Microcapsules comprising hydroxyalkyl cellulose

Patent metadata

Field	Value
Publication number	US-10201795-B2
Application number	US-201515523953-A
Country	US
Kind code	B2
Filing date	Oct 27, 2015
Priority date	Nov 7, 2014
Publication date	Feb 12, 2019
Grant date	Feb 12, 2019

Abstract

The application describes an aqueous dispersion of microcapsules, wherein the shell of the microcapsules comprises at least one polyurea and the core comprises one or more lipophilic components with the proviso that the core does not contain a fragrance, and having a percentage of the shell weight with reference to the total weight of the capsules of 5 to 40% and wherein the microcapsules have a volume average diameter of 15 to 90 μm and the dispersion comprises hydroxyalkylcellulose and the use of such a dispersion.

First claim

The invention claimed is:

1. A method for forming a composition, the method comprising:
providing an aqueous dispersion of microcapsules, wherein:
a shell of the microcapsules comprises at least one polyurea and a core comprises one or more lipophilic components with the proviso that the core does not contain a fragrance, and having a percentage of the shell weight with reference to a total weight of the microcapsules of 5 to 40%;
the microcapsules have a volume average diameter of 15 to 90 μm;
the dispersion comprises a hydroxyalkylcellulose as a stabilizing agent; and
a ratio of the shell weight percentage to the volume average diameter of the microcapsules is at most 0.7 μm −1 ; and

adding the aqueous dispersion of microcapsules to a cosmetic composition, a hygiene composition, a disinfection composition, a laundry detergent, a fabric softener, a dishwashing liquid, a household cleaner, or an industrial cleaner.

2. The method of claim 1 , wherein a ratio of the shell weight percentage to the volume average diameter of the capsules is at most 0.5 μm −1 .

3. The method of claim 1 , wherein a nominal rupture stress of the capsules is in a range of 0.1 to 2 MPa.

4. The method of claim 1 , wherein the one or more lipophilic components are selected from components having a solubility in water of ≤10 mg/mL at 20° C.

5. The method of claim 1 , wherein a viscosity of the dispersion is ≤4 Pa s, measured on a rheometer with rotating discs at a shear rate of 21 s −1 and at a temperature of 25° C.

6. The method of claim 1 , wherein an amount of the hydroxyalkylcellulose is 0.05 to 1.2% by weight based on the total weight of the dispersion.

7. The method of claim 1 , wherein the hydroxyalkylcellulose comprises at least one hydroxyethylcellulose.

8. The method of claim 1 , wherein the one or more lipophilic components are selected from the group consisting of oil bodies, UV-filters, biocides, dyes, emollients, vitamins, cosmetically active ingredients, pharmaceutically active ingredient, cosmetically and pharmaceutically acceptable auxiliaries, detergents, and mixtures thereof.

9. The method of claim 3 , wherein the nominal rupture stress of the capsules is in a range of 0.2 to 1.5 mPa.

10. The method of claim 3 , wherein the nominal rupture stress of the capsules is in a range of 0.4 to 1 mPa.

11. A method for forming a composition, the method comprising:
providing microcapsules obtained by drying an aqueous dispersion of microcapsules, wherein:
a shell of the microcapsules comprises at least one polyurea and a core comprises one or more lipophilic components with the proviso that the core does not contain a fragrance, and having a percentage of the shell weight with reference to a total weight of the microcapsules of 5 to 40%;
the microcapsules have a volume average diameter of 15 to 90 μm;
the dispersion comprises a hydroxyalkylcellulose as a stabilizing agent; and
a ratio of the shell weight percentage to the volume average diameter of the microcapsules is at most 0.7 μm −1 ; and

adding the microcapsules to a personal care composition, a material protection composition, a pharmaceutical composition, a plant protection composition, or a home care product.

12. A method for forming a composition, the method comprising:
providing microcapsules obtained by drying an aqueous dispersion of microcapsules, wherein:
a shell of the microcapsules comprises at least one polyurea and a core comprises one or more lipophilic components with the proviso that the core does not contain a fragrance, and having a percentage of the shell weight with reference to a total weight of the microcapsules of 5 to 40%;
the microcapsules have a volume average diameter of 15 to 90 μm;
the dispersion comprises a hydroxyalkylcellulose as a stabilizing agent; and
a ratio of the shell weight percentage to the volume average diameter of the microcapsules is at most 0.7 μm −1 ; and

adding the microcapsules to a cosmetic composition, a hygiene composition, a disinfection composition, a laundry detergent, a fabric softener, a dishwashing liquid, a household cleaner, or an industrial cleaner.

13. A method for forming an article, the method comprising:
providing microcapsules obtained by drying an aqueous dispersion of microcapsules, wherein:
a shell of the microcapsules comprises at least one polyurea and a core comprises one or more lipophilic components with the proviso that the core does not contain a fragrance, and having a percentage of the shell weight with reference to a total weight of the microcapsules of 5 to 40%;
the microcapsules have a volume average diameter of 15 to 90 μm;
the dispersion comprises a hydroxyalkylcellulose as a stabilizing agent; and
a ratio of the shell weight percentage to the volume average diameter of the microcapsules is at most 0.7 μm −1 ; and

adding the microcapsules to a textile, a paper, or a nonwoven.

14. The method of claim 1 , wherein the microcapsules have a percentage of the shell weight with reference to a total weight of the microcapsules of 10 to 20%.

15. The method of claim 1 , wherein a ratio of the shell weight percentage to the volume average diameter of the capsules is in a range from 0.2 μm −1 to 0.7 μm −1 .

Assignees

• Basf Se

Inventors

• Burakowska-Meise Ewelina
• Denuell Wolfgang
• Soltys Thomas
• Aussant Emmanuel Julien Leon Christian
• Fadel Addi
• Harrison Ian

Classifications

• A61Q19/00

  Preparations for care of the skin · CPC title

• A61K8/11 Primary

  Encapsulated compositions · CPC title

• A61K8/84

  obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds · CPC title

• A61K8/8176

  Homopolymers of N-vinyl-pyrrolidones. Compositions of derivatives of such polymers · CPC title

• A61K9/4858

  Organic compounds · CPC title