Stabilized blends containing friction modifiers

Patent metadata

Field	Value
Publication number	US-10190071-B2
Application number	US-201514886206-A
Country	US
Kind code	B2
Filing date	Oct 19, 2015
Priority date	Nov 30, 2009
Publication date	Jan 29, 2019
Grant date	Jan 29, 2019

Abstract

The present invention relates to functional fluid compositions containing friction modifiers, and specifically stable compositions containing friction modifiers with limited solubility in and/or limited compatibility with the functional fluids with which they are used. In particular the present invention deals with functional fluids used in internal combustion engines, such as engine oils, and friction modifiers derived from hydroxy-carboxylic acids, where the friction modifier is present in the functional fluid composition at levels that would otherwise cause the composition to be unstable and/or hazy.

First claim

We claim:

1. A composition comprising:
(a) a medium comprising a solvent, a functional fluid, an additive concentrate or combinations thereof; and
(b) a friction modifier component comprising a condensation product of tartaric and/or citric acid and a linear or branched fatty alcohol of 10 to 18 carbon atoms wherein said condensation product is not fully soluble in the medium; and
(c) a stabilizing component comprising a dispersant that is soluble in (a) and that interacts with (b) such that the solubility of (b) in (a) is improved, wherein said stabilizing component is present at about 4% to about 8% by weight of said composition;
wherein component (b) is present in component (a) in the form of dispersed particles wherein no more than 10 percent by weight of the particles have a diameter of more than 0.5 microns;
wherein component (b) is present in the overall composition at a level of 2 to 4 percent by weight;
wherein component (c), the stabilizing component, comprises: (i) a nitrogen-containing dispersant comprising a reaction product of a hydrocarbyl-substituted succinic acylating agent and a polyamine; (ii) a borated nitrogen-containing dispersant comprising a reaction product of a hydrocarbyl-substituted succinic acylating agent and a polyamine which is borated; (iii) an alkyl imidazoline derived from a polyalkylene amine and a fatty mono-carboxylic acid; or combinations thereof;
wherein a N:CO ratio of (i) or (ii) ranges from greater than 1.3:1 to about 2:1; and
wherein a TBN, as defined by ASTM D4739, of (iii) is greater than 9.

2. The composition of claim 1 wherein component (c), the stabilizing component, comprises a compound represented by the formula:

or salted versions thereof wherein: X 1 is O or NR 5 where R 1 and R 5 can optionally link to form a ring; R 3 is H or a hydrocarbyl and R 4 is H, a hydrocarbyl group, or —CH 2 C(O)—X 2 where X 2 is —OH or the N atom in the formula above such that the —CH 2 C(O)— group forms a ring; and wherein each R 1 and R 2 are independently H, a hydrocarbyl group or —(CH 2 CH 2 NH) n —R 1 .

3. The composition of claim 1 wherein component (c), the stabilizing component, comprises a compound represented by one or more of the following formulas:

wherein each R 6 is independently a hydrocarbyl group; each X 3 is independently a nitrogen containing group derived from a polyethylene polyamine.

4. The composition of claim 1 wherein the turbidity of the overall composition is improved, as defined by a lower JTU and/or NTU value compared to the same composition that does not contain (c), the stabilizing component.

5. The composition of claim 1 wherein the nitrogen containing dispersant of the stabilizing agent has at least one of the following properties:
(i) the dispersant includes at least one hydrocarbyl group containing 10 to 500 carbon atoms;
(ii) the dispersant has a TBN, as defined by ASTM D4739, of at least 10; and
(iii) the dispersant contains at least 0.1% weight boron.

6. The composition of claim 1 , wherein the linear or branched fatty alcohol comprises 2-ethylhexanol, isotridecyl alcohol, or mixtures thereof.

7. A process of preparing a clear and stable composition comprising:
(a) a medium comprising a solvent, a functional fluid, an additive concentrate, or combinations thereof; and
(b) of a friction modifier component comprising a condensation product of tartaric and/or citric acid and a linear or branched fatty alcohol of 10 to 18 carbon atoms wherein said condensation product is not fully soluble in the medium; and
(c) a stabilizing component comprising a dispersant that is soluble in (a) and that interacts with (b) such that the solubility of (b) in (a) is improved, wherein said stabilizing component is present at about 4% to about 8% by weight of said composition;
said method comprising the steps of:
I. adding components (b) and (c) to component (a) wherein component (b) is present in the overall composition at 2 to 4 percent by weight;
II. mixing the components so that component (b) are present in component (a) in the form of dispersed particles wherein no more than 10 percent by weight of the particles have a diameter of more than 0.5 microns;
wherein component (c), the stabilizing component, comprises: (i) a nitrogen-containing dispersant comprising a reaction product of a hydrocarbyl-substituted succinic acylating agent and a polyamine; (ii) a borated nitrogen-containing dispersant comprising a reaction product of a hydrocarbyl-substituted succinic acylating agent and a polyamine which is borated; (iii) an alkyl imidazoline derived from a polyalkylene amine and a fatty mono-carboxylic acid; or combinations thereof;
wherein a N:CO ratio of (i) or (ii) ranges from greater than 1.3:1 to about 2:1; and
wherein a TBN, as defined by ASTM D4739, of (iii) is greater than 9.

8. The process of claim 7 wherein the clarity of the resulting mixture is improved, as defined by a lower JTU and/or NTU value compared to the same composition that does not contain (c), the stabilizing component.

9. The process of claim 7 , wherein the linear or branched fatty alcohol comprises 2-ethylhexanol, isotridecyl alcohol, or mixtures thereof.

10. The composition of claim 7 , wherein the linear or branched fatty alcohol has 11 to 14 carbon atoms.

11. The composition of claim 1 , wherein said composition comprises at least 3 wt % of said friction modifier.

12. The process of claim 7 , wherein the linear or branched fatty alcohol has 11 to 14 carbon atoms.

13. The process of claim 7 , wherein said composition comprises at least 3 wt % of said friction modifier.

14. The composition of claim 1 , wherein component (c), the stabilizing component, comprises an alkyl imidazoline derived from a polyalkylene amine and a fatty mono-carboxylic acid and has a TBN, as defined by ASTM D4739, of greater than 9.

15. The process of claim 7 , wherein component (c), the stabilizing component, comprises an alkyl imidazoline derived from a polyalkylene amine and a fatty mono-carboxylic acid and has a TBN, as defined by ASTM D4739, of greater than 9.

Assignees

• Lubrizol Corp

Inventors

• Delbridge Ewan E
• Mullay John J
• Burrington James D
• Sharpe Jonathan R
• Dunkerley John W

Classifications

• C10M2219/089

  Overbased salts · CPC title

• C10M2223/04

  Phosphate esters · CPC title

• C10M2223/045

  Metal containing thio derivatives · CPC title

• C10M2207/289

  containing free hydroxy groups · CPC title

• C10N2030/70

  Soluble oils · CPC title