Fouling mitigation in equipment used during hydrocarbon production

Patent metadata

Field	Value
Publication number	US-10196287-B2
Application number	US-201313798572-A
Country	US
Kind code	B2
Filing date	Mar 13, 2013
Priority date	Mar 13, 2013
Publication date	Feb 5, 2019
Grant date	Feb 5, 2019

Abstract

Methods for dispersing foulants are disclosed herein. Various effective dispersant compositions are also disclosed. The dispersant composition can include a silt dispersant and a hydrocarbon dispersant. Generally, the silt dispersant can be a homopolymer or a copolymer of one or more monomers, and the monomers can be one or more of acrylic acid, methacrylic acid, α-halo acrylic acid, maleic acid, itaconic acid, vinyl acetic acid, allyl acetic acid, fumaric acid, β-carboxylic acrylate, and their salts. The silt dispersant can also be a terpolymer of acrylic acid, acrylamide, and sulfonated acrylamide. The hydrocarbon dispersant can be a non-ionic surfactant or a nonylphenol or a nonylphenol ethoxylate, such as a high EO 9 Nonyl phenol resin. Also disclosed are methods for preventing or reducing fouling in equipment that contacts water used during a hydrocarbon production process.

First claim

What is claimed is:

1. A method for dispersing a deposit, comprising:
contacting the deposit with an aqueous solution comprising a dispersant composition, wherein said dispersant composition comprises a silt dispersant and a hydrocarbon dispersant, wherein the silt dispersant is a terpolymer of acrylic acid, acrylamide, and sulfonated acrylamide, wherein the deposit comprises silt and a component selected from the group consisting of tar, grease, oil, bitumen, organic salt, naphthenate, hydrocarbon, and any combination thereof; and dispersing the deposit,
wherein the hydrocarbon dispersant is a high EO 9 Nonyl phenol resin, and
wherein the aqueous solution comprises from about 0.5 ppm to about 150 ppm of the hydrocarbon dispersant and from about 0.5 ppm to about 200 ppm of the silt dispersant, based on the volume of the aqueous solution.

2. A method for preventing or reducing fouling in equipment that contacts water used during a hydrocarbon production process, the method comprising:
adding to the water a composition comprising water, a silt dispersant and a hydrocarbon dispersant,
wherein the hydrocarbon dispersant is a high EO 9 Nonyl phenol resin, wherein the water comprises silt and a foulant selected from the group consisting of tar, grease, oil, bitumen, organic salt, naphthenale, and any combination thereof; and
preventing fouling of the equipment,
wherein the hydrocarbon dispersant is added to the water in an amount from about 0.5 ppm to about 150 ppm and the silt dispersant is added to the water in an amount from about 0.5 ppm to about 10 ppm based on volume of the composition.

3. The method of claim 2 , wherein said equipment is selected from the group consisting of evaporators, once through steam generators, and heat exchangers.

4. The method of claim 2 , wherein said silt dispersant is a homopolymer or a copolymer of one or more monomers, optionally wherein said one or more monomers are selected from the group consisting of acrylic acid, methacrylic acid, α-halo acrylic acid, maleic acid, itaconic acid, vinyl acetic acid, allyl acetic acid, fumaric acid, β-carboxylic acrylate, and any combination or salt thereof.

5. The method of claim 2 , wherein the silt dispersant comprises an acrylic acid monomer copolymerized with a member selected from the group consisting of styrene sulfonic acid, 2-acrylimido-2-methylpropylsulfonic acid, 2-methyacrylimido-2-methylpropylsulfonic acid, vinyl sulfonic acid, sulfoalkyl acrylate, sulfoalkyl methacrylate, allyl sulfonic acid, 3-methacrylamido-2-hydroxypropylsulfonic acid, and any combination or salt thereof.

6. The method of claim 2 , wherein the silt dispersant is a terpolymer of acrylic acid, acrylamide, and sulfonated acrylamide.

7. The method of claim 2 , wherein the composition is added continuously to an inlet of a heat exchanger.

8. A method for dispersing a foulant deposited on equipment, comprising:
contacting the foulant with an aqueous solution comprising water, a silt dispersant, and a hydrocarbon dispersant, wherein the silt dispersant comprises an acrylic acid monomer copolymerized with a member selected from the group consisting of styrene sulfonic acid, 2-acrylimido-2-methylpropylsulfonic acid, 2-methyacrylimido-2-methylpropylsulfonic acid, vinyl sulfonic acid, allyl sulfonic acid, 3-methacrylamido-2-hydroxypropylsulfonic acid, and any combination or salt thereof; and
wherein the foulant comprises silt and a component selected from the group consisting of tar, grease, oil, bitumen, organic salt, naphthenate, hydrocarbon, and any combination thereof;
dispersing the foulant deposited on the equipment;
wherein the hydrocarbon dispersant is a high EO 9 Nonyl phenol resin, and
wherein the hydrocarbon dispersant is added to the water in an amount from about 0.5 ppm to about 150 ppm and the silt dispersant is added to the water in an amount from about 0.5 ppm to about 10 ppm, based on volume of the aqueous solution.

9. The method of claim 1 , wherein the component is selected from the group consisting of tar, oil, bitumen, hydrocarbon, and any combination thereof.

10. The method of claim 1 , wherein the component is bitumen.

11. The method of claim 1 , wherein the component is tar.

Assignees

• Ecolab Usa Inc
• Ecolab Usa Inc

Inventors

• Gill Jasbir S
• Maharajh Edward
• Miller Thomas M

Classifications

• C02F1/682 Primary

  by addition of chemical compounds for dispersing an oily layer on water · CPC title

• C02F5/10 Primary

  using organic substances · CPC title

• C02F2103/365

  from petrochemical industry (e.g. refineries) · CPC title