Surfactant composition

Patent metadata

Field	Value
Publication number	US-10196556-B2
Application number	US-201314402461-A
Country	US
Kind code	B2
Filing date	May 21, 2013
Priority date	May 25, 2012
Publication date	Feb 5, 2019
Grant date	Feb 5, 2019

Abstract

The invention provides a synergistic surfactant composition comprising: (a) from 5 to 95 wt % of a first surfactant which is selected from derivatives of alkyl polyglucosides and mixtures thereof; and (b) from 5 to 95 wt % of a second surfactant which is selected from: amphoteric surfactants, cationic surfactants, anionic surfactants, non-ionic surfactants, and mixtures thereof. This surfactant composition may be used to generate foam that is used for unloading a liquid from a hydrocarbon reservoir. It may be that the liquid unloading of foam generated using the surfactant composition is greater than that of foam generated from the first and second surfactants when they are foamed individually.

First claim

The invention claimed is:

1. A method of unloading liquid from a hydrocarbon reservoir, the method comprising: introducing two surfactants into the liquid, in order to foam the liquid; and then removing foamed liquid from the reservoir;
wherein the first surfactant comprises an alkyl polyglucoside derivative selected from the group consisting of:
Sodium hydroxypropyl sulfonate decyl glucose crosspolymer,
Sodium hydroxypropyl sulfonate lauryl glucose crosspolymer,
Disodium sulfosuccinate decyl glucoside crosspolymer,
Disodium sulfosuccinate lauryl glucoside crosspolymer,
Sodium succinate lauryl glucoside crosspolymer,
Poly sodium decyl glucoside hydroxypropyl phosphate,
Poly sodium lauryl glucoside hydroxypropyl phosphate,
Coco glucoside betaine crosspolymer,
Lauryl glucoside betaine crosspolymer,
Hydroxypropyltrimonium coco glucosides chloride, and
Stearvidimonium hydroxypropyl lauryl glucosides chloride, and the second surfactant is selected from the group consisting of:
Lauramidopropyl hydroxysultaine,
Cocamidopropyl hydroxysultaine,
Lauramidopropyl betaine,
Disodium lauramphodiacetate, and
Disodium lauraminodipropionate.

2. The method of claim 1 , wherein the surfactants are used in the reservoir at a total active surfactant concentration of:
(a) 100ppm or more; or
(b) 150ppm or more; or
(c) 250ppm or more; or
(d) 500ppm or more; or
(e) from 250ppm to 10,000ppm; or
(f) from 500ppm to 5,000ppm.

3. The method according to claim 1 wherein the ratio of the first surfactant to the second surfactant by weight is:
(a) from about 5:1 to about 1:5, or
(b) from about 4:1 to about 1:4, or
(c) from about 3:1 to about 1:3.

4. A method of unloading a liquid from a reservoir comprising the step of using a surfactant composition to generate a foam, wherein the composition comprises: a first surfactant which comprises an alkyl polyglucoside derivative selected from the group consisting of:
Sodium hydroxypropyl sulfonate decvtglucose crosspolymer,
Sodium hydroxypropyl sulfonate lauryl glucose crosspolymer,
Disodium sulfosuccinate decyl glucoside crosspolymer,
Disodium sulfosuccinate lauryl glucoside crosspolymer,
Sodium succinate lauryl glucoside crosspolymer,
Poly sodium decyl glucoside hydroxypropyl phosphate,
Poly sodium lauryl glucoside hydroxypropyl phosphate,
Coco glucoside betaine crosspolymer,
Lauryl glucoside betaine crosspolymer,
Hydroxypropyltrimonium coco glucosides chloride, and
Stearylidimonium hydroxypropyl lauryl glucosides chloride; and a second surfactant which is selected from the group consisting of
Lauramidopropyl hydroxysultaine,
Cocamidopropyl hydroxysultaine,
Lauramidopropyl betaine,
Disodium lauramphodiacetate, and
Disodium lauraminodipropionate.

5. A method of synergistically enhanced liquid unloading from a reservoir comprising a step of using two surfactants in combination, wherein the first surfactant comprises an alkyl polyglucoside derivative selected from the group consisting of:
Sodium hydroxypropyl sulfonate decyl glucose crosspolymer,
Sodium hydroxypropyl sulfonate lauryl glucose crosspolymer,
Disodium sulfosuccinate decyl glucoside crosspolymer,
Disodium sulfosuccinate lauryl glucoside crosspolymer,
Sodium succinate lauryl glucoside crosspolymer,
Poly sodium decyl glucoside hydroxypropyl phosphate,
Poly sodium lauryl glucoside hydroxypropyl phosphate,
Coco glucoside betaine crosspolymer,
Lauryl glycoside betaine crosspolymer,
Hydroxypropyltrimonium coco glucosides chloride,and
Stearyldimonium hydroxypropyl lauryl glucosides chloride; and the second surfactant is selected from the group consisting of
Lauramidopropyl hydroxysultaine,
Cocamidopropyl hydroxysultaine,
Lauramidopropyl betaine,
Disodium lauramphodiacetate, and
Disodium lauraminodipropionate.

6. The method of claim 5 , wherein the reservoir is a hydrocarbon reservoir.

Assignees

• Rhodia Operations

Inventors

• Hatchman Kevan
• Collins Gareth
• Jones Chris

Classifications

• C09K8/58

  Compositions for enhanced recovery methods for obtaining hydrocarbons, i.e. for improving the mobility of the oil, e.g. displacing fluids · CPC title

• C09K8/94

  Foams · CPC title

• C09K8/584 Primary

  characterised by the use of specific surfactants · CPC title

• C09K2208/32

  Anticorrosion additives · CPC title

• C09K8/588

  characterised by the use of specific polymers {(polymeric surfactants C09K8/584)} · CPC title