Process for the production of a zeolitic material employing elemental precursors

Patent metadata

Field	Value
Publication number	US-10196275-B2
Application number	US-201314433566-A
Country	US
Kind code	B2
Filing date	Oct 1, 2013
Priority date	Oct 5, 2012
Publication date	Feb 5, 2019
Grant date	Feb 5, 2019

Abstract

The present invention relates to a process for the production of a zeolitic material having a framework structure comprising YO2, wherein said process comprises: (1) preparing a mixture comprising one or more tetravalent elements Y in elemental form, one or more organic hydroxide salts, and one or more protic solvents; (2) reacting the mixture obtained in step (1) for converting at least part of the one or more tetravalent elements Y into an oxidic form thereof containing one or more Y—O single bonds and/or one or more Y═O double bonds; and (3) crystallizing a zeolitic material from the mixture obtained in step (2).

First claim

The invention claimed is:

1. A process for producing a zeolitic material having a framework structure comprising YO 2 , the process comprising:
(1) preparing a first mixture comprising two or more tetravalent elements Y in elemental form, organic hydroxide salts, and one or more protic solvents;
(2) reacting the first mixture for converting at least part of the tetravalent elements Y into an oxidic form thereof comprising Y—O single bonds and/or Y═O double bonds, thereby obtaining a second mixture; and
(3) crystallizing a zeolitic material from the second mixture, thereby obtaining a crystallization product, wherein the crystalizing is conducted under solvothermal conditions;
wherein the tetravalent elements Y comprise a mixture of Si and Ti,
wherein both Si and Ti are in elemental forms, and
wherein after (2) and prior to (3) the second mixture is freed from solid matter.

2. The process of claim 1 , wherein the first mixture further comprises one or more trivalent elements X in elemental form for producing a zeolitic material having a framework structure comprising YO 2 and X 2 O 3 , and wherein in (2) at least part of the one or more trivalent elements X is converted into an oxidic form thereof.

3. The process of claim 2 , wherein the one or more trivalent elements X in elemental form are selected from the group consisting of Al, B, In, Ga, and a mixture of two or more thereof.

4. The process of claim 2 , wherein after (2) and prior to (3) one or more sources for X 2 O 3 are further added to the second mixture for producing a zeolitic material having a framework structure comprising YO 2 and X 2 O 3 .

5. The process of claim 4 , wherein X in the one or more sources for X 2 O 3 are selected from the group consisting of Al, B, In, Ga, and a mixture of two or more thereof.

6. The process of claim 2 , wherein in the second mixture crystallized in (3) a molar ratio of a total amount of the tetravalent elements Y to a total amount of the one or more trivalent elements X ranges from 1 to 1,000.

7. The process of claim 1 , wherein after (2) and prior to (3) one or more sources for YO 2 are further added to the second mixture.

8. The process of claim 7 , wherein Y in the one or more sources for YO 2 is selected from the group consisting of Si, Sn, Ti, Zr, Ge, and a mixture of two or more thereof.

9. The process of claim 1 , wherein the second mixture crystallized in (3) comprises 1 wt. % or less of one or more elements M based on 100 wt. % of the tetravalent elements Y calculated as the elements, wherein M stands for at least one of sodium and potassium.

10. The process of claim 9 , wherein M stands for sodium and potassium.

11. The process of claim 1 , wherein the one or more protic solvents comprise one or more solvents selected from the group consisting of an alkanol, water, and a mixture of two or more thereof.

12. The process of claim 1 , wherein a pH of the second mixture in (3) ranges from 13 to 16.

13. The process of claim 1 , wherein the one or more organic hydroxide salts comprises one or more cationic organotemplates.

14. The process of claim 1 , wherein in the first mixture a molar ratio of a total amount of the one or more organic hydroxide salts to a total amount of the tetravalent elements Y in elemental form ranges from 0.1 to 15.

15. The process of claim 1 , wherein the reacting (2) involves heating of the first mixture.

16. The process of claim 1 , wherein the crystallizing (3) involves heating of the second mixture.

17. The process of claim 1 , said process further comprising at least one of
(4) isolating the zeolitic material;
(5) washing the zeolitic material;
(6) drying, calcining, or both drying and calcining the zeolitic material;
and
(7) subjecting the zeolitic material to an ion-exchange procedure.

18. The process of claim 17 , wherein after (3) and prior to (4) a pH of the crystallization product is adjusted to a pH in a range of from 5 to 9.

19. The process of claim 17 , wherein the-process comprises the calcining (6), which is conducted at a temperature in a range of 300 to 850° C.

Assignees

• Basf Se

Inventors

• Maurer Stefan
• Ruetz Roger
• Petry Julia
• Mueller Ulrich

Classifications

• B01J20/18

  Synthetic zeolitic molecular sieves · CPC title

• C01B39/12

  the replacing atoms being {at least} boron atoms · CPC title

• C07D301/12

  with hydrogen peroxide or inorganic peroxides or peracids · CPC title

• B01J29/035

  {Microporous crystalline materials not having base exchange properties, such as} silica polymorphs, e.g. silicalites · CPC title

• C01B37/02

  Crystalline silica-polymorphs, e.g. silicalites {dealuminated aluminosilicate zeolites} · CPC title