Liquid crystal display device

Patent metadata

Field	Value
Publication number	US-10203558-B2
Application number	US-201515507084-A
Country	US
Kind code	B2
Filing date	Aug 24, 2015
Priority date	Aug 29, 2014
Publication date	Feb 12, 2019
Grant date	Feb 12, 2019

Abstract

The present invention provides a liquid crystal display device that maintains a sufficient voltage holding ratio over a long period of time even when a liquid crystal panel having a narrower frame is used and that undergoes no burn-in or no stains on a display screen. The liquid crystal display device of the present invention includes an active-matrix liquid crystal panel and a backlight, wherein the liquid crystal panel includes a liquid crystal layer, a pair of substrates between which the liquid crystal layer is sandwiched, alignment layers disposed on surfaces of the pair of substrates facing the liquid crystal layer, and a seal part that bonds the pair of substrates to each other and that is disposed around the liquid crystal layer, and the liquid crystal panel is formed by a liquid crystal one-drop fill process, wherein the liquid crystal layer includes a liquid crystal material and at least one of a radical scavenger and an antioxidant, and the seal part has a width of 0.6 mm or less at least in part.

First claim

The invention claimed is:

1. A liquid crystal display device comprising an active-matrix liquid crystal panel and a backlight,
wherein the liquid crystal panel comprises a liquid crystal layer, a pair of substrates between which the liquid crystal layer is sandwiched, alignment layers disposed on surfaces of the pair of substrates facing the liquid crystal layer, and a seal part that bonds the pair of substrates to each other and that is disposed around the liquid crystal layer, and
the liquid crystal panel is formed by a liquid crystal one-drop fill process,
wherein the liquid crystal layer comprises a liquid crystal material and at least one of a radical scavenger and an antioxidant,
wherein the radical scavenger comprises a compound represented by formula (1):

wherein X represents a monovalent organic group, and R represents a hydrocarbon group, and
the antioxidant comprises a compound represented by formula (2):

wherein X represents a monovalent organic group, and
wherein the alignment layers are photo-alignment layers formed of a photo-alignable material, and

the photo-alignment layer is a polymer obtained by polymerizing a monomer comprising an acid anhydride represented by formula (3):

wherein hydrogen may be substituted, and
the seal part has a width of 0.6 mm or less at least in part.

2. The liquid crystal display device according to claim 1 , wherein the seal part is formed from a photocurable material comprising a photopolymerization initiator.

3. The liquid crystal display device according to claim 1 , wherein the seal part has a width of 0.4 mm or less at least in part.

4. The liquid crystal display device according to claim 3 , wherein the seal part has a width of 0.2 mm or less at least in part.

5. The liquid crystal display device according to claim 1 , wherein at least one component of the liquid crystal material is a compound having an alkenyl structure.

6. The liquid crystal display device according to claim 5 , wherein the compound having an alkenyl structure is a compound represented by formula (4-1), (4-2), or (4-3):

wherein m and n are the same or different integers.

7. The liquid crystal display device according to claim 1 , wherein at least one component of the liquid crystal material is a compound comprising an alkoxy structure.

8. The liquid crystal display device according to claim 7 , wherein the compound comprising an alkoxy structure is a compound represented by formula (5-1), (5-2), (5-3), (5-4), or (5-5):

wherein m and n are the same or different integers.

9. The liquid crystal display device according to claim 1 , wherein the liquid crystal panel further comprises, on surfaces of the alignment layers facing the liquid crystal layer, a layer comprising a polymer obtained by polymerizing a photophlymerizable monomer represented by formula (6):
A1-Y-A2  (6)

wherein Y represents a structure comprising at least one benzene ring and/or fused benzene ring, and hydrogen in the benzene ring and the fused benzene ring may be substituted with halogen; and at least one of A1 and A2 represents acrylate or methacrylate, A1 and A2 being directly bonded to the benzene ring or the fused benzene ring.

10. The liquid crystal display device according to claim 9 , wherein Y in formula (6) is a structure represented by formula (7-1), (7-2), or (7-3):

wherein hydrogen may be substituted with halogen.

Assignees

• Sharp Kk

Inventors

• Miyachi Koichi
• Mizusaki Masanobu
• Okazaki Tsuyoshi
• Tsuchiya Hiroshi
• Miyake Isamu
• Matsumoto Toshihiro

Classifications

• G02F1/1341

  Filling or closing of cells · CPC title

• C09K19/12 Primary

  at least two benzene rings directly linked, e.g. biphenyls · CPC title

• G02F1/13

  based on liquid crystals, e.g. single liquid crystal display cells · CPC title

• C09K2019/301

  Cy-Cy-Ph · CPC title

• C09K2019/3016

  Cy-Ph-Ph · CPC title