System for preparing nanoparticles by supercritical hydrothermal synthesis

Patent metadata

Field	Value
Publication number	US-10195671-B2
Application number	US-201415301388-A
Country	US
Kind code	B2
Filing date	Nov 10, 2014
Priority date	Apr 2, 2014
Publication date	Feb 5, 2019
Grant date	Feb 5, 2019

Abstract

A system for preparing nanoparticles by supercritical hydrothermal synthesis is provided. Firstly, a mixture of a first reactant and a second reactant and high-temperature water at an outlet of a heating furnace ( 10 ) are mixed and are heated to a reaction temperature, the mixture is connected to a supercritical hydrothermal synthesis reactor ( 14 ), and a product at an outlet of the supercritical hydrothermal synthesis reactor enters a heat regenerator ( 9 ); hot water at an outlet of a low-temperature section of the heating furnace ( 10 ) first enters the heat regenerator, and then enters a high-temperature section of the heating furnace so as to be continuously heated to a set temperature; fluid at the pipe side outlet of the heat regenerator separately passes through a heat exchange coil in a first reactant modulation pool ( 1 ) and a steam generator ( 2 ) in a waste heat power generation system ( 20 ).

First claim

What is claimed is:

1. A system for preparing nanoparticles by supercritical hydrothermal synthesis, comprising a first reactant modulation pool ( 1 ), a steam generator ( 2 ), a back pressure valve ( 4 ), a gas-liquid separator ( 5 ), a centrifugal separator ( 6 ), an oil-water separator ( 7 ), a heat regenerator ( 9 ), a heating furnace ( 10 ), a first material pump ( 11 ), a premixer ( 12 ), a mixer ( 13 ), a supercritical hydrothermal synthesis reactor ( 14 ), a second material pump ( 16 ), a pure water pump ( 17 ), a pure water storage tank ( 18 ), a second reactant storage pool ( 19 ), and a waste heat power generation system ( 20 ), wherein:
an outlet of the first reactant modulation pool ( 1 ) is communicated with an inlet of the first material pump ( 11 ), an outlet of the first material pump ( 11 ) is communicated with a first inlet of the premixer ( 12 );
an outlet of the second reactant storage pool ( 19 ) is communicated with an inlet of the second material pump ( 16 ), an outlet of the second material pump ( 16 ) is communicated with a second inlet of the premixer ( 12 ), and an outlet of the premixer ( 12 ) is communicated with a vertical inlet of the mixer ( 13 );
an outlet of the pure water storage tank ( 18 ) is communicated with an inlet of the pure water pump ( 17 ), an outlet of the pure water pump ( 17 ) is communicated with a low-temperature section inlet of the heating furnace ( 10 ), a low-temperature section outlet of the heating furnace ( 10 ) is communicated with a casing side inlet of the heat regenerator ( 9 ), a casing side outlet of the heat regenerator ( 9 ) is communicated with a high-temperature section inlet of the heating furnace ( 10 ), a high-temperature section outlet of the heating furnace ( 10 ) is communicated with a high-temperature water inlet of the mixer ( 13 ), a vertical outlet of the mixer ( 13 ) is communicated with an inlet of the supercritical hydrothermal synthesis reactor ( 14 ), an outlet of the supercritical hydrothermal synthesis reactor ( 14 ) is communicated with a pipe side inlet of the heat regenerator ( 9 ), a pipe side outlet of the heat regenerator ( 9 ) is divided into two portions, one portion is communicated with an inlet of a heat exchange coil in the first reactant modulation pool ( 1 ), the other portion is merged with an outlet of the heat exchange coil and then communicated with an inlet of the steam generator ( 2 ) in the waste heat power generation system ( 20 ), an outlet of the steam generator ( 2 ) is communicated with an inlet of the back pressure valve ( 4 ), an outlet of the back pressure valve ( 4 ) is communicated with an inlet of the centrifugal separator ( 6 ), an outlet of the centrifugal separator ( 6 ) is communicated with an oil-phase inlet of the oil-water separator ( 7 ), an oil-phase outlet of the oil-water separator ( 7 ) is communicated with an inlet of the second reactant storage pool ( 19 ).

2. The system for preparing nanoparticles by supercritical hydrothermal synthesis, as recited in claim 1 , further comprising a desalination device ( 15 ) which is located at a pipeline where the outlet of the supercritical hydrothermal synthesis reactor ( 14 ) is communicated with the pipe side inlet of the heat regenerator ( 9 ), the outlet of the supercritical hydrothermal synthesis reactor ( 14 ) is communicated with an inlet of the desalination device ( 15 ), and an outlet of the desalination device ( 15 ) is communicated with the pipe side inlet of the heat regenerator ( 9 ).

3. The system for preparing nanoparticles by supercritical hydrothermal synthesis, as recited in claim 1 , further comprising a desalination device ( 15 ) which is located at a pipeline where the outlet of the centrifugal separator ( 6 ) is communicated with the oil-phase inlet of the oil-water separator ( 7 ), the outlet of the centrifugal separator ( 6 ) is communicated with an inlet of the desalination device ( 15 ), and an outlet of the desalination device ( 15 ) is communicated with the oil-phase inlet of the oil-water separator ( 7 ).

4. The system for preparing nanoparticles by supercritical hydrothermal synthesis, as recited in claim 1 , further comprising a pipeline filter ( 3 ) which is located at a pipeline where the outlet of the steam generator ( 2 ) is communicated with the inlet of the back pressure valve ( 4 ), the outlet of the steam generator ( 2 ) is communicated with an inlet of the pipeline filter ( 3 ), and an outlet of the pipeline filter ( 3 ) is communicated with the inlet of the back pressure valve ( 4 ).

5. The system for preparing nanoparticles by supercritical hydrothermal synthesis, as recited in claim 2 , further comprising a pipeline filter ( 3 ) which is located at a pipeline where the outlet of the steam generator ( 2 ) is communicated with the inlet of the back pressure valve ( 4 ), the outlet of the steam generator ( 2 ) is communicated with an inlet of the pipeline filter ( 3 ), and an outlet of the pipeline filter ( 3 ) is communicated with the inlet of the back pressure valve ( 4 ).

6. The system for preparing nanoparticles by supercritical hydrothermal synthesis, as recited in claim 3 , further comprising a pipeline filter ( 3 ) which is located at a pipeline where the outlet of the steam generator ( 2 ) is communicated with the inlet of the back pressure valve ( 4 ), the outlet of the steam generator ( 2 ) is communicated with an inlet of the pipeline filter ( 3 ), and an outlet of the pipeline filter ( 3 ) is communicated with the inlet of the back pressure valve ( 4 ).

7. The system for preparing nanoparticles by supercritical hydrothermal synthesis, as recited in claim 1 , further comprising a fine filtration unit ( 8 ) which is located at a pipeline where a water-phase outlet of the oil-water separator ( 7 ) is communicated with the oil-phase inlet of the oil-water separator ( 7 ), the water-phase outlet of the oil-water separator ( 7 ) is communicated with an inlet of the fine filtration unit ( 8 ), and an outlet of the fine filtration unit ( 8 ) is communicated with the oil-phase inlet of the oil-water separator ( 7 ).

8. The system for preparing nanoparticles by supercritical hydrothermal synthesis, as recited in claim 2 , further comprising a fine filtration unit ( 8 ) which is located at a pipeline where a water-phase outlet of the oil-water separator ( 7 ) is communicated with the oil-phase inlet of the oil-water separator ( 7 ), the water-phase outlet of the oil-water separator ( 7 ) is communicated with an inlet of the fine filtration unit ( 8 ), and an outlet of the fine filtration unit ( 8 ) is communicated with the oil-phase inlet of the oil-water separator ( 7 ).

9. The system for preparing nanoparticles by supercritical hydrothermal synthesis, as recited in claim 6 , further comprising a fine filtration unit ( 8 ) which is located at a pipeline where a water-phase outlet of the oil-water separator ( 7 ) is communicated with the oil-phase inlet of the oil-water separator ( 7 ), the water-phase outlet of the oil-water separator ( 7 ) is communicated with an inlet of the fine filtration unit ( 8 ), and an outlet of the fine filtration unit ( 8 ) is communicated with the oil-phase inlet of the oil-water separator ( 7 ).

10. The system for preparing nanoparticles by supercritical hydrothermal synthesis, as recited in claim 1 , wherein: a regulating valve is located at a pipeline of the pipe side outlet of the heat regenerator ( 9 ).

11. The system for preparing nanoparticles by supercritical hydrothermal synthesis, as recited in claim 2 , wherein: a regulating valve is located at a pipeline of the pipe side outlet of the heat regenerator ( 9 ).

12. The system for preparing nanoparticles by s

Assignees

• Univ Xi An Jiaotong
• Xian Wonfu Energy And Environment Tech Co Ltd

Inventors

• Wang Shuzhong
• Zhou Lu
• Gong Yanmeng
• Qian Lili
• Ren Mengmeng
• Li Yanhui

Classifications

• B22F1/054

  Nanosized particles · CPC title

• B01D21/26

  Separation of sediment aided by centrifugal force {or centripetal force}(centrifuges B04B; cyclones B04C) · CPC title

• B01D19/0068

  General arrangements, e.g. flowsheets (B01D19/0063 takes precedence) · CPC title

• B22F2201/05

  Water or water vapour · CPC title

• B22F9/24 Primary

  starting from liquid metal compounds, e.g. solutions · CPC title