Alkali metal ion source with moderate rate of ion release and methods of forming

Patent metadata

Field	Value
Publication number	US-10196317-B2
Application number	US-201615139456-A
Country	US
Kind code	B2
Filing date	Apr 27, 2016
Priority date	May 6, 2013
Publication date	Feb 5, 2019
Grant date	Feb 5, 2019

Abstract

An alkali metal ion source with a moderate rate of release of the ion (e.g. potassium) is formed by a method that includes: 1) combining an particulate ore that contains at least one of an alkali metal ion-bearing framework silicate (e.g. syenite ore) with at least one of an oxide and hydroxide of at least one of an alkali metal and alkaline earth metal such as calcium hydroxide; 2) milling the mixture of these two components optionally, with water, optionally, milling the dry components separately and blended thereafter, optionally, with water; 3) forming a mixture by adding water to the solid mixture after milling, if water was not added before milling; 4) exposing the mixture to an elevated temperature and pressure to form a gel that includes silica and the alkali metal of the framework silicate.

First claim

What is claimed is:

1. A method, comprising:
milling a combination which comprises i) a particulate alkali metal ion bearing framework silicate; and ii) a metal oxide and/or a metal hydroxide; and
after milling the combination, hydrothermally processing the combination to provide a gel,
wherein milling the combination reduces the size of the particulate alkali metal ion bearing framework silicate so that at least about 50% by weight of the particles of the particulate alkali metal ion bearing framework silicate have a diameter of equal to or less than 5 μm as measured by laser-based particle-size distribution analysis.

2. The method of claim 1 , wherein the particulate alkali metal ion bearing framework silicate comprises at least one member selected from the group consisting of lithium, sodium and potassium.

3. The method of claim 1 , wherein the particulate alkali metal ion-bearing framework silicate comprises potassium.

4. The method of claim 1 , when the particulate alkali metal ion bearing framework silicate comprises an aluminosilicate.

5. The method of claim 1 , wherein the particulate alkali metal ion bearing framework silicate comprises at least one member selected from the group consisting of potassium feldspar (KAlSi 3 O 8 ), leucite (KAlSi 2 O 6 ), kalsilite (KAlSiO 4 ) and nepheline (Na 3 KAl 4 Si 4 O 16 ).

6. The method of claim 1 , wherein the particulate alkali metal ion bearing framework silicate comprises at least about 5% by weight of an equivalent amount of K 2 O.

7. The method of claim 1 , wherein the particulate alkali metal ion bearing framework silicate comprises at least one member selected from the group consisting of syenite, nepheline syenite, and granite.

8. The method of claim 1 , wherein the metal oxide and/or a metal hydroxide comprises at least one member selected from the group consisting of an alkali metal oxide, an alkali metal hydroxide, an alkaline earth oxide and an alkaline earth hydroxide.

9. The method of claim 1 , wherein hydrothermally processing the combination comprises heating the combination to a temperature of between about 100° C. and about 350° C.

10. The method of claim 1 , wherein hydrothermally processing the combination heating the combination comprises at a pressure of between about 100 PSIG and about 500 PSIG.

11. The method of claim 1 , wherein hydrothermally processing the combination comprises exposing the combination to a pressure of between about 100 PSIG and about 500 PSIG.

12. The method of claim 1 , further comprising combining the gel with soil.

13. The method of claim 1 , comprising at least one member selected from the group consisting of dry milling the combination and wet milling the combination.

14. An alkali metal ion source formed by the method of claim 1 ,
wherein the alkali metal ion source has a Brunauer-Emmett-Teller (BET) specific surface area between about 3 m 2 /g and about 10 m 2 /g.

15. The alkali metal ion source of claim 14 , wherein the particulate alkali metal ion bearing framework silicate comprises at least one member selected from the group consisting of lithium, sodium and potassium.

16. The alkali metal ion source of claim 14 , wherein the particulate alkali metal ion bearing framework silicate comprises potassium.

17. The alkali metal ion source of claim 14 , wherein the particulate alkali metal ion bearing framework silicate comprises an aluminosilicate.

18. The alkali metal ion source of claim 14 , wherein the particulate alkali metal ion bearing silicate framework comprises at least one member selected from the group consisting of potassium feldspar (KAlSi 3 O 8 ), leucite (KAlSi 2 O 6 ), kalsilite (KAlSiO 4 ) and nepheline (Na 3 KAl 4 Si 4 O 16 ).

19. The alkali metal ion source of claim 14 , wherein the particulate alkali metal ion bearing framework silicate comprises at least about 5% by weight of an equivalent amount of K 2 O.

20. The alkali metal ion source of claim 14 , wherein the particulate alkali metal ion bearing framework silicate comprises at least one member selected from the group consisting of syenite, nepheline syenite, and granite.

Assignees

• Massachusetts Inst Technology

Inventors

• Skorina Taisiya
• Allanore Antoine

Classifications

• C05G1/00

  Mixtures of fertilisers belonging individually to different subclasses of C05 · CPC title

• C05D1/04 Primary

  from minerals or volcanic rocks · CPC title

• C01B33/26

  Aluminium-containing silicates {, i.e. silico-aluminates} · CPC title

• C05D9/00 Primary

  Other inorganic fertilisers · CPC title

• C05D9/02

  containing trace elements · CPC title