Process for producing a Ziegler Natta procatalyst for ethylene polymerisation

Patent metadata

Field	Value
Publication number	US-10184016-B2
Application number	US-201314649472-A
Country	US
Kind code	B2
Filing date	Dec 20, 2013
Priority date	Dec 21, 2012
Publication date	Jan 22, 2019
Grant date	Jan 22, 2019

Abstract

Process for the preparation of a particulate Group 2 metal/transition metal polymerization catalyst component for ethylene polymerization comprising a special bi-(oxygen containing ring) compound as internal donor, and to the use of such a catalyst component for preparing a catalyst used in the polymerization of ethylene.

First claim

The invention claimed is:

1. A process for producing an ethylene homo- or copolymer by polymerizing ethylene and optionally a C 3 -C 20 alpha-olefin comonomer in the presence of a Ziegler-Natta (ZN) type ethylene polymerization catalyst component in the form of solid particles and a co-catalyst, said catalyst component obtained by the steps of:
a) a 1 ) providing a solution of an alkoxy compound (Ax) that is the reaction product of a Group 2 metal compound and an alcohol mixture of a monohydric alcohol (A) and an alcohol (B) comprising in addition to the hydroxyl moiety at least one further oxygen bearing group that is different from a hydroxyl moiety, optionally in an organic liquid reaction medium; or
a 2 ) providing a solution of an alkoxy compound mixture of at least a first alkoxy compound (Ax) that is the reaction product of a Group 2 metal compound and a monohydric alcohol (A), optionally in an organic liquid reaction medium, and at least a second alkoxy compound (Bx) that is the reaction product of a Group 2 metal compound and an alcohol (B) comprising in addition to the hydroxyl moiety at least one further oxygen bearing group that is different from a hydroxyl moiety, optionally in an organic liquid reaction medium; and
b) adding said solution to at least one compound of a transition metal (CT),
c) preparing the catalyst component in the form of solid particles,
d) optionally performing one or more washing steps and
e) recovering the catalyst component in the form of solid particles,
wherein a compound of the formula (I) or an isomer mixture therefrom is added as internal donor at any step prior to step e)

wherein in the formula (I)
X is C or Si,
R 1 can be the same or different and can be hydrogen, a linear or branched C 1 to C 8 -alkyl group, or a C 3 -C 8 -alkylene group,
and R 2 to R 5 are the same or different and can be hydrogen, a linear or branched C 1 to C 8 -alkyl group, or a C 3 -C 8 -alkylene group,
whereby two or more of R 1 to R 5 can form a ring,
n is the same for both oxygen-containing rings and can be 0, 1 or 2,
whereby the two oxygen-containing rings can be individually saturated or unsaturated;
wherein no external carrier material is used to form the catalyst component into solid particles; and
wherein the solid particles of the catalyst component have an average particle size range of 5 to 200 μm.

2. The process according to claim 1 , wherein in formula (I) X is C, both R 1 's are the same and are a linear C 1 to C 4 alkyls, R 2 to R 5 are the same or different and can be H or a C 1 to C 2 alkyl, n for both oxygen-containing rings is 1, and both oxygen-containing rings are saturated.

3. The process according to claim 1 , wherein in formula (I) X is C, both R 1 are the same and are methyl, up to four of the residues R 2 and R 5 are methyl and the remaining residues are H, n for both oxygen-containing rings is 1, and both oxygen-containing rings are saturated.

4. The process according to claim 1 , wherein the monohydric alcohol (A) is of formula ROH in which R is a linear or branched C 1 -C 20 alkyl.

5. The process according to claim 1 , wherein the alcohol (B) is a C 2 to C 4 -glycol monoether, wherein the ether moiety comprises from 2 to 18 carbon atoms.

6. The process according to claim 1 , wherein said Group 2 metal is magnesium.

7. The process according to claim 1 , wherein said at least one compound of a transition metal is selected from Group 4 and/or Group 5 metal compounds.

