Coating inspection method

Patent metadata

Field	Value
Publication number	US-10201831-B2
Application number	US-201514963256-A
Country	US
Kind code	B2
Filing date	Dec 9, 2015
Priority date	Dec 9, 2015
Publication date	Feb 12, 2019
Grant date	Feb 12, 2019

Abstract

Provided herein are methods and compositions which allow for efficient inspection, maintenance and repair of ceramic coatings.

First claim

The invention claimed is:

1. A method for determination of uniformity of deposition of a material in a thermal barrier coating, the method comprising:
(a) illuminating a surface of the thermal barrier coating with a stimulant radiation, wherein the thermal barrier coating is disposed on a superalloy substrate or on a metallic bond coated superalloy substrate, and wherein the thermal barrier coating comprises a plurality of surface-connected openings at the surface and the material disposed in at least some of the surface-connected openings, the material comprising
i. one or more phosphors; and
ii. one or more protective agents;

(b) detecting an emission radiation from the material in response to the stimulant radiation; and
(c) recording the distribution of the material within the thermal barrier coating based on the intensity of the detected emission radiation as a function of position on the surface.

2. The method of claim 1 , wherein, after illumination of the area in which the material is disposed with a stimulant radiation, the wavelength of the light emitted from the one or more disposed phosphors is different from any wavelength of light emitted by the original thermal barrier coating under the same illumination.

3. The method of claim 1 , further comprising identifying regions of insufficient concentration of the material based on the recorded distribution of the material, and disposing an additional quantity of the material in the regions of insufficient concentration of the material.

4. The method of claim 1 , wherein the stimulant radiation is ultra-violet (UV) light.

5. The method of claim 1 , wherein the phosphor is present in the material in an amount from about 0.1% to about 5% by weight of the material.

6. The method of claim 1 , wherein the phosphor comprises a host and an activator.

7. The method of claim 6 , wherein the host is alumina.

8. The method of claim 7 , wherein the activator is europium.

9. The method of claim 1 , wherein the phosphor comprises one or more of europium, tungsten, molybdenum, lead, boron, titanium, manganese, uranium, chromium, terbium, dysprosium, yttrium, cerium, gadolinium, lanthanum, phosphorous, oxygen, lutetium or nitrogen.

10. The method of claim 9 , wherein the phosphor contains europium.

11. The method of claim 10 , wherein the europium is present in the material in an amount from about 0.1% to about 2.5% by weight of the material.

12. The method of claim 1 , wherein the protective agent is a barrier agent, an anti-calcium-magnesium-aluminum-silicon-oxide (CMAS) agent, or a combination thereof.

13. The method of claim 12 , wherein, in a first quantity, the disposed material comprises one or more barrier agents; and in a second quantity, the disposed material comprises one or more anti-CMAS agents.

14. The method of claim 13 , wherein in a first quantity, the disposed material comprises one or more barrier agents and a first phosphor, and in a second quantity, the disposed material comprises one or more anti-CMAS agents and a second phosphor; wherein, after illumination of the area in which the one or more quantities of the material is disposed with a stimulant radiation, the wavelength of the light emitted from the first phosphor is different from the wavelength of light emitted by the second phosphor.

15. The method of claim 12 , wherein the anti-CMAS agent comprises one or more rare earth elements or alkaline earth elements, or a combination thereof.

16. The method of claim 15 , wherein the one or more rare earth elements are selected from the group consisting of lanthanum, neodymium, erbium, cerium, and gadolinium.

17. The method of claim 15 , wherein the one or more alkaline earth elements are selected from the group consisting of beryllium, magnesium, calcium, strontium, barium, and radium.

18. The method of claim 15 , wherein the anti-CMAS agent comprises a nitride, an oxide, or combinations thereof.

19. The method of claim 15 , wherein the anti-CMAS agent further comprises zirconium, hafnium, titanium, tantalum, or niobium.

20. The method of claim 12 , where in the protective agent comprises a barrier agent and the barrier agent comprises aluminum oxide, hafnium oxide or cerium oxide, or a combination thereof.

21. The method of claim 12 , where in the barrier agent comprises Al 2 O 3 , HfO 2 , Ce 2 O 3 , or a combination thereof.

22. The method of claim 1 , wherein the material comprises a barrier agent and a phosphor.

23. The method of claim 1 , wherein the material comprises an anti-CMAS agent and a phosphor.

24. The method of claim 23 , wherein the anti-CMAS agent is physically separated from the
(i) bond coat, if bond coat is present, or
(ii) substrate, if no bond coat is present.

25. The method of claim 1 , wherein the protective agent is selected from the group consisting of GdAlO 3 , Gd 3 NbO 7 , and GdTa 3 O 9 .

26. The method of claim 1 , wherein the material comprises 1.5 weight % of Eu 2 O 3 by total weight of the material.

27. The method of claim 1 , wherein the material comprises Gd 0.98 Eu 0.02 AlO 3 .

28. The method of claim 1 , wherein disposing the material within the thermal barrier coating comprises infiltrating the surface connected openings of the thermal barrier coating with a liquid.

29. The method of claim 28 , wherein the liquid comprises a carrier fluid and a plurality of particles suspended within the carrier fluid.

30. The method of claim 28 , wherein the liquid comprises a solvent and a solute dissolved in the solvent.

31. The method of claim 28 , further comprising volatilizing the liquid to form a residue disposed in the surface-connected openings of the thermal barrier coating.

32. A method for determination of uniformity of deposition of a material in a thermal barrier coating, the method comprising:
(a) illuminating a surface of the thermal barrier coating with a UV radiation, wherein the thermal barrier coating is disposed on a superalloy substrate or on a metallic bond coated superalloy substrate, and wherein the thermal barrier coating comprises a plurality of surface-connected openings at the surface and the material disposed in at least some of the surface-connected openings, the material comprising
i. phosphorescent alumina; and
ii. one or more protective agents;

(b) detecting an emission radiation from the material in response to the UV radiation; and
(c) recording the distribution of the material within the thermal barrier coating based on the intensity of the detected emission radiation as a function of position on the surface.

33. The method of claim 32 , wherein the phosphorescent alumina comprises europium dopant.

Assignees

• Gen Electric

Inventors

• Sivaramakrishnan Shankar
• Hasz Wayne Charles
• Brosnan Kristen Hall
• Murphy James Edward

Classifications

• C04B41/5009

  containing nitrogen in the anion, e.g. nitrites · CPC title

• F05D2230/90

  Coating; Surface treatment · CPC title

• C23C14/221

  Ion beam deposition (C23C14/46, C23C14/48 take precedence) · CPC title

• C23C30/00

  Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process (C23C26/00, C23C28/00 take precedence) · CPC title

• C23C16/44

  characterised by the method of coating (C23C16/04 takes precedence) · CPC title