Inhibiting fouling tendency in high coal ash-containing water systems

Patent metadata

Field	Value
Publication number	US-10196509-B2
Application number	US-201615144183-A
Country	US
Kind code	B2
Filing date	May 2, 2016
Priority date	May 7, 2015
Publication date	Feb 5, 2019
Grant date	Feb 5, 2019

Abstract

Dispersions of coal ash in water can be inhibited or prevented from scaling and simultaneously be inhibited or prevented from fouling by introducing thereto an additive blend that includes an anionic water-soluble polymer and a second polymer different from the anionic water-soluble polymer, where the second polymer is selected from the group consisting of copolymers and terpolymers having a plurality of hydrophobic groups.

First claim

What is claimed is:

1. A method of simultaneously inhibiting or preventing calcium carbonate scale deposition and inhibiting or preventing fouling by a dispersion of coal ash in water, the method comprising adding to the coal ash dispersion an amount of an additive blend effective to simultaneously inhibit scale deposition and prevent fouling, where the additive blend comprises:
an anionic water-soluble polymer selected from the group consisting of maleic olefin copolymers, water-soluble lignin sulphonates, and an olefin maleic anhydride copolymer; and
a second polymer different from the anionic water-soluble polymer, where the second polymer is selected from the group consisting of copolymers and terpolymers having a plurality of hydrophobic groups and comprises monomers selected from the group consisting of isobutylene, polyvinyl alcohol, phosphate-containing acrylates and maleates, phosphonate-containing acrylates and maleates, and phosphonocarboxylic acid.

2. The method of claim 1 where:
the weight average molecular weight of the anionic water-soluble polymer ranges from about 500 to about 15,000 Mw; except in the case of water-soluble lignin sulphonates the weight average molecular weight ranges from about 3000 to about 90,000 Mw; and
the weight average molecular weight of the second polymer ranges from about 500 to about 15,000 Mw.

3. The method of claim 1 where the effective amount of additive blend in the coal ash dispersion ranges from about 2 to about 40 ppm by weight active polymer.

4. The method of claim 1 where the weight ratio of the anionic water-soluble polymer to the second polymer in the additive blend ranges from about 10:1 to about 3:2.

5. The method of claim 1 where for the second polymer, the hydrophobic groups are selected from the group consisting of aromatic groups and alkyl groups having at least two carbon atoms.

6. The method of claim 1 where the coal ash dispersion has the following characteristics:
a pH between about 8 and about 10; and
a hardness between about 100 to about 1000 ppm weight calcium as CaCO 3 .

7. A method of simultaneously inhibiting or preventing calcium carbonate scale deposition and inhibiting or preventing fouling by a dispersion of coal ash in water, the method comprising adding to the coal ash dispersion an amount of an additive blend effective to simultaneously inhibit scale deposition and prevent fouling, where the additive blend comprises:
an anionic water-soluble polymer selected from the group consisting of maleic olefin copolymers, water-soluble lignin sulphonates, and an olefin maleic anhydride copolymer; and
a second polymer different from the anionic water-soluble polymer, where the second polymer is selected from the group consisting of copolymers and terpolymers having a plurality of hydrophobic groups, and where the second polymer comprises monomers selected from the group consisting of isobutylene, polyvinyl alcohol, phosphate-containing acrylates and maleates, phosphonate-containing acrylates and maleates, and phosphonocarboxylic acid,

where the amount of coal ash in the water ranges from about 500 to about 5000 ppm by weight.

8. The method of claim 7 where:
the weight average molecular weight of the anionic water-soluble polymer ranges from about 500 to about 15,000 Mw; except in the case of water-soluble lignin sulphonates the weight average molecular weight ranges from about 3000 to about 90,000 Mw; and
the weight average molecular weight of the second polymer ranges from about 500 to about 15,000 Mw.

9. The method of claim 8 where the effective amount of additive blend in the coal ash dispersion ranges from about 2 to about 40 ppm by weight active polymer.

10. The method of claim 7 where the coal ash dispersion has the following characteristics:
a pH between about 8 and about 10; and
a hardness between about 100 to about 1000 ppm weight calcium as CaCO 3 .

11. A dispersion of coal ash in water simultaneously inhibited against scale deposition and fouling, where the coal ash dispersion comprises:
water;
coal ash; and
an additive blend comprising:
an anionic water-soluble polymer selected from the group consisting of maleic olefin copolymers, water-soluble lignin sulphonates, and an olefin maleic anhydride copolymer; and
a second polymer different from the anionic water-soluble polymer, where the second polymer is selected from the group consisting of copolymers and terpolymers having a plurality of hydrophobic groups and comprises monomers selected from the group consisting of isobutylene, polyvinyl alcohol, phosphate-containing acrylates and maleates, phosphonate-containing acrylates and maleates, and phosphonocarboxylic acid,

where the amount of the additive blend is effective to simultaneously inhibit or prevent against scale deposition and fouling.

12. The coal ash dispersion of claim 11 where the amount of coal ash in the water ranges from about 500 to about 5000 ppm.

13. The coal ash dispersion of claim 11 where:
the weight average molecular weight of the anionic water-soluble polymer ranges from about 500 to about 15,000 Mw; except in the case of water-soluble lignin sulphonates the weight average molecular weight ranges from about 3000 to about 90,000 Mw; and
the weight average molecular weight of the second polymer ranges from about 500 to about 15,000 Mw.

14. The coal ash dispersion of claim 11 where the effective amount of additive blend in the coal ash dispersion ranges from about 2 to about 40 ppm by weight active polymer.

15. The coal ash dispersion of claim 11 where the weight ratio of the anionic water-soluble polymer to the second polymer in the additive blend ranges from about 10:1 to about 3:2.

16. The coal ash dispersion of claim 11 where for the second polymer, the hydrophobic groups are selected from the group consisting of aromatic groups and alkyl groups having at least six carbon atoms.

17. The coal ash dispersion of claim 11 , where the coal ash dispersion has the following characteristics:
a pH between about 8 and about 10; and
a hardness between about 100 to about 1000 ppm weight calcium as CaCO 3 .

Assignees

• Baker Hughes Inc
• Baker Hughes A Ge Co Llc

Inventors

• Felipe Mary Jane Legaspi
• Nguyen Khac Truc
• Dunn Sidney A

Classifications

• C02F5/145

  combined with inorganic substances · CPC title

• C02F5/125

  combined with inorganic substances · CPC title

• C02F2303/22

  Eliminating or preventing deposits, scale removal, scale prevention (C02F1/042, C02F1/4602, C02F5/00 take precedence) · CPC title

• C08L23/32 Primary

  by reaction with compounds containing phosphorus or sulfur · CPC title

• C08L35/00

  Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical, and containing at least one other carboxyl radical in the molecule, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers · CPC title