8. The process according to claim 1 , wherein the internal donor of formula (I) or an isomer mixture thereof is added to solution a 1 ) or a 2 ) prepared in step a).

9. The process according to claim 1 , wherein preparation of the catalyst component in the form of solid particles comprises the steps of:
(1) providing a solution (S1) of
(1-1) an alkoxy compound (Ax) that is the reaction product of a Group 2 metal compound and an alcohol mixture of a monohydric alcohol (A) and an alcohol (B) comprising in addition to the hydroxyl moiety at least one further oxygen bearing group that is different from a hydroxyl moiety, or
(1-3) an alkoxy compound mixture of at least a first alkoxy compound (Ax) that is the reaction product of a Group 2 metal compound and a monohydric alcohol (A) and at least a second alkoxy compound (Bx) that is the reaction product of a Group 2 metal compound and an alcohol (B) comprising in addition to the hydroxyl moiety at least one further oxygen bearing group that is different from a hydroxyl moiety, optionally in an organic liquid reaction medium,
(2) combining said solution (S1) with at least one transition metal compound (CT),
(3) precipitating said catalyst component in the form of a solid particle,
(4) optionally performing one or more washing steps, and
(5) recovering the solidified particles of the catalyst component, wherein an electron donor of formula (I) or an isomer mixture thereof is added at any step prior to step (5).

10. The process according to claim 9 , wherein the internal donor of formula (I) or an isomer mixture thereof is added to solution (1-1) or (1-2) prepared in step (1).

11. The process according to claim 9 , wherein the addition of solution (S1) to the at least one transition metal compound (CT) in step (2) is done at a temperature range of 50 to 110° C., at which temperature the at least one transition metal compound (CT) is in a liquid form, resulting in the precipitation of said solid catalyst components, whereby a surfactant can be added in step (1) to solutions (1, 1) or (1-2) in step (2).

12. The process according to claim 9 , wherein the solution (S1) is mixed with at least one transition metal compound (CT) in liquid form at a temperature of about −20° C. to about 30° C. and precipitating the solid catalyst components by subsequently slowly raising the temperature to a temperature range of 50 to 110 ° C., whereby the rate of temperature increase is in the range from 0.1° C. to 30° C. per minute and whereby a surfactant is added to the solution (S1) before step (2).

13. The process according to claim 1 , wherein the preparation of the catalyst component in form of solid particles comprises the steps of:
(1) providing a solution (S1) of
(1-1) an alkoxy compound (Ax) that is the reaction product of a Group 2 metal compound and an alcohol mixture of a monohydric alcohol (A) and an alcohol (B) comprising in addition to the hydroxyl moiety at least one further oxygen bearing group being different from a hydroxyl moiety, or
(1-2) an alkoxy compound mixture of at least a first alkoxy compound (Ax) that is the reaction product of a Group 2 metal compound and a monohydric alcohol (A), and at least a second alkoxy compound (Bx) that is the reaction product of a Group 2 metal compound and an alcohol (B) comprising in addition to the hydroxyl moiety at least one further oxygen bearing group being different from a hydroxyl moiety,
(2) adding said solution (S1) to at least one compound of a transition metal (CT) to produce an emulsion, wherein the dispersed phase of the emulsion is in the form of droplets and contains more than 50 mol% of the Group 2 metal in said alkoxy compound(s),
(3) agitating the emulsion in order to maintain the droplets of said dispersed phase within a predetermined average size range of 5 to 200 μm,
(4) solidifying said droplets of the dispersed phase,
(5) optionally performing one or more washing steps, and
(6) recovering the solidified particles of the catalyst

Assignees

• Borealis Ag

Inventors

• Jayaratne Kumudini
• Leinonen Timo
• Denifl Peter

Classifications

• C08F10/02 Primary

  Ethene · CPC title

• C08F4/651

  Pretreating with non-metals or metal-free compounds · CPC title

• C08F4/6565

  and magnesium or compounds thereof · CPC title