Composition for forming electrode of solar cell and electrode formed thereof

Patent metadata

Field	Value
Publication number	US-10186622-B2
Application number	US-201715492539-A
Country	US
Kind code	B2
Filing date	Apr 20, 2017
Priority date	Feb 15, 2013
Publication date	Jan 22, 2019
Grant date	Jan 22, 2019

Abstract

Disclosed herein is a composition for solar cell electrodes. The composition includes a conductive powder, a glass frit, and an organic vehicle, wherein the glass frit is a bismuth oxide-tellurium oxide-zinc oxide-lithium oxide-based glass frit comprising: 5 wt % to 20 wt % of bismuth oxide; 55 wt % to 80 wt % of tellurium oxide; 0.1 wt % to 15 wt % of zinc oxide; and 0.1 wt % to 10 wt % of lithium oxide. Solar cell electrodes formed of the composition have low serial resistance (Rs) and high open voltage (Voc), thus providing high conversion efficiency and good adhesive strength with respect to a ribbon.

First claim

The invention claimed is:

1. A composition for solar cell electrodes, the composition comprising:
60 wt % to 95 wt % of silver powder,
0.5 wt % to 20 wt % of a glass frit, and
1 wt % to 30 wt % of an organic vehicle,
the glass frit consisting essentially of:
5 wt % to 20 wt % of bismuth oxide;
55 wt % to 80 wt % of tellurium oxide;
0.1 wt % to 15 wt % of zinc oxide;
0.1 wt % to 10 wt % of lithium oxide; and
0 wt % to 10 wt % of tungsten oxide.

2. The composition according to claim 1 , wherein the glass frit includes 60 wt % to 80 wt % of tellurium oxide.

3. The composition according to claim 1 , wherein the glass frit has an average particle diameter (D50) of 0.1 μm to 10 μm.

4. The composition according to claim 1 , wherein the silver powder has an average particle diameter (D50) of 0.1 μm to 10 μm.

5. The composition according to claim 1 , further comprising: at least one additive selected from the group consisting of dispersants, thixotropic agents, plasticizers, viscosity stabilizers, anti-foaming agents, pigments, UV stabilizers, antioxidants, and coupling agents.

6. A solar cell electrode prepared from the composition for solar cell electrodes according claim 1 .

7. A composition for solar cell electrodes, the composition comprising:
60 wt % to 95 wt % of silver powder,
0.5 wt % to 20 wt % of a glass fit, and
1 wt % to 30 wt % of an organic vehicle,
the glass frit consisting of:
5 wt % to 20 wt % of bismuth oxide;
55 wt % to 80 wt % of tellurium oxide;
0.1 wt % to 15 wt % of zinc oxide;
0.1 wt % to 10 wt % of lithium oxide.

Assignees

• Cheil Ind Inc

Inventors

• Park Young Ki
• Kim Dong Suk
• Park Min Su
• Jung Seok Hyun
• Kim Min Jae

Classifications

• C03C8/18

  containing free metals · CPC title

• C09D5/24

  Electrically-conducting paints {(conductive materials H01B1/00)} · CPC title

• H01B1/22 Primary

  the conductive material comprising metals or alloys · CPC title

• C03C4/14

  for electro-conductive glass · CPC title

• Y02E10/50

  Photovoltaic [PV] energy · CPC title