Nitrile rubber composition
US-2015371744-A1 · Dec 24, 2015 · US
US10203222B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10203222-B2 |
| Application number | US-201515311379-A |
| Country | US |
| Kind code | B2 |
| Filing date | May 18, 2015 |
| Priority date | May 16, 2014 |
| Publication date | Feb 12, 2019 |
| Grant date | Feb 12, 2019 |
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Provided is a method for a magnetic encoder having a magnetic body comprised of a magnetic rubber molded article, comprising a mixing step of mixing and then kneading a nitrile rubber (A), a ferrite magnetic powder (B) and a vulcanizing agent (C) to provide a magnetic rubber composition; and a molding step of molding and vulcanizing the magnetic rubber composition in a mold to which a magnetic field is applied to provide the magnetic rubber molded article, wherein a content of the ferrite magnetic powder (B) is 700 to 1500 parts by mass based on 100 parts by mass of the nitrile rubber (A); and a compressed density of the ferrite magnetic powder (B) is 3.5 g/cm 3 or more. According to this method, a magnetic encoder having a magnetic body with high coercivity and residual magnetic flux density can be produced by vulcanizing a magnetic rubber composition having favorable moldability.
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The invention claimed is: 1. A method for manufacturing a magnetic encoder having a magnetic body comprised of a magnetic rubber molded article, comprising a mixing step of mixing and then kneading a nitrile rubber (A), a ferrite magnetic powder (B) and a vulcanizing agent (C) to provide a magnetic rubber composition; and a molding step of molding and vulcanizing the magnetic rubber composition in a mold to which a magnetic field is applied to provide the magnetic rubber molded article, wherein a content of the ferrite magnetic powder (B) is 700 to 1500 parts by mass based on 100 parts by mass of the nitrile rubber (A); a compressed density of the ferrite magnetic powder (B) is 3.5 g/cm 3 or more; and a minimum torque ML of the magnetic rubber composition is 3 to 8 kgf·cm as determined in a vulcanization curve at 180° C. 2. The method for manufacturing a magnetic encoder as claimed in claim 1 , wherein the ferrite magnetic powder (B) has a particle size distribution with a plurality of peaks. 3. The method for manufacturing a magnetic encoder as claimed in claim 2 , wherein the ferrite magnetic powder (B) is an anisotropic magnetic powder. 4. The method for manufacturing a magnetic encoder as claimed in claim 1 , wherein the ferrite magnetic powder (B) is an anisotropic magnetic powder. 5. The method for manufacturing a magnetic encoder as claimed in claim 1 , wherein in the mixing step, the nitrile rubber (A), the ferrite magnetic powder (B) and the vulcanizing agent (C) are mixed and then kneaded at 60 to 130° C. for 10 to 60 min to provide the magnetic rubber composition. 6. The method for manufacturing a magnetic encoder as claimed in claim 1 , wherein vulcanization is conducted at 140 to 250° C. for 1 to 30 min in the mold to which a magnetic field is applied. 7. The method for manufacturing a magnetic encoder as claimed in claim 1 , wherein the magnetic encoder comprises a supporting member attachable to a rotator and an annular magnetic rubber molded article mounted on the supporting member, in which the magnetic rubber molded article is circumferentially alternately magnetized in N-pole and S-pole. 8. A magnetic encoder having a magnetic body comprised of a magnetic rubber molded article, wherein the magnetic rubber molded article is obtained by vulcanizing a magnetic rubber composition comprising a nitrile rubber (A) and a ferrite magnetic powder (B), a content of the ferrite magnetic powder (B) is 700 to 1500 parts by mass based on 100 parts by mass of the nitrile rubber (A), a compressed density of the ferrite magnetic powder (B) is 3.5 g/cm 3 or more, an average particle diameter of the ferrite magnetic powder (B) is 0.5 to 2 μm, the ferrite magnetic powder (B) has a particle size distribution with a plurality of peaks, and a minimum torque ML of the magnetic rubber composition is 3 to 8 kgf·cm as determined in a vulcanization curve at 180° C. 9. The magnetic encoder as claimed in claim 8 , wherein the ferrite magnetic powder (B) is an anisotropic magnetic powder. 10. The magnetic encoder as claimed in claim 8 , comprising a supporting member attachable to a rotator and an annular magnetic rubber molded article mounted on the supporting member, in which the magnetic rubber molded article is circumferentially alternately magnetized in N-pole and S-pole. 11. A method for manufacturing the magnetic encoder as claimed in claim 8 , comprising a mixing step of mixing and then kneading the nitrile rubber (A), the ferrite magnetic powder (B) and a vulcanizing agent (C) to provide the magnetic rubber composition; and a molding step of molding and vulcanizing the magnetic rubber composition to provide the magnetic rubber molded article. 12. The method for manufacturing the magnetic encoder as claimed in claim 11 , wherein in the mixing step, the nitrile rubber (A), the ferrite magnetic powder (B) and the vulcanizing agent (C) are mixed and then kneaded at 60 to 130° C. for 10 to 60 min to provide the magnetic rubber composition. 13. The method for manufacturing the magnetic encoder as claimed in claim 11 , wherein in the molding step, the vulcanization is conducted at 140 to 250° C. for 1 to 30 min. 14. The method for manufacturing the magnetic encoder as claimed in claim 11 , wherein in the molding step, the magnetic rubber composition is molded and vulcanized in a mold to which a magnetic field is applied.
Flexible bodies · CPC title
Magnetic or paramagnetic · CPC title
influencing the magnitude of a current or voltage · CPC title
Heating or curing, e.g. crosslinking or vulcanizing {during moulding, e.g. in a mould}(cold vulcanisation B29C35/18 {; vulcanising tyres, presses therefor B29D30/0601}) · CPC title
Use of rubber not provided for in a single one of main groups {B29K2007/00 - B29K2011/00,} as moulding material · CPC title
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