Microwave drying of lithium-ion battery materials

Patent metadata

Field	Value
Publication number	US-10181599-B2
Application number	US-201314385761-A
Country	US
Kind code	B2
Filing date	Mar 14, 2013
Priority date	Mar 16, 2012
Publication date	Jan 15, 2019
Grant date	Jan 15, 2019

Abstract

A method for making a lithium-ion cell includes depositing an electrode material as a coating on a substrate of the lithium-ion cell, irradiating the deposited electrode material with microwave radiation of varying frequency, wetting the irradiated electrode material with a non-aqueous electrolyte solution, and sealing the wetted electrode material in an air-tight enclosure.

First claim

The invention claimed is:

1. A method for making a lithium-ion cell, the method comprising:
depositing electrode materials including a positive electrode material and a negative electrode material as coatings on respective substrates of the lithium-ion cell, the substrates in the form of a continuous sheet;
passing the deposited electrode materials through a microwave radiation field of varying frequency while flowing a gas over the deposited electrode materials to heat the electrode materials before winding or folding the electrode materials with one or more separator layers, wherein the frequency increases linearly from an initial frequency to a final frequency, the increasing coincident with a time taken for a given portion of the electrode material to pass through the field of microwave radiation;
wetting the irradiated electrode materials with a non-aqueous electrolyte solution; and
sealing the wetted electrode materials in an air-tight enclosure.

2. The method of claim 1 wherein the electrode materials include one or more of lithium cobaltate, lithium manganate, lithium nickelate, and lithium nickel cobaltate.

3. The method of claim 1 wherein the electrode materials include lithium-intercalated carbon.

4. The method of claim 1 wherein the one or more separator layers are arranged between the positive and negative electrode materials.

5. The method of claim 1 wherein the electrode materials are applied from an aqueous slurry.

6. The method of claim 1 wherein depositing the electrode materials includes spray coating and/or transfer coating the electrode materials onto the respective substrates.

7. The method of claim 1 wherein one or more of the respective substrates includes a metal foil.

8. The method of claim 1 wherein the non-aqueous electrolyte solution includes one or more of ethylene carbonate, dimethylcarbonate, and diethylcarbonate.

9. The method of claim 1 wherein the non-aqueous electrolyte solution includes a dissolved hygroscopic solid.

10. An apparatus for making a lithium-ion cell, the apparatus comprising:
an electrode-material deposition stage configured to deposit an electrode material as a coating on a substrate of the lithium-ion cell;
a desiccation stage including a microwave emitter, a feed roller feeding the deposited electrode material as a continuous sheet to the desiccation stage, and a gas conduit with an inlet and an outlet, wherein the deposited electrode material is continuously irradiated with microwave radiation of an output power while ramping a frequency from a first frequency to a final frequency while passing through the gas conduit, wherein a gas is conducted through the gas conduit from the inlet to the outlet, and the feed roller is configured to maintain a suitable amount of tension in the sheet;
a wetting stage configured to wet the irradiated electrode material with a non-aqueous electrolyte solution; and
a sealing stage configured to seal the wetted electrode material in an air-tight enclosure.

11. The apparatus of claim 10 wherein the desiccation stage is configured to convey the electrode material and substrate as a continuous sheet.

12. The apparatus of claim 10 wherein the gas conduit includes a glass or ceramic window permeable to microwave radiation.

13. The apparatus of claim 10 wherein the ramped frequency of the microwave emitter is adjustable between 1 and 8 gigahertz.

14. The apparatus of claim 10 wherein a power of the microwave emitter is ten kilowatts per square meter or greater.

15. The apparatus of claim 14 wherein the ramped frequency of the microwave emitter is configured to ramp up or down as the electrode material is conveyed through the desiccation stage while the power of the microwave emitter is ten kilowatts per square meter or greater.

16. A method for making a lithium-ion cell, the method comprising:
depositing an electrode material as a coating on a substrate of the lithium-ion cell, the substrate in the form of a continuous sheet;
passing the deposited electrode material through a field of microwave irradiation, wherein the deposited electrode material is continuously irradiated with microwave radiation linearly increased from an initial frequency to a final frequency, the initial frequency and the final frequency chosen for a threshold output power and further to prevent nodal planes from forming along the electrode material, wherein the increasing coincides with a time taken for a given portion of the electrode material to pass through the field of microwave irradiation, wherein a feed roller for feeding the deposited electrode material through the field of microwave irradiation is configured to maintain a suitable amount of tension in the sheet;
folding or winding the electrode material with one or more separator layers;
wetting the irradiated electrode material with a non-aqueous electrolyte solution; and
sealing the wetted electrode material in an air-tight enclosure.

17. The method of claim 16 wherein the substrate includes a metal, which is irradiated along with the electrode material.

Assignees

• A123 Systems Llc

Inventors

• Allison Chad
• Ahmad Iftikhar

Classifications

• F26B21/40

  using gases other than air · CPC title

• H01M10/0404

  Machines for assembling batteries · CPC title

• H01M4/133

  Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx · CPC title

• H01M4/1393

  of electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx · CPC title

• H01M4/0419

  involving spraying · CPC title