Method for preparing salt-resistant and detergent-resistant alginate fiber

Patent metadata

Field	Value
Publication number	US-10190237-B2
Application number	US-201615566918-A
Country	US
Kind code	B2
Filing date	Apr 15, 2016
Priority date	Apr 16, 2015
Publication date	Jan 29, 2019
Grant date	Jan 29, 2019

Abstract

A method for preparing a salt-resistant and detergent-resistant alginate fiber by contacting and infiltrating a finished alginate fiber with a borate-containing adjuvant solution and using selected proper raw materials in selected proportions and reaction conditions. The preparation method solves the problem that the alginate fiber and a fabric made therefrom are neither salt-resistant nor detergent-resistant. The borate-modified alginate fiber and a fabric made therefrom have excellent salt resistances, and can be washed with an alkaline detergent. The swelling degree of the alginate fiber modified by the adjuvant solution can be reduced to 39.8% after the fiber is immersed in a normal saline at 30° C. for 72 h and can be reduced to 55.3% after the fiber is immersed in a standard detergent for 24 h, while the fiber maintains its original morphology without any obvious dissolution phenomenon, and the self flame-resisting performance of the alginate fiber is also maintained.

First claim

The invention claimed is:

1. A method for preparing a salt-resistant and detergent-resistant alginate fiber, wherein the fiber is obtained by contacting and infiltrating an alginate fiber with an adjuvant solution for 1-300 minutes, washing after the infiltration is completed, and then drying; the adjuvant solution is prepared by dissolving a combination of one or more of boric acid, borate, tetraborate, pentaborate, metaborate or perborate in water; the mass fraction of the adjuvant in the adjuvant solution is 0.1-8%, the alginate fiber is contacted with and infiltrated in the adjuvant solution at a temperature of 10-70° C. for a time period of 1-300 minutes, and the pH value of the adjuvant solution is 8-11; and the mass ratio of the alginate fiber to the adjuvant is 3-100:1.

2. The method for preparing a salt-resistant and detergent-resistant alginate fiber of claim 1 , wherein the adjuvant solution comprises one or more of boric acid, borate, tetraborate, pentaborate or metaborate; the mass fraction of the adjuvant in the adjuvant solution is 0.3-6%, the alginate fiber is contacted with and infiltrated in the adjuvant solution at a temperature of 40-70° C.; and the mass ratio of the alginate fiber to the adjuvant is 3-50:1.

3. The method for preparing a salt-resistant and detergent-resistant alginate fiber of claim 2 , wherein the adjuvant solution comprises one or more of potassium tetraborate, sodium metaborate, boric acid or pentaborate; the mass fraction of the adjuvant in the adjuvant solution is 0.3-4%; the alginate fiber is contacted with and infiltrated in the adjuvant solution at a temperature of 50-55° C.; and the mass ratio of the alginate fiber to the adjuvant is 20-50:1.

4. The method for preparing a salt-resistant and detergent-resistant alginate fiber of claim 1 , wherein the alginate fiber is a finished alginate fiber, or a semi-finished alginate fiber after the fiber is removed from a coagulating bath and before the fiber is coated by a glazing agent, or a fabric containing the alginate fiber, wherein the alginate fiber is a calcium alginate fiber, a zinc alginate fiber, a lead alginate fiber, a copper alginate fiber or an aluminum alginate fiber.

5. The method for preparing a salt-resistant and detergent-resistant alginate fiber of claim 1 , wherein the pH value of the adjuvant solution is adjusted by using sodium hydroxide, potassium hydroxide, ammonium hydroxide, sodium carbonate, potassium carbonate, sodium bicarbonate or potassium bicarbonate as a conditioning agent.

Assignees

• Univ Qingdao

Inventors

• Xia Yanzhi
• Tian Xing
• Cheng Fangfang
• Wang Bingbing
• Quan Fengyu
• Ji Quan

Classifications

• D01F9/04 Primary

  of alginates · CPC title

• D06M11/82 Primary

  with boron oxides; with boric, meta- or perboric acids or their salts, e.g. with borax · CPC title

• D06M2101/04

  Vegetal fibres · CPC title

• C08B37/0084

  Guluromannuronans, e.g. alginic acid, i.e. D-mannuronic acid and D-guluronic acid units linked with alternating alpha- and beta-1,4-glycosidic bonds; Derivatives thereof, e.g. alginates · CPC title