Pressure sensitive adhesive composition, pressure sensitive adhesive film, and method of manufacturing organic electronic device using the same

Patent metadata

Field	Value
Publication number	US-10202525-B2
Application number	US-201414647365-A
Country	US
Kind code	B2
Filing date	Aug 5, 2014
Priority date	Aug 5, 2013
Publication date	Feb 12, 2019
Grant date	Feb 12, 2019

Abstract

Provided are a pressure-sensitive adhesive composition, a pressure-sensitive adhesive film, and a method of manufacturing an organic electronic device using the same. The pressure-sensitive adhesive composition that may effectively prevent moisture or oxygen added to an organic electronic device from an external environment, and exhibit reliability under harsh conditions such as high temperature and high humidity and excellent optical characteristics, and a pressure-sensitive adhesive film including the same are provided.

First claim

What is claimed is:

1. An encapsulated organic electronic device, comprising:
a substrate;
an organic electronic element formed on the substrate; and
a crosslinked pressure-sensitive adhesive film encapsulating the organic electronic element,
wherein the pressure-sensitive adhesive film comprises a pressure-sensitive adhesive layer including a pressure-sensitive adhesive composition,
wherein the pressure-sensitive adhesive composition comprises:
an encapsulating resin comprising a copolymer of a diene and an olefin-based compound having one carbon-carbon double bond;
a tackifier; and
a multifunctional active energy ray-polymerizable compound satisfying Formula 1 which is included at 5 to 18 parts by weight relative to 100 parts by weight of the encapsulating resin,

wherein the encapsulating resin has a glass transition temperature of less than 0° C., and
wherein the pressure-sensitive adhesive composition has been crosslinked and has a gel content represented by Equation 1 of 50% or more,

wherein R 1 is hydrogen or an alkyl group having 1 to 4 carbon atoms, n is an integer of 2 or more, and X is a residue induced from a linear, branched, or cyclic alkyl group having 3 to 30 carbon atoms,
Gel content (%)=B/A×100  [Equation 1]

wherein A is a mass of the pressure-sensitive adhesive composition, and B is a dry mass of an insoluble content of the pressure-sensitive adhesive composition remaining after being dipped in toluene at 60° C. for 24 hours and filtered through a 200-mesh filter (pore size of 200 μm).

2. The organic electronic device of claim 1 , wherein the pressure-sensitive adhesive composition has a haze of 3% or less while being formed in a film.

3. The organic electronic device of claim 1 , wherein the tackifier is a hydrogenated cyclic olefin-based polymer.

4. The organic electronic device of claim 1 , wherein, in the pressure-sensitive adhesive composition, the tackifier is included at 5 to 100 parts by weight relative to 100 parts by weight of the encapsulating resin.

5. The organic electronic device of claim 1 , wherein the pressure-sensitive adhesive composition further comprises a radical initiator.

6. The organic electronic device of claim 5 , wherein, the radical initiator is a photoinitiator or a thermal initiator.

7. The organic electronic device of claim 5 , wherein, in the pressure-sensitive adhesive composition, the radical initiator is included at 0.2 to 20 parts by weight relative to 100 parts by weight of the active energy ray-polymerizable compound.

8. The organic electronic device of claim 1 , wherein the pressure-sensitive adhesive composition further comprises a moisture absorbent.

9. The organic electronic device of claim 1 , wherein the pressure sensitive adhesive film comprises a first layer having the pressure sensitive adhesive layer, and a second layer having a pressure-sensitive adhesive resin or an adhesive resin.

10. The organic electronic device of claim 1 , wherein the pressure-sensitive adhesive film has a water vapor transmission rate in a thickness direction of 50 g/m 2 ·day or less when manufactured to have a thickness of 100 μm.

11. The organic electronic device of claim 1 , wherein the pressure-sensitive adhesive film has a light transmittance of 90% or more with respect to a visible-ray region.

12. The organic electronic device of claim 1 , wherein the pressure-sensitive adhesive film has a haze of 3% or less.

13. A method of manufacturing an encapsulated organic electronic device, comprising:
providing a substrate;
forming an organic electronic element on the substrate,
applying the pressure-sensitive adhesive composition of claim 1 on the substrate to cover the organic electronic element; and
curing the pressure-sensitive adhesive composition to form a crosslinked pressure-sensitive adhesive film.

Assignees

• Lg Chemical Ltd

Inventors

• Park Sang Min
• Cho Yoon Gyung
• Bae Kyung Yul
• Yoo Hyun Jee
• Shim Jung Sup
• Park Min Soo

Classifications

• C09J151/04

  grafted on to rubbers · CPC title

• C09D151/04

  grafted on to rubbers · CPC title

• C09J123/22 Primary

  Copolymers of isobutene; Butyl rubber {; Homo- or copolymers of other iso-olefines} · CPC title

• C08F255/10

  on to butene polymers · CPC title

• C09J2433/00

  Presence of (meth)acrylic polymer · CPC title