Method for revamping a urea production complex

Patent metadata

Field	Value
Publication number	US-10196348-B2
Application number	US-201515325050-A
Country	US
Kind code	B2
Filing date	Apr 21, 2015
Priority date	Jul 15, 2014
Publication date	Feb 5, 2019
Grant date	Feb 5, 2019

Abstract

The present invention provides a method for increasing the capacity of a urea production complex, the method comprising a step of adding to an existing urea production complex a CO 2 production unit, which unit employs a CO 2 production method comprising: i) subjecting a hydrocarbon feed to short contact time catalytic partial oxidation (SCT-CPO) to produce a first gas mixture comprising H 2 , CO and CO 2 , ii) subjecting said first gas mixture to a water gas shift reaction yielding a second gas mixture, iii) separating CO 2 from said second gas mixture yielding a purified CO 2 stream and a hydrogen containing stream and subsequently iv) reacting said purified CO 2 stream with ammonia from the ammonia production unit to produce urea. The invention also provides a urea production complex realized by the application of this method and a urea production method.

First claim

The invention claimed is:

1. A method for obtaining an improved urea production complex with increased capacity compared to an existing urea complex, the method comprising the steps of:
(a) providing an existing urea complex, said urea complex comprising a syngas production unit, an ammonia production unit and a urea production unit, which units produce respectively syngas, ammonia and urea, wherein said syngas production unit is a steam reformer and/or an autothermal reformer,
wherein said ammonia production unit is configured to produce said ammonia at least partially by a method comprising reacting nitrogen with hydrogen obtained from syngas produced in said syngas production unit,
(b) adding to said existing urea production complex a CO 2 production unit, wherein the CO 2 production unit comprises:
(i) a short contact time catalytic partial oxidation reactor (SCT-CPO reactor) provided with an inlet for a hydrocarbon feed, an inlet for an oxygen containing feed and an outlet for a first gas mixture,
(ii) a water gas shift (WGS) reactor provided with an inlet for the first gas mixture and an outlet for a second gas mixture, and
(iii) a CO 2 removal unit, provided with an inlet for the second gas mixture, an outlet for a purified CO 2 stream and an outlet for a hydrogen containing stream, wherein CO 2 is separated from the second gas mixture, and wherein the CO 2 removal unit is connected with the urea production unit so that the purified CO 2 stream obtained in the CO 2 removal unit is used as a CO 2 feed for urea production,
so as to obtain an improved urea production complex.

2. The method according to claim 1 , wherein said syngas production unit of said existing urea complex is a steam reforming unit with natural gas supply to said steam reforming unit.

3. The method according to claim 2 , wherein the capacity of the SCT-CPO in terms of CO 2 production is less than 20% of the CO 2 production capacity of the steam reforming unit.

4. A method for urea production from an ammonia feed and a carbon dioxide feed, wherein at least a portion of the carbon dioxide feed is produced by a method comprising :
i) subjecting a hydrocarbon feed to short contact time catalytic partial oxidation (SCT-CPO) to produce a first gas mixture comprising H 2 , CO and CO 2 ,
ii) subjecting said first gas mixture to a water gas shift reaction yielding a second gas mixture,
iii) separating CO 2 from said second gas mixture yielding a purified CO 2 stream and a hydrogen containing stream, and
iv) reacting CO 2 obtained in step (iii) with ammonia feed to form urea in a urea production unit which includes a syngas production unit; and
wherein said ammonia feed is at least partially produced by a method comprising reacting nitrogen with hydrogen wherein said hydrogen is produced by steam reforming and/or autothermal reforming.

5. The method of claim 4 , wherein said hydrogen containing stream is used as fuel in an auxiliary boiler, which produces steam required for the ammonia or urea synthesis, or in the syngas production unit of the urea production unit.

6. The method of claim 4 , wherein the first gas mixture is cooled by quenching with water prior to the water gas shift reaction.

7. The method of claim 6 , wherein the quench water is taken from a condensed steam stream or a process condensate stream from the urea production unit.

8. The method of claim 4 , wherein the first gas mixture is cooled by indirect heat exchange in a heat exchanger wherein the cooling medium provided to the heat exchanger is boiler feed water (BFW) from the urea production unit.

9. The method of claim 8 , wherein during the indirect heat exchange the boiler feed water is raised in pressure to produce steam with a pressure 12-22 bar and is subsequently used in the urea synthesis.

10. The method of claim 4 , wherein the SCT-CPO is performed in the presence of air as the oxygen source.

11. The method of claim 4 , wherein the purified CO 2 stream is fed to the CO 2 compressor of the urea production unit, which compresses CO 2 for use in the high pressure synthesis section of the urea production unit.

12. The method of claim 4 , wherein the purified CO 2 stream is compressed to medium pressure and fed to a medium pressure synthesis section of the urea production unit.

Assignees

• Stamicarbon B V Acting Under The Name Of Mt Innovation Center
• Stamicarbon

Inventors

• Iaquaniello Gaetano
• Dobree Joey

Classifications

• C01B2203/1241

  Natural gas or methane · CPC title

• C01B3/382

  Processes with two or more reaction steps, of which at least one is catalytic, e.g. steam reforming and partial oxidation · CPC title

• C01C1/0488

  Processes integrated with preparations of other compounds, e.g. methanol, urea or with processes for power generation · CPC title

• C01B2203/141

  At least two reforming, decomposition or partial oxidation steps in parallel · CPC title

• C01B3/48

  followed by reaction of water vapour with carbon monoxide · CPC title