Methods and systems for treating a switchable polarity material, and related methods of liquid treatment

Patent metadata

Field	Value
Publication number	US-10195543-B2
Application number	US-201615177528-A
Country	US
Kind code	B2
Filing date	Jun 9, 2016
Priority date	Jun 9, 2016
Publication date	Feb 5, 2019
Grant date	Feb 5, 2019

Abstract

A method of treating a switchable polarity material comprises introducing a first feed stream comprising a solvent and a non-polar form of the switchable polarity material to a first side of a gas diffusion membrane. A second feed stream comprising an acid gas is introduced to a second side of the gas diffusion membrane opposing the first side of the gas diffusion membrane. Molecules of the acid gas of the second feed stream are diffused across the gas diffusion membrane and into the first feed stream to form a product stream comprising a polar form of the switchable polarity material. A treatment system for a switchable polarity material, and a method of liquid treatment are also described.

First claim

What is claimed is:

1. A method of treating a switchable polarity material comprising:
introducing a first feed stream comprising water and a non-polar form of the switchable polarity material to a first side of a gas diffusion membrane;
introducing a second feed stream comprising an acid gas to a second side of the gas diffusion membrane opposing the first side of the gas diffusion membrane; and
diffusing molecules of the acid gas of the second feed stream across the gas diffusion membrane and into the first feed stream to react with the water and the non-polar form of the switchable polarity material and form a product stream comprising a polar form of the switchable polarity material.

2. The method of claim 1 , further comprising: selecting the non-polar form of the switchable polarity material of the first feed stream to comprise one or more of an amine compound, an amidine compound, and a guanidine compound.

3. The method of claim 2 , wherein selecting the non-polar form of the switchable polarity material of the first feed stream to comprise one or more of an amine compound, an amidine compound, and a guanidine compound comprises selecting the non-polar form of the switchable polarity material to comprise a tertiary amine compound having a ratio of nitrogen to carbon within a range of from about 1:2 to about 1:15.

4. The method of claim 2 , further comprising selecting the acid gas of the second feed stream to comprise one or more of carbon dioxide, carbon disulfide, and carbonyl sulfide.

5. The method of claim 2 , wherein diffusing molecules of the acid gas of the second feed stream across the gas diffusion membrane and into the first feed stream to form a product stream comprising a polar form of the switchable polarity material comprises diffusing molecules of carbon dioxide across the gas diffusion membrane and into the first feed stream to form one or more an aminium bicarbonate, an aminium alkyl carbonate, an amidinium bicarbonate, an aminium alkyl carbonate, a guanidinium bicarbonate, and a guanidinium alkyl carbonate.

6. The method of claim 1 , further comprising controlling one or more of a temperature, a pressure, and a flow rate of each of the first feed stream and the second feed stream to form greater than or equal to about 4.0 mol/kg of the polar form of the switchable polarity material in the product stream in less than or equal to about 4 hours.

7. The method of claim 1 , further comprising selecting the gas diffusion membrane to exhibit a size, a shape, a material composition, and a porosity effectuating the diffusion of the molecules of the acid gas of the second feed stream into the first feed stream at a rate permitting the acid gas to substantially remain in solution with the water of the first feed stream until the formation of the non-polar form of the switchable polarity material.

8. The method of claim 1 , further comprising selecting the gas diffusion membrane to comprise a substantially hydrophobic material formulated to prevent release of components thereof into the first feed stream.

9. The method of claim 8 , further comprising selecting the gas diffusion membrane to further comprise at least one material that catalyzes the formation of the polar form of the switchable polarity material from the water and the non-polar form of the switchable polarity material of the first feed stream and the acid gas of the second feed stream.

10. The method of claim 1 , wherein the first feed stream further comprises at least one additive comprising one or more of a homogeneous material and a heterogeneous material.

11. The method of claim 10 , wherein diffusing molecules of the acid gas of the second feed stream across the gas diffusion membrane and into the first feed stream to form a product stream comprising a polar form of the switchable polarity material comprises forming the product stream to comprise a first phase comprising the polar form of the switchable polarity material and a second phase comprising the at least one additive.

12. The method of claim 1 , further comprising recycling at least a portion of the product stream into the first feed stream upstream of the gas diffusion membrane.

13. The method of claim 1 , further comprising:
introducing the product stream to a first side of an additional gas diffusion membrane downstream of the gas diffusion membrane;
introducing a third feed stream comprising the acid gas to a second side of the additional gas diffusion membrane opposing the first side of the additional gas diffusion membrane; and
diffusing molecules of the acid gas of the third feed stream across the additional gas diffusion membrane and into the product stream to form an additional product stream comprising a greater concentration of the polar form of the switchable polarity material than the product stream.

14. A treatment system for a switchable polarity material, comprising:
a source of a non-polar form of the switchable polarity material;
a source of an acid gas; and
a gas diffusion membrane apparatus in fluid communication with the source of the non-polar form of the switchable polarity material and the source of the acid gas and comprising a housing structure and a gas diffusion membrane within the housing structure, the gas diffusion membrane apparatus configured to separately receive the non-polar form of the switchable polarity material and the acid gas on opposing sides of the gas diffusion membrane and to diffuse molecules of the acid gas through the gas diffusion membrane to convert at least some of the non-polar form of the switchable polarity material and into a polar form of the switchable polarity material, the gas diffusion membrane comprising at least one hydrophobic material and at least one catalyst material formulated to promote the conversion of the non-polar form of the switchable polarity material into the polar form of the switchable polarity material.

15. The treatment system of claim 14 , wherein:
the non-polar form of the switchable polarity material is selected from the group consisting of an amine compound, an amidine compound, and a guanidine compound; and
the acid gas comprises carbon dioxide.

16. The treatment system of claim 14 , wherein the gas diffusion membrane exhibits one or more of a cuboidal shape and a tubular shape.

17. The treatment system of claim 14 , wherein the gas diffusion membrane exhibits pores extending in tortuous paths throughout a thickness of the gas diffusion membrane, each of the pores independently exhibiting an average pore size of less than or equal to about 500 nanometers.

18. The treatment system of claim 14 , further comprising an additional gas diffusion membrane apparatus downstream of the gas diffusion membrane and comprising an additional gas diffusion membrane within an additional housing structure, the additional gas diffusion membrane apparatus configured to receive the polar form of the switchable polarity material and any remaining non-polar form of the switchable polarity material exiting the gas diffusion membrane apparatus on a first side of the additional gas diffusion membrane and additional acid gas on a second, opposing side of the additional gas diffusion membrane, and to diffuse molecules of the additional acid gas through the additional gas diffusion membrane to convert at least some of the remaining non-polar form of the switchable polarity material and into an additional amount of the polar form of the switchable polarity material.

19. A method of liquid treatment, comprising:
delivering a multiphase mixture c

Assignees

• Battelle Energy Alliance Llc

Inventors

• Wilson Aaron D
• Wendt Daniel S
• Orme Christopher J
• Mines Gregory L
• Jones Michael G
• Adhikari Birendra

Classifications

• B01D53/225

  Multiple stage diffusion · CPC title

• B01D69/02

  characterised by their properties · CPC title

• B01D2325/38

  Hydrophobic membranes · CPC title

• B01D2313/42

  Catalysts within the flow path · CPC title

• B01D2251/80

  Organic bases or salts · CPC title