Electrophotographic photosensitive member, process cartridge, and image forming apparatus

Patent metadata

Field	Value
Publication number	US-10191397-B2
Application number	US-201715668774-A
Country	US
Kind code	B2
Filing date	Aug 4, 2017
Priority date	Aug 10, 2016
Publication date	Jan 29, 2019
Grant date	Jan 29, 2019

Abstract

An electrophotographic photosensitive member includes a conductive substrate and a photosensitive layer. The photosensitive layer is a single-layer photosensitive layer. The photosensitive layer contains a charge generating material, a hole transport material, an electron transport material, and a binder resin. The binder resin contains a polyarylate resin. The polyarylate resin is represented by general formula (1). The hole transport material contains a compound represented by general formula (HTM1), (HTM2), (HTM3), (HTM4), (HTM5), (HTM6), or (HTM7). The photosensitive layer has a scratch resistance depth of no greater than 0.50 μm. The photosensitive layer has a Vickers hardness of at least 17.0 HV.

First claim

What is claimed is:

1. An electrophotographic photosensitive member comprising a conductive substrate and a photosensitive layer, wherein
the photosensitive layer is a single-layer photosensitive layer,
the photosensitive layer contains a charge generating material, a hole transport material, an electron transport material, and a binder resin,
the binder resin contains a polyarylate resin,
a combination of the polyarylate resin and the hole transport material is either:
a combination of a polyarylate resin represented by a chemical formula (R-2) and a hole transport material represented by a chemical formula (HTM2-1); or
a combination of a polyarylate resin represented by a chemical formula (R-3) and a hole transport material represented by a chemical formula (HTM6-1),

the photosensitive layer has a scratch resistance depth of no greater than 0.50 μm,
the photosensitive layer has a Vickers hardness of at least 17.0 HV,
the scratch resistance depth of the photosensitive layer is measured by a measurement method using a scratching apparatus,
the scratching apparatus includes a scratching stylus and a fixing table having an upper surface in a rectangular shape,
the scratching stylus has a hemispherical sapphire tip end having a diameter of 1 mm, and
the measurement method includes:
fixing the electrophotographic photosensitive member onto the upper surface of the fixing table such that a longitudinal direction of the electrophotographic photosensitive member is parallel to a longitudinal direction of the fixing table;
bringing the scratching stylus into perpendicular contact with a surface of the photosensitive layer;
forming a scratch on the surface of the photosensitive layer by the scratching stylus in a manner that the fixing table and the electrophotographic photosensitive member fixed on the upper surface of the fixing table are moved by 30 mm at a speed of 30 mm/minute while 10 g of a load is applied to the photosensitive layer through the scratching stylus in perpendicular contact with the surface of the photosensitive layer; and
measuring the scratch resistance depth that is a maximum depth of the scratch,

2. The electrophotographic photosensitive member according to claim 1 , wherein
the electron transport material is represented by general formula (ETM1),

where, in the general formula (ETM1),
R 42 and R 43 each represent, independently of one another, an alkyl group having 1 to 6 carbon atoms or an alkoxy group having 1 to 6 carbon atoms.

3. The electrophotographic photosensitive member according to claim 2 , wherein
in the general formula (ETM1), R 42 and R 43 each represent, independently of one another, an alkyl group having 1 to 5 carbon atoms.

4. The electrophotographic photosensitive member according to claim 1 , wherein
the charge generating material is X-form metal-free phthalocyanine.

5. A process cartridge comprising the electrophotographic photosensitive member according to claim 1 .

6. An image forming apparatus comprising:
an image bearing member;
a charger configured to charge a surface of the image bearing member;
an exposure section configured to expose the charged surface of the image bearing member to form an electrostatic latent image on the surface of the image bearing member;
a developing device configured to develop the electrostatic latent image into a toner image; and
a transfer section configured to transfer the toner image from the image bearing member to a recording medium, wherein
the image bearing member is the electrophotographic photosensitive member according to claim 1 ,
the charger has a positive charge polarity, and
the transfer section transfers the toner image to the recording medium in a state in which the surface of the image bearing member is in contact with the recording medium.

7. The image forming apparatus according to claim 6 , wherein
the developing device develops the electrostatic latent image into the toner image while in contact with the surface of the image bearing member.

8. The image forming apparatus according to claim 6 , wherein
the developing device cleans the surface of the image bearing member.

9. The image forming apparatus according to claim 6 , wherein
the charger is a charging roller.

Assignees

• Kyocera Document Solutions Inc

Inventors

• Maruo Keiji
• Shimizu Tomofumi
• Azuma Jun

Classifications

• G03G5/0668

  containing only one methine or polymethine group · CPC title

• G03G5/0696

  Phthalocyanines · CPC title

• G03G5/102

  consisting of or comprising metals · CPC title

• G03G5/056 Primary

  Polyesters · CPC title

• G03G5/0609

  containing oxygen · CPC title