Use of a water-soluble unit dose article to improve the user dosing experience

Patent metadata

Field	Value
Publication number	US-10183794-B2
Application number	US-201715620384-A
Country	US
Kind code	B2
Filing date	Jun 12, 2017
Priority date	Jun 13, 2016
Publication date	Jan 22, 2019
Grant date	Jan 22, 2019

Abstract

The present invention relates to the use of water-soluble unit dose article to improve the user dosing experience.

First claim

What is claimed is:

1. A unit dose article comprising at least a first water-soluble film, a second water-soluble film and optionally a composition contained within the unit dose article, wherein the first water-soluble film and the second water-soluble film are chemically different to one another;
wherein the first water soluble film has a first elongation modulus, the second water soluble film has a second elongation modulus, the first elongation modulus is greater than the second elongation modulus, and the difference between the first elongation modulus and the second elongation modulus is from 0.5 MPa to 10 MPa;
provided that when the composition is a fabric care or household care composition and at least one of the first water-soluble film and the second water-soluble film comprises a blend of a polyvinyl alcohol homopolymer resin and an anionic polyvinyl alcohol copolymer resin, then both the first water soluble film and the second water soluble film comprise blends that include 65 wt. % or greater of an anionic polyvinyl alcohol copolymer resin; and
provided that when the composition is a fabric care or household care composition and at least one of the first water-soluble film and the second water-soluble film comprises a blend of at least two anionic polyvinyl alcohol copolymer resins, then both the first water soluble film and the second water soluble film comprise blends of at least two anionic polyvinyl alcohol copolymer resins.

2. The unit dose article according to claim 1 , wherein the difference between the first elongation modulus and the second elongation modulus is from 1 MPa to 8 MPa.

3. The unit dose article according to claim 1 , wherein the first elongation modulus is from 1 MPa to 20 MPa.

4. The unit dose article according to claim 3 , wherein the second elongation modulus is from 1 MPa to 15 MPa.

5. The unit dose article according to claim 1 , wherein the first water-soluble film has a first tensile strain at break, the second water-soluble film has a second tensile strain at break, wherein the first tensile strain at break is greater than the second tensile strain at break and the difference between the first tensile strain at break and the second tensile strain at break is from 10% to 1000%; and
wherein the first tensile strain at break is from 300% to 1600%; and
wherein the second tensile strain at break is from 300% to 1200%.

6. The unit dose article according to claim 1 wherein the first water soluble film comprises a first water soluble resin and the second water soluble film comprises a second water soluble resin.

7. The unit dose article according to claim 6 , wherein the first water soluble resin comprises a blend of a polyvinyl alcohol homopolymer and a polyvinyl alcohol copolymer comprising an anionic monomer unit, optionally wherein the blend comprises from 0% to 70% of the polyvinyl alcohol copolymer comprising an anionic monomer unit and from 30% to about 100% of the polyvinyl alcohol homopolymer, based on the total weight of the first water soluble resin in the first film, or wherein the blend comprises from 10% to 70% of the polyvinyl alcohol copolymer comprising an anionic monomer unit, based on the total weight of the first water soluble resin in the first film.

8. The unit dose article according to claim 6 , wherein the second water soluble resin comprises a blend of a polyvinyl alcohol homopolymer and a polyvinyl alcohol copolymer comprising an anionic monomer unit, optionally wherein the blend comprises from 0% to 70% of the polyvinyl alcohol copolymer comprising an anionic monomer unit and from 30% to 100% of the polyvinyl alcohol homopolymer, based on the total weight of the second water soluble resin in the second film, or wherein the blend comprises from 10% to 70%of the polyvinyl alcohol copolymer comprising an anionic monomer unit, based on the total weight of the second water soluble resin in the second film.

9. The unit dose article of claim 7 , wherein the first water soluble resin comprises from 65% by weight or greater of the first water soluble resin of the polyvinyl alcohol copolymer comprising an anionic monomer unit and the second water soluble resin comprises from 65% by weight or greater of the second water soluble resin of the polyvinyl alcohol copolymer comprising an anionic monomer unit.

10. The unit dose article according to claim 1 , wherein at least one of the first water-soluble film and the second water-soluble film comprises a polyvinyl alcohol copolymer comprising an anionic monomer unit, the anionic monomer unit selected from the group consisting of anionic monomers derived from vinyl acetic acid, alkyl acrylates, maleic acid, monoalkyl maleate, dialkyl maleate, monomethyl maleate, dimethyl maleate, maleic anhydride, fumaric acid, monoalkyl fumarate, dialkyl fumarate, monomethyl fumarate, dimethyl fumarate, fumaric anhydride, itaconic acid, monomethyl itaconate, dimethyl itaconate, itaconic anhydride, citraconic acid, monoalkyl citraconate, dialkyl citraconate, citraconic anhydride, mesaconic acid, monoalkyl mesaconate, dialkyl mesaconate, mesaconic anhydride, glutaconic acid, monoalkyl glutaconate, dialkyl glutaconate, glutaconic anhydride, vinyl sulfonic acid, alkyl sulfonic acid, ethylene sulfonic acid, 2-acrylamido-1-methyl propane sulfonic acid, 2-acrylamide-2-methylpropanesulfonic acid, 2-methylacrylamido-2-methylpropanesulfonic acid, 2-sulfoethyl acrylate, alkali metal salts thereof, esters thereof, and combinations thereof.

11. The unit dose article according to claim 1 wherein the first water-soluble film, and the second water-soluble film independently have a thickness of between 40 microns and 100 microns.

12. The unit dose article according to claim 1 wherein the first water-soluble film has a first water capacity and the second water-soluble film has a second water capacity wherein the first water capacity is less than the second water capacity and wherein the difference between the water capacity of the first water soluble film and the second water-soluble film is between 0.01% and 1%.

13. The unit dose article according to claim 12 , wherein the first water-soluble film has a water capacity from 1% to 10% and the second water-soluble film has a water capacity from 1.5% to 12%.

14. A method of using the unit dose article according to claim 1 comprising transferring at least one water-soluble unit dose article from a storage receptacle.

15. The method of using a unit dose article according to claim 14 , wherein the transferring is by hand.

16. The method of using the unit dose article according to claim 14 comprising transferring at least one water-soluble unit dose article from a storage receptacle to an automatic washing machine.

17. The method of using a unit dose article according to claim 16 wherein the storage receptacle is a flexible bag, a rigid tub or a mixture thereof.

18. The unit dose article according to claim 1 , wherein the unit dose article contains a non-household care composition.

19. The unit dose article according to claim 18 , wherein the non-household care composition is selected from agricultural compositions, aviation compositions, food and nutritive compositions, industrial compositions, livestock compositions, marine compositions, medical compositions, mercantile compositions, military and quasi-military compositions, office compositions, and recreational and park compositions, pet compositions, water-treatment compositions.

20. The unit dose article according to claim 19 , wherein the non-household care compositio

Assignees

• Monosol Llc

Inventors

• Souter Philip Frank
• Keuleers Robby Renilde Francois
• Labeque Regine
• Courchay Florence Catherine
• Renmans Marc Rene Bert

Classifications

• B65D65/46 Primary

  Applications of disintegrable, dissolvable or edible materials · CPC title

• C11D17/042 Primary

  Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions · CPC title

• B65D65/38

  Packaging materials of special type or form · CPC title

• Y10T428/1334

  Nonself-supporting tubular film or bag [e.g., pouch, envelope, packet, etc.] · CPC title

• C11D17/043

  Liquid or thixotropic (gel) compositions · CPC title