Method for radionuclide contaminatecontaminant mitigation

Patent metadata

Field	Value
Publication number	US-10199129-B1
Application number	US-201615233680-A
Country	US
Kind code	B1
Filing date	Aug 10, 2016
Priority date	Aug 10, 2016
Publication date	Feb 5, 2019
Grant date	Feb 5, 2019

Abstract

The method and system disclosed provides radionuclide contamination mitigation by applying an aqueous carrier solution comprising a cation to a surface bearing a radionuclide contaminant to cause the radionuclide contaminant to enter solution forming a laden solution, then contacting the laden solution with a sequestering agent to bind to the radionuclide contaminant to form a laden sequestering agent. The removal and sequestration of the radionuclide contaminant from the contaminated surface leads directly to a reduction in the amount of radiologically-impacted critical infrastructure and the environment. The method and system are able to be performed or utilized economically with materials quickly available in the event of a radiological dispersion event.

First claim

We claim:

1. A method of radionuclide contaminant mitigation, which comprises
applying a carrier solution to a surface bearing a radionuclide contaminant, where the radionuclide contaminant is selected from the group consisting of 60 Co, 137 Cs, 192 Ir, 90 Sr and 241 Am,

where the carrier solution an anionic surfactant comprises water and a cation,
where the cation is selected from the group consisting of K + , Na+, Mg + , Li + , NH 4 + , Ba 2+ , Ca 2+ , and Mg 2+ , and
where the cation is in a concentration range from about 0.01 M to about 1.0 M, causing at least a portion of the radionuclide contaminant to enter the carrier solution to form a laden carrier solution comprising the radionuclide contaminant and carrier solution; and
contacting the laden solution with a sequestering agent,

where the sequestering agent is a clay,
where at least a portion of the radionuclide contaminant of the laden solution binds to at least a portion of the sequestering agent to form a laden sequestering agent and to generate a laden slurry comprising the laden sequestering agent and reformed carrier solution.

2. The method of claim 1 where the sequestering agent comprises a clay selected from the group consisting of montmorillonite, vermiculite, zeolite, illite, kaolinite, and bentonite.

3. The method of claim 1 where the surfactant is in a concentration range from about 10 −6 M to about 5×10 −2 M.

4. The method of claim 3 where the surfactant is sodium dodecyl sulfate or ammonium dodecyl sulfate.

5. The method of claim 1 further comprising separating the laden slurry to remove at least a portion of the laden sequestering agent from the reformed carrier solution.

6. The method of claim 5 further comprising separating by centrifugal filtration.

7. The method of claim 5 further comprising recycling the reformed carrier solution.

8. A method of radionuclide contaminant mitigation, which comprises
forming a brine comprising water and a cation,

where the cation is selected from the group consisting of K + , Mg + , Na + , and NH 4 + ,
mixing a carrier solution an anionic surfactant comprising water and the brine,

where the cation in the carrier solution is in a concentration in the range from about 0.01 M to about 1.0 M;
applying the carrier solution to a surface bearing a radionuclide contaminant,

where the radionuclide contaminant is selected from the group consisting of 60 Co, 137 Cs, 192 Ir, 90 Sr and 241 Am, causing at least a portion of the radionuclide contaminant to enter the carrier solution to form laden carrier solution comprising the radionuclide contaminant and carrier solution; and
contacting the laden solution with a sequestering agent,

where the sequestering agent is a clay,
where at least a portion of the radionuclide contaminant of the laden solution binds to at least a portion of the sequestering agent to form a laden sequestering agent and to generate a laden slurry comprising the laden sequestering agent and reformed carrier solution.

9. The method of claim 8 where the sequestering agent comprises a clay selected from the group consisting of montmorillonite, vermiculite, zeolite, illite, kaolinite, and bentonite.

10. The method of claim 8 where the surfactant is in the concentration range from about 10 −6 M to about 5×10 −2 M.

11. The method of claim 8 where the surfactant is sodium dodecyl sulfate or ammonium dodecyl sulfate.

12. The method of claim 8 further comprising separating the laden slurry to remove at least a portion of the laden sequestering agent from the reformed carrier solution.

13. The method of claim 12 further comprising separating by centrifugal filtration.

14. The method of claim 12 further comprising recycling the laden slurry to remove at least a portion of the laden sequestering agent from the carrier solution.

Assignees

• Us Energy
• Us Dept Energy

Inventors

• Kaminski Michael D
• Mertz Carol J

Classifications

• B01J20/12

  Naturally occurring clays or bleaching earth · CPC title

• B01D11/0288

  Applications, solvents · CPC title

• B01J39/14

  Base exchange silicates, e.g. zeolites · CPC title

• G21F9/16

  by fixation in stable solid media {(G21F9/305 takes precedence)} · CPC title

• G21F9/162

  in an inorganic matrix, e.g. clays, zeolites · CPC title