Internal olefin sulfonate composition

Patent metadata

Field	Value
Publication number	US-10184076-B2
Application number	US-201414772795-A
Country	US
Kind code	B2
Filing date	Mar 4, 2014
Priority date	Mar 6, 2013
Publication date	Jan 22, 2019
Grant date	Jan 22, 2019

Abstract

The present invention provides an internal olefin sulfonate composition, comprising water and an internal olefin sulfonate mixture having an average carbon number of at least 20, wherein the internal olefin sulfonate mixture comprises hydroxy sulfonates and alkene sulfonates in a weight ratio of hydroxy sulfonates to alkene sulfonates of at least 3.25. The invention further provides a method of treating a crude oil containing formation.

First claim

That which is claimed is:

1. An internal olefin sulfonate composition, comprising water and an internal olefin sulfonate mixture having an average carbon number of at least 20, wherein the internal olefin sulfonate mixture comprises hydroxy sulfonates and alkene sulfonates in a weight ratio of hydroxy sulfonates to alkene sulfonates of at least 3.25 and the internal olefin sulfonate mixture further comprises disulfonate compounds in an amount equal to or less than 1.4 wt % on an active matter basis and wherein the lower limit for disulfonates in the internal olefin sulfonate mixture is no less than 0.0005 wt %, based on the weight of the active matter wherein active matter is defined as the total of mono sulfonates, disulfonates and higher sulfonates in the internal olefin sulfonate composition.

2. The internal olefin sulfonate composition according to claim 1 , wherein the internal olefin sulfonate mixture comprises hydroxy sulfonates and alkene sulfonates in a weight ratio of hydroxy sulfonates to alkene sulfonates of at least 3.50.

3. The internal olefin sulfonate composition according to claim 1 , wherein the internal olefin sulfonate composition further comprises inorganic sulfide compounds in an amount equal to or less than 5 wt % on an active matter basis.

4. The internal olefin sulfonate composition according to claim 1 , wherein the internal olefin sulfonate mixture further comprises diolefin sulfonate compounds in an amount equal to or less than 1.1 wt % on an active matter basis.

5. The internal olefin sulfonate composition according to claim 1 , comprising a C20-24 internal olefin sulfonate.

6. The internal olefin sulfonate composition according to claim 1 , comprising a C24-28 internal olefin sulfonate.

7. The internal olefin sulfonate composition according to claim 1 , comprising a C19-23 internal olefin sulfonate.

8. The internal olefin sulfonate composition according to claim 7 , having a concentration of active matter of from 30% to 35%.

9. The internal olefin sulfonate composition according to claim 1 , having a concentration of active matter of from 30% to 95%.

10. The internal olefin sulfonate composition according to claim 1 , having a kinematic viscosity of no more than 1000 mm 2 /s, as measured with ASTM D445 at 26.7° C. and 20 wt % active matter, based on the internal olefin sulfonate composition.

11. The internal olefin sulfonate composition according to claim 1 , further comprising a viscosity reducing compound.

12. A method of treating a crude oil containing formation comprising admixing at least the internal olefin sulfonate composition according to claim 1 with water and/or brine to form an injectable fluid, wherein the active matter comprises in the range of from 0.05 to 1.0 wt % of the injectable fluid and then injecting the injectable fluid into the formation.

13. The method of treating a crude oil containing formation according to claim 12 wherein the active matter comprises in the range of from 0.1 to 0.8 wt % of the injectable fluid.

14. The method of claim 12 wherein the water and/or brine is from the formation from which the crude oil is to be extracted.

Assignees

• Shell Oil Co

Inventors

• Barnes Julian Richard
• Buechele James Laurel
• Dirkzwager Hendrik
• Genuit Willem Johan Louis
• Purcell Jeremiah Michael
• Semien Catherine
• Reznik Carmen Geraldine

Classifications

• C08F220/387

  and containing nitrogen and oxygen · CPC title

• C09K8/882

  obtained by reactions only involving carbon-to-carbon unsaturated bonds · CPC title

• E21B43/16

  Enhanced recovery methods for obtaining hydrocarbons · CPC title

• C08F220/56

  Acrylamide; Methacrylamide · CPC title

• C09K8/24

  Polymers · CPC title