Method for producing porous cellulose beads and adsorbent employing same

Patent metadata

Field	Value
Publication number	US-10189007-B2
Application number	US-201415029551-A
Country	US
Kind code	B2
Filing date	Oct 14, 2014
Priority date	Oct 15, 2013
Publication date	Jan 29, 2019
Grant date	Jan 29, 2019

Abstract

The objective of the present invention is to provide a method for easily and efficiently producing cellulose beads which have pore shape suitable for an adsorbent and of which adsorption performance is excellent without using highly toxic and highly corrosive auxiliary raw material and without industrially disadvantageous cumbersome step. The method for producing porous cellulose beads according to the present invention is characterized in comprising (a) the step of preparing a fine cellulose dispersion by mixing a low temperature alkaline aqueous solution and cellulose, (b) the step of preparing a mixed liquid by adding a crosslinking agent to the fine cellulose dispersion, (c) the step of preparing an emulsion by dispersing the mixed liquid in a dispersion medium, (d) the step of contacting the emulsion with a coagulating solvent.

First claim

The invention claimed is:

1. A method for producing porous cellulose beads, the method comprising:
mixing an alkaline aqueous solution having a temperature of not less than −20° C. and not more than 20° C. and cellulose to obtain a cellulose dispersion;
adding a crosslinking agent to the cellulose dispersion to obtain a mixed liquid;
dispersing the mixed liquid in a dispersion medium to obtain an emulsion; and
contacting the emulsion with a coagulating solvent.

2. The method according to claim 1 , wherein, in the mixing, the temperature of the alkaline aqueous solution is not less than 0° C. and not more than 20° C.

3. The method according to claim 1 , wherein the crosslinking agent is an epoxy group-containing compound.

4. The method according to claim 3 , wherein the epoxy group-containing compound is a glycidyl ether compound.

5. The method according to claim 1 , wherein the crosslinking agent has a solubility in water of not less than 50%.

6. The method according to claim 1 , wherein a viscosity of the crosslinking agent is not less than 100 mPa·s and not more than 50,000 mPa·s.

7. The method according to claim 1 , wherein, in the mixing, the temperature of the alkaline aqueous solution is not less than −20° C. and not more than 15° C.

8. The method according to claim 1 , wherein a concentration of the crosslinking agent in the mixed liquid is from 1 wt % to 20 wt %.

9. The method according to claim 1 , wherein an alkali concentration of the alkaline aqueous solution is from 3 wt % to 20 wt %.

10. The method according to claim 1 , wherein the cellulose has a polymerization degree of not more than 1,000.

11. The method according to claim 1 , wherein a concentration of the cellulose in the cellulose dispersion is from 1 wt % to 20 wt %.

Assignees

• Kaneka Corp

Inventors

• Hayashi Asuka
• Kawai Yoshikazu
• Morio Ken-Ichiro

Classifications

• B01J20/3293

  Coatings on a core, the core being particle or fiber shaped, e.g. encapsulated particles, coated fibers · CPC title

• B01J20/3274

  Proteins, nucleic acids, polysaccharides, antibodies or antigens · CPC title

• B01J20/3085

  Chemical treatments not covered by groups B01J20/3007 - B01J20/3078 · CPC title

• B01J20/3212

  consisting of a polymer obtained by reactions otherwise than involving only carbon to carbon unsaturated bonds · CPC title

• B01J20/3217

  Resulting in a chemical bond between the coating or impregnating layer and the carrier, support or substrate, e.g. a covalent bond · CPC title