Inner liner barrier from multilayer thin film

Patent metadata

Field	Value
Publication number	US-10195642-B2
Application number	US-201214369947-A
Country	US
Kind code	B2
Filing date	Dec 28, 2012
Priority date	Dec 30, 2011
Publication date	Feb 5, 2019
Grant date	Feb 5, 2019

Abstract

A tire has a coating with a quadlayer or multiple quadlayers, and a method produces the same. In an embodiment, the method for coating a rubber substrate includes exposing the rubber substrate to a first cationic solution to produce a first cationic layer on the rubber substrate. The method also includes exposing the first cationic layer to a first anionic solution to produce a first anionic layer on the first cationic layer. In addition, the method includes exposing the first anionic layer to a second cationic solution to produce a second cationic layer on the first anionic layer. The method further includes exposing the second cationic layer to a second anionic solution to produce a second anionic layer on the second cationic layer. A quadlayer includes the first cationic layer, the first anionic layer, the second cationic layer, and the second anionic layer. The coating includes the quadlayer.

First claim

What is claimed is:

1. A method for coating a rubber substrate, comprising:
(A) exposing the rubber substrate to a first cationic solution comprising polyethylene oxide to produce a first cationic layer on the rubber substrate;
(B) exposing the first cationic layer to a first anionic solution to produce a first anionic layer on the first cationic layer;
(C) exposing the first anionic layer to a second cationic solution comprising polyethylenimine to produce a second cationic layer on the first anionic layer; and
(D) exposing the second cationic layer to a second anionic solution to produce a second anionic layer on the second cationic layer, wherein a quadlayer comprises the first cationic layer, the first anionic layer, the second cationic layer, and the second anionic layer, wherein the coating comprises the quadlayer, wherein the coating has a gas transmission rate between 0.03 cc/(m 2 *day*atm) and 100 cc/(m 2 *day*atm), wherein a pH of the first anionic solution and the second anionic solution is between about 1 to about 7, and wherein a pH of the first cationic solution and the second cationic solution is between about 3 to about 12, and wherein the pH of the first cationic solution is greater than the pH of the first anionic solution, the second cationic solution, and the second anionic solution.

2. The method of claim 1 , wherein the first cationic solution and the second cationic solution comprise cationic materials.

3. The method of claim 2 , wherein the cationic materials comprise a polymer, a colloidal particle, a nanoparticle, or any combinations thereof.

4. The method of claim 3 , wherein the polymer comprises a cationic polymer, a polymer with hydrogen bonding, or any combinations thereof.

5. The method of claim 4 , wherein the cationic polymer comprises branched polyethylenimine, linear polyethylenimine, cationic polyacrylamide, cationic polydiallyldimethylammonium chloride, poly(allyl amine), poly(allyl amine) hydrochloride, poly(vinyl amine), poly(acrylamide-co-diallyldimethyl ammonium chloride), or any combinations thereof.

6. The method of claim 1 , wherein the first anionic solution and the second anionic solution comprise layerable materials.

7. The method of claim 6 , wherein the layerable materials comprise an anionic polymer, a colloidal particle, or any combinations thereof.

8. The method of claim 7 , wherein the anionic polymer comprises a polystyrene sulfonate, a polymethacrylic acid, a polyacrylic acid, a poly(acrylic acid, sodium salt), a polyanetholesulfonic acid sodium salt, poly(vinylsulfonic acid, sodium salt), or any combinations thereof.

9. The method of claim 7 , wherein the colloidal particle comprises a clay, a colloidal silica, an inorganic hydroxide, a silicon based polymer, a polyoligomeric silsesquioxane, a carbon nanotube, a graphene, or any combinations thereof.

10. The method of claim 1 , wherein the first cationic layer comprises polyethylene oxide, the first anionic layer comprises polyacrylic acid, the second cationic layer comprises polyethylenimine, and the second anionic layer comprises sodium montmorillonite.

11. The method of claim 1 , wherein the rubber substrate further comprises a primer layer disposed between the rubber substrate and the first cationic layer.

12. The method of claim 11 , wherein the primer layer comprises a bilayer, wherein the bilayer comprises a first primer layer comprising a cationic layer and a second primer layer comprising an anionic layer.

13. The method of claim 1 , further comprising repeating steps (A), (B), (C), and (D) to produce a plurality of quadlayers, wherein the coating comprises the plurality of quadlayers.

14. The method of claim 1 , wherein the rubber substrate comprises a portion of a tire.

15. A method for coating a rubber substrate, comprising:
(A) exposing the rubber substrate to a first anionic solution to produce a first anionic layer on the rubber substrate;
(B) exposing the first anionic layer to a first cationic solution comprising polyethylene oxide to produce a first cationic layer on the first anionic layer;
(C) exposing the first cationic layer to a second anionic solution to produce a second anionic layer on the first cationic layer; and
(D) exposing the second anionic layer to a second cationic solution comprising polyethylenimine to produce a second cationic layer on the second anionic layer, wherein a quadlayer comprises the first anionic layer, the first cationic layer, the second anionic layer, and the second cationic layer wherein the coating comprises the quadlayer; wherein the coating has a gas transmission rate between 0.03 cc/(m 2 *day*atm) and 100 cc/(m 2 *day*atm), wherein a pH of the first anionic solution and the second anionic solution is between about 1 to about 7, wherein the pH of the first cationic solution and the second cationic solution is between about 3 to about 12, and wherein the pH of the first cationic solution is greater than the pH of the first anionic solution, the second cationic solution, and the second anionic solution.

16. A method for coating a rubber substrate, comprising:
(A) exposing the rubber substrate to a first solution comprising polyethyleneimine to produce a first layer on the rubber substrate;
(B) exposing the first layer to a second solution comprising polyethylene oxide a second layer on the first layer;
(C) exposing the second layer to a third solution comprising polyacrylic acid to produce a third layer on the first second layer; and
(D) exposing the third layer to a fourth solution comprising sodium montmorillonite to produce a fourth layer on the third layer, wherein the first solution has a pH that is greater than a pH of the second solution, the third solution, and the fourth solution.

17. The method of claim 16 wherein the rubber substrate comprises a portion of a tire.

Assignees

• Michelin & Cie
• Texas A & M Univ Sys
• Michelin & Cie

Inventors

• Grunlan Jaime C
• Priolo Morgan A
• Bergman Brian R
• Mchugh John J

Classifications

• Y10T428/31826

  Of natural rubber · CPC title

• B32B2307/308

  Heat stability · CPC title

• B32B27/06

  as the main or only constituent of a layer, {which is} next to another layer of {the same or of} a {different material (next to a layer of a particular substance B32B9/045; next to a bituminous or tarry layer B32B11/046; next to a water setting substance layer B32B13/12; next to a metal layer B32B15/08; next to a glass layer B32B17/10; next to a layer formed of natural mineral fibres or particles B32B19/045; next to a wood layer B32B21/08; next to a cellulosic plastic layer B32B23/08; next to a natural or synthetic rubber layer B32B25/08)} · CPC title

• B32B2264/02

  Synthetic macromolecular particles · CPC title

• B32B25/00

  Layered products comprising {a layer of} natural or synthetic rubber {(fibrous or filamentary layer made of a natural or synthetic rubber B32B5/02; particulate layer made of a natural or synthetic rubber B32B5/16; foamed layer made of a natural or synthetic rubber B32B5/18)} · CPC title