Integrated system for nanofiber production

Patent metadata

Field	Value
Publication number	US-10196757-B1
Application number	US-201615203943-A
Country	US
Kind code	B1
Filing date	Jul 7, 2016
Priority date	Mar 23, 2015
Publication date	Feb 5, 2019
Grant date	Feb 5, 2019

Abstract

The invention provides a system for producing nanotubes, nanofibers and nanorods, the system comprising a wire array shaped as a cylinder such that the cylinder defines a void; a first furnace positioned within the void; a second furnace positioned opposite the first furnace to define a channel adapted to receive a portion of the cylinder as the cylinder rotates about its axis; a device for depositing spun fiber onto the wire array as the cylinder rotates; and a device for removing the deposited fiber from the array after the deposited fiber is heated within the channel. The invention also provides a method for producing nanotubes, the method comprising: supplying a cylindrical wire array, wherein the array defines an internal void; positioning a first furnace within the void; positioning a second furnace opposite the first furnace so as to define a channel between the first furnace and second furnace, the channel adapted to receive a portion of the cylindrical array as the array rotates about its axis; depositing spun fiber onto the array as the array rotates; heating the deposited fiber as it enters the channel; and removing the deposited fiber as it exits the channel.

First claim

The embodiment of the invention in which an exclusive property or privilege is claimed is defined as follows:

1. A system for continually producing nanotubes and nanowires, the system comprising:
a) a wire array shaped as a cylinder such that the cylinder defines a void;
b) a first furnace positioned within the void;
c) a second furnace positioned opposite the first furnace to define a channel adapted to receive a portion of the cylinder as the cylinder rotates about its axis;
d) a dispenser for depositing spun fiber onto the wire array as the cylinder rotates; and
e) a collection device for removing the nanotubes and nanowires from the channel.

2. The system as recited in claim 1 wherein the wire array is electrified.

3. The system as recited in claim 1 wherein the first and second furnaces are IR radiation sources.

4. The system as recited in claim 1 wherein the spun fiber comprises a polymer selected from the group consisting of polyvinylpyrrolidone, polyethylene oxide, polyvinyl acetate, polyethylene glycol, block copolymers and combinations thereof.

5. The system as recited in claim 1 wherein the means for depositing fiber comprises:
a) a supply of a polymer mixture; and
b) an electrical potential between the polymer mixture and the wire array.

6. The system as recited in claim 1 wherein the nanotubes are between approximately 15 nm and 500 nm in diameter.

7. The system as recited in claim 1 wherein the nanotubes are separately produced from each other.

8. The system as recited in claim 7 wherein the tubes remain separate from each other during heating and harvesting.

9. A method for continuously producing nanotubes or nanorods, the method comprising:
a) supplying a cylindrical wire array, wherein the array defines an internal void;
b) positioning a first furnace within the void;
c) positioning a second furnace opposite the first furnace so as to define a channel between the first furnace and second furnace, the channel adapted to receive a portion of the cylindrical array as the array rotates about its axis;
d) depositing spun fiber onto the array as the array rotates;
e) heating the deposited fiber as it enters the channel so as transform the fiber into a nanotube or nanorod; and
f) removing the nanotube or nanorod from the array as it exits the channel.

10. The method as recited in claim 9 wherein the step of depositing spun fiber further comprises establishing an electrical potential between the spun fiber and the wire array.

11. The method as recited in claim 9 wherein the deposited fiber is exposed to radiation selected from the group consisting of infra red, ultra violet, visible light, laser light, and combinations thereof.

12. The method as recited in claim 9 wherein the nano tubes are between approximately 15 nm and approximately 500 nm in diameter, and the walls of the nanotubes are between 5 and 100 nm thick.

13. The method as recited in claim 9 wherein the nanotubes remain as separate entities during deposition, heating and removal.

14. The method as recited in claim 9 wherein the nanotube or nanorod has a first end connected to a first wire on the array, and a second end connected to an adjacent second wire on the array.

15. The method as recited in claim 14 wherein the length of the nanotube or nanorod is approximately equal to the distance between the first wire and adjacent second wire.

16. The method as recited in claim 14 wherein the removing step further comprises the nanotube or nanorod disengaging from the first wire and the second wire such that the nanotube or nanorod has a length approximately equal to the distance between the first wire and the second wire.

17. The method as recited in claim 11 wherein the fiber is heated while attached to the array.

18. The method as recited in claim 11 wherein the heating stops before nanotube or nanorod is removed from the array.

19. The method as recited in claim 16 wherein negative pressure facilitates disengagement of the nanotube or nanorod from the first and second wires.

20. The method as recited in claim 9 wherein the spun fiber comprises polymer and the tube is formed before the polymer substantially completely evaporates during heating.

Assignees

• Chen Xing
• Grocke Garrett L
• Vajda Viktor
• Zhou Ziyao
• Uchicago Argonne Llc

Inventors

• Chen Xing
• Grocke Garrett L
• Vajda Viktor
• Zhou Ziyao

Classifications

• D01D5/0092

  characterised by the electrical field, e.g. combined with a magnetic fields, using biased or alternating fields · CPC title

• D01D5/0061

  characterised by the electro-spinning apparatus · CPC title

• D01D5/0084

  Coating by electro-spinning, i.e. the electro-spun fibres are not removed from the collecting device but remain integral with it, e.g. coating of prostheses · CPC title

• D01D5/0076 Primary

  characterised by the collecting device, e.g. drum, wheel, endless belt, plate or grid (D01D5/0046 takes precedence) · CPC title

• D01F9/08

  of inorganic material (working or processing of metal wire B21F; from softened glass, minerals or slags C03B37/00) · CPC title