Polymer on graphene

Patent metadata

Field	Value
Publication number	US-10192971-B2
Application number	US-201715419719-A
Country	US
Kind code	B2
Filing date	Jan 30, 2017
Priority date	Nov 25, 2013
Publication date	Jan 29, 2019
Grant date	Jan 29, 2019

Abstract

A top-gated graphene field effect transistor can be fabricated by forming a layer of graphene on a substrate, and applying an electrochemical deposition process to deposit a layer of dielectric polymer on the graphene layer. An electric potential between the graphene layer and a reference electrode is cycled between a lower potential and a higher potential. A top gate is formed above the polymer.

First claim

What is claimed is:

1. A graphene transistor comprising:
a substrate;
a layer of graphene on the substrate;
a layer of dielectric polymer comprising poly(phenylene oxide) on the graphene layer; and
a top gate above the polymer.

2. The transistor of claim 1 in which the graphene layer is patterned to form a channel, and the transistor further comprises drain and source electrodes that are electrically coupled to the graphene.

3. The transistor of claim 1 , comprising a layer of second dielectric material on the dielectric polymer layer, the second dielectric material having a dielectric constant that is higher than the dielectric constant of the polymer.

4. The transistor of claim 1 in which the dielectric polymer layer has a thickness that is less than 10 nm.

5. An apparatus comprising:
a substrate;
a layer of two-dimensional material on the substrate; and
a layer of polymer on the layer of two-dimensional material, the polymer comprising poly(phenylene oxide).

6. The apparatus of claim 5 in which the two-dimensional material comprises graphene.

7. The apparatus of claim 6 comprising a drain electrode, a source electrode, and a top gate, in which the layer of graphene is disposed between the drain and source electrodes and is configured to function as a channel, and the top gate is disposed above the layer of polymer.

8. The apparatus of claim 7 , comprising a dielectric layer disposed between the polymer layer and the top gate.

9. The apparatus of claim 8 in which the dielectric layer comprises a dielectric that has a dielectric constant that is higher than the dielectric constant of the polymer.

10. The apparatus of claim 6 in which the layer of graphene comprises a monolayer of graphene.

11. The apparatus of claim 5 in which the polymer layer has a thickness in a range between 500 nm to 1 μm.

12. The apparatus of claim 5 in which the polymer layer has a thickness in a range from 100 nm to 500 nm.

13. The apparatus of claim 5 in which the polymer layer has a thickness in a range from 10 nm to 100 nm.

14. The apparatus of claim 5 in which the polymer layer has a thickness less than 10 nm.

15. The apparatus of claim 5 in which the two-dimensional material comprises phosphorene.

16. The apparatus of claim 15 in which the polymer layer covers the phosphorene to prevent oxidation of the phosphorene.

17. An apparatus comprising:
a substrate;
a layer of two-dimensional material on the substrate, in which the two-dimensional material is at least one of a conducting or a semiconducting material; and
a dielectric polymer formed on the layer of two-dimensional material in which the dielectric polymer comprises poly(phenylene oxide).

18. The apparatus of claim 17 in which the two-dimensional material comprises graphene.

19. The apparatus of claim 17 in which the two-dimensional material comprises phosphorene.

20. The apparatus of claim 17 , comprising a layer of dielectric material on the polymer layer, the dielectric material having a dielectric constant that is higher than the dielectric constant of the polymer layer.

21. The graphene transistor of claim 1 in which the top gate comprises a conducting polymer.

22. The graphene transistor of claim 1 in which the top gate comprises poly(3,4-ethylenedioxythiophene) (PEDOT).

23. The apparatus of claim 5 , comprising a layer of dielectric material on the polymer layer, the dielectric material having a dielectric constant that is higher than the dielectric constant of the polymer layer.

24. An organic flexible electronic device comprising:
a substrate;
a layer of graphene on the substrate;
a layer of dielectric polymer comprising poly(phenylene oxide) on the graphene layer;
a layer of second dielectric material on the layer of dielectric polymer, the second dielectric materials having a dielectric constant that is higher than the dielectric constant of the polymer; and
a top gate above the layer of second dielectric material, in which the top gate comprises a conducting polymer.

25. The organic flexible electronic device of claim 24 in which the top gate comprises poly(3,4-ethylenedioxythiophene) (PEDOT).

26. The apparatus of claim 24 in which the layer of graphene comprises a monolayer of graphene.

27. An apparatus comprising:
a substrate;
a layer of two-dimensional material on the substrate, in which the two-dimensional material is at least one of a conducting or a semiconducting material, and in which the two-dimensional material comprises phosphorene; and
a dielectric polymer formed on the layer of two-dimensional material by applying an electrochemical deposition process to deposit the dielectric polymer on the two-dimensional material, in which a rate of deposition of the dielectric polymer at a given location of the two-dimensional material decreases as a thickness of the dielectric polymer layer increases.

28. The apparatus of claim 27 in which the dielectric polymer comprises poly(phenylene oxide).

29. The apparatus of claim 27 in which the two-dimensional material comprises graphene.

30. The apparatus of claim 27 , comprising a layer of dielectric material on the polymer layer, the dielectric material having a dielectric constant that is higher than the dielectric constant of the polymer layer.

Assignees

• Nutech Ventures

Inventors

• Redepenning Jody G
• Sinitskii Alexander
• Wymore Benjamin

Classifications

• H10P14/3406

  Carbon, e.g. diamond-like carbon · CPC title

• H10P14/2923

  being conductive materials, e.g. metallic silicides · CPC title

• H10P14/24

  using chemical vapour deposition [CVD] · CPC title

• H10P14/6342

  Liquid deposition, e.g. spin-coating, sol-gel techniques or spray coating · CPC title

• H10P14/683

  carbon-based polymeric organic materials, e.g. polyimides, poly cyclobutene or PVC · CPC title