Catalyst and its use in hydrocarbon conversion process

Patent metadata

Field	Value
Publication number	US-10202318-B2
Application number	US-201615240622-A
Country	US
Kind code	B2
Filing date	Aug 18, 2016
Priority date	Sep 25, 2015
Publication date	Feb 12, 2019
Grant date	Feb 12, 2019

Abstract

The invention relates to catalysts and their use in processes for conversion of hydrocarbon feedstock to a product comprising single-ring aromatic hydrocarbons having six or more carbon atoms, to the methods of making such catalysts, to processes for using such catalysts, and to apparatus and systems for carrying out such processes. One of more of the catalysts comprise a crystalline aluminosilicate having a Constraint Index in the range of 1 to 12, a first metal and/or a second metal, and at least one selectivating agent, such as, for example, an organo-silicate.

First claim

The invention claimed is:

1. A process for conversion of a light paraffinic hydrocarbon feedstock comprising one or more light hydrocarbons having no more than five carbon atoms, the one or more light hydrocarbons comprising ethane, to form a product comprising at least one single-ring aromatic hydrocarbon having six or more carbon atoms, said process comprising the step of contacting said feedstock under suitable conversion conditions in the presence of a catalyst which includes
(a) a crystalline aluminosilicate having a Constraint Index in the range of 1 to 12;
(b) a first metal and a second metal, wherein said second metal is different from said first metal; and
(c) at least one organo-silicate selectivating agent,

wherein the catalyst comprises at least 0.005 wt. % of the selectivating agent, based on a weight of the catalyst, the selectivating agent being added to the catalyst after addition of the first metal and the second metal.

2. The process of claim 1 , wherein said one or more light hydrocarbons further comprise methane, propane, butane, and mixtures of two or more thereof.

3. The process of claim 1 , wherein said single-ring aromatic hydrocarbon is selected from the group consisting of benzene, toluene, xylenes, and mixtures of two or more thereof.

4. The process of claim 1 , wherein said suitable conversion conditions include at least a temperature of in the range of about 450° C. to about 750° C., a pressure in the range of from about 35 kPa to about 1480 kPa and a WHSV from about 0.1 hr −1 to about 20 hr −1 .

5. The process of claim 4 , wherein said catalyst provides over about 40% reaction selectivity to benzene, toluene or xylenes, and mixtures thereof, and/or less than about 10% reaction selectivity to naphthalene, in a process for conversion of a light paraffinic hydrocarbon feedstock comprising one or more light hydrocarbons having no more than five carbon atoms to form a product comprising at least one single-ring aromatic hydrocarbon under said suitable conversion conditions.

6. The process of claim 1 , wherein the first metal is selected from the group consisting of zinc, gallium, platinum, copper, rhenium, iron, and mixtures of two or more thereof.

Assignees

• Exxonmobil Chemical Patents Inc

Inventors

• Shekhar Mayank
• Keusenkothen Paul F
• Mertens Machteld M W
• Go Anthony

Classifications

• Y02P20/584

  Recycling of catalysts · CPC title

• C10G35/065

  containing crystalline zeolitic molecular sieves, other than aluminosilicates · CPC title

• B01J2229/16

  to increase the Si/Al ratio; Dealumination · CPC title

• B01J38/04

  Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst · CPC title

• B01J29/90

  Regeneration or reactivation · CPC title