situating a membrane between the first gas diffusion layer and the second gas diffusion layer, the membrane having outer edges that define an outer periphery of the membrane;
situating a third plastic material between at least the second gas diffusion layer and the second electrode, the third plastic material having a width which is smaller than a width of the second plastic material and having outer edges that define an outer periphery of the third plastic material, the outer edges of the membrane being offset outwardly beyond the outer edges of the third plastic material;
melting the first plastic material such that the first plastic material at least partially impregnates a portion of the first gas diffusion layer and secures the first gas diffusion layer to the first electrode; and
melting the second plastic material such that the second plastic material at least partially impregnates a portion of the second gas diffusion layer and secures the second gas diffusion layer to the second electrode with the third plastic material between the second electrode and the second gas diffusion layer and embedded in the second plastic material for electrically isolating the second gas diffusion layer from the first gas diffusion layer, wherein at least a portion of the second plastic material is situated between the third plastic material and the second electrode.

13. The method of claim 12 , comprising:
situating the plastic materials, the gas diffusion layers and the electrodes within a press;
applying a pressing force to at least the plastic materials and the gas diffusion layers within the press;
heating the plastic materials sufficiently to at least partially melt the first and second plastic materials while the plastic materials are subject to the pressing force; and
cooling the plastic materials subsequent to the heating while the plastic materials are subject to the pressing force.

14. The method of claim 13 , comprising heating the plastic materials to a temperature that is at least a melting temperature of the first and second plastic materials and less than a melting temperature of the third plastic material.

15. The method of claim 14 , comprising softening the third plastic material without melting the third plastic material.

16. The method of claim 13 , comprising
layering the gas diffusion layers, the plastic materials and the electrodes such that
at least on

Assignees

• Vicino Jr Thomas F
• Audi Ag

Inventors

• Vicino Jr Thomas F

Classifications

• H01M8/0284

  Organic resins; Organic polymers · CPC title

• H01M8/0282

  Inorganic material · CPC title

• H01M8/028

  Sealing means characterised by their material · CPC title

• H01M8/023 Primary

  Porous and characterised by the material · CPC title

• H01M8/1004 Primary

  characterised by membrane-electrode assemblies [MEA] (H01M8/12 takes precedence) · CPC title