Hydroprocessing catalyst composition containing an acetoacetic acid compound, a method of making such a catalyst, and a process of using such catalyst

Patent metadata

Field	Value
Publication number	US-10189015-B2
Application number	US-201514918613-A
Country	US
Kind code	B2
Filing date	Oct 21, 2015
Priority date	Oct 22, 2014
Publication date	Jan 29, 2019
Grant date	Jan 29, 2019

Abstract

A composition that comprises a support material having incorporated therein a metal component and impregnated with an additive compound that is an acetoacetic acid compound. The composition includes the support material that is impregnated with the additive compound and is useful in the hydroprocessing of hydrocarbon feedstocks, especially in the denitrogenation and desulfurization of distillate feedstocks to make ultra low sulfur diesel.

First claim

That which is claimed is:

1. A catalyst composition comprising: a calcined shaped support material that is impregnated by a single impregnation step with a cobalt or nickel component, a molybdenum component, and a phosphorous component and dried without calcination and incorporated with an acetoacetic acid compound additive, wherein the catalyst composition is non-sulfurized.

2. A catalyst composition as recited in claim 1 , wherein said catalyst composition further comprises a material absence of a hydrocarbon oil.

3. A catalyst composition as recited in claim 1 , wherein said molybdenum component is present in said catalyst composition in an amount in the range of from 5 wt. % to 50 wt. % and said cobalt or nickel component is present in said catalyst composition in an amount in the range of from 0.5 wt. % to 20 wt. %.

4. A catalyst composition as recited in claim 1 , wherein said acetoacetic acid compound additive is selected from the group of compounds having the following molecular structural formula: R1-O—CO—CR3R4-CO—R2
Wherein: R1=either hydrogen or a C1 to C4 alkyl group;
R2=a C1 to C4 alkyl group;
R3=either hydrogen or a C1 to C4 alkyl group;
R4=either hydrogen or a C1 to C4 alkyl group.

5. A catalyst composition as recited in claim 4 , wherein said acetoacetic acid compound additive is selected from the group consisting of acetoacetic acid, ethyl acetoacetic acid, methyl acetoacetic acid, and ethyl 2-methyl acetoacetic acid.

6. A process for hydrotreating a hydrocarbon feedstock, wherein said process comprises: contacting under suitable hydrotreating process conditions said hydrocarbon feedstock with the catalyst composition recited in claim 1 ; and yielding a treated product.

7. A method of making a composition, wherein said method comprises:
providing a calcined shaped particle comprising an inorganic oxide material;
impregnating by a single impregnation step said calcined shaped particle with a metal-containing aqueous solution, comprising a molybdenum metal component, a cobalt or nickel component, and a phosphorous component to incorporate into said calcined shaped particle cobalt or nickel in an amount in the range of from 0.5 wt. % to 20 wt. % and molybdenum in an amount in the range of from 5 wt. % to 50 wt. %, based on a dry support and the metal component as the element, regardless of its actual form, to provide a metal-incorporated support material;
drying said metal-impregnated support material under a drying temperature that is less than a calcination temperature not exceeding 400° C. to provide a dried metal-impregnated support material;
incorporating an acetoacetic acid compound additive into said metal-incorporated support material to thereby provide an additive-impregnated composition; and
wherein the additive-impregnated composition is non-sulfurized.

8. A method as recited in claim 7 , further comprising: contacting said additive-impregnated composition under suitable hydrogen treatment conditions with hydrogen to thereby provide a hydrogen-treated composition.

9. A method as recited in claim 8 , wherein prior to said incorporating of said acetoacetic acid compound additive into said metal-incorporated support material, said metal-incorporated support material is dried so as to contain a volatiles content in the range of from 3 to 20 wt. % LOI.

10. A composition made by the method of claim 7 .

Assignees

• Shell Oil Co

Inventors

• Gabrielov Alexei Grigorievich

Classifications

• B01J27/19 Primary

  Molybdenum · CPC title

• B01J27/14

  Phosphorus; Compounds thereof · CPC title

• B01J37/02

  Impregnation, coating or precipitation ({B01J37/0009 and B01J37/0018 take precedence } ; protection by coating B01J33/00) · CPC title

• B01J31/34

  of chromium, molybdenum or tungsten · CPC title

• B01J23/28

  Molybdenum · CPC